公开(公告)号：US5545837A

公开(公告)日：1996-08-13

申请号：US441906

申请日：1995-05-16

申请人： Hideki Kobayashi

发明人： Hideki Kobayashi

IPC分类号： C07F7/08 ,  C08G77/48 ,  C08G77/50 ,  C08G81/00 ,  C07F7/18

CPC分类号： C08G77/485 ,  C08G77/48 ,  C08G77/50

摘要： The present invention relates to cyclic organosilicon compounds which are viscous liquids at room temperature and have a high surface tension. The present invention also relates to methods of making the cyclic organosilicon compounds which easily produce these compounds in good yields.

摘要翻译： 本发明涉及在室温下为粘性液体并具有高表面张力的环状有机硅化合物。 本发明还涉及制备环状有机硅化合物的方法，所述环状有机硅化合物容易以良好的产率生产这些化合物。

公开(公告)号：US5545682A

公开(公告)日：1996-08-13

申请号：US447663

申请日：1995-05-23

申请人： Nobuo Kaiya ,  Hideki Kobayashi

发明人： Nobuo Kaiya ,  Hideki Kobayashi

IPC分类号： C08L83/05 ,  C08L83/04 ,  C08L83/07 ,  C08L83/14 ,  C09D183/00 ,  C09D183/04 ,  C09D183/05 ,  C09D183/07 ,  C09D183/14 ,  C09J7/02 ,  D21H19/00 ,  C08K5/54

CPC分类号： C09D183/04 ,  C09D183/14

摘要： The introduction of release coating-forming silicone compositions that yield cured release coatings that exhibit excellent release properties against tacky substances and do not impair the residual adhesion of tacky substances.Silicone composition for the formation of cured release coatings, that characteristically comprises(A) 100 weight parts of a cured coating-forming silicone composition into which there is admixed(B) 0.5 to 500 weight parts organosilicon polymer with the following average unit formula ##STR1## wherein R represents C.sub.1 to C.sub.10 monovalent hydrocarbon groups that are free of aliphatic unsaturation; R.sup.1 represents organic groups selected from the group consisting essentially of C.sub.2 to C.sub.20 alkylene groups and organic groups with the formulas --R.sup.3 (OR.sup.3).sub.y -- and --R.sup.3 --(R.sub.2 SiO).sub.z R.sub.2 Si--R.sup.3 -- (R is defined as above, R.sup.3 denotes C.sub.2 to C.sub.20 alkylene groups, which may be the same or different, y is an integer with a value of 1 or more, and z is zero or an integer with a value of 1 or more); R.sup.2 represents groups selected from the group consisting essentially of C.sub.1 to C.sub.10 monovalent hydrocarbon groups, the hydrogen atom, C.sub.1 to C.sub.10 alkoxy groups, and the hydroxyl group; n=3 to 20; x=1 to 13; and n.gtoreq.x.

摘要翻译： 引入形成脱胶涂层的脱模涂层硅氧烷组合物，其产生对粘性物质具有优异的剥离性能并且不损害粘性物质的残留粘附性的固化脱模涂层。 用于形成固化剥离涂层的硅氧烷组合物，其特征在于包含（A）100重量份固化的涂覆形成硅氧烷组合物，其中混合（B）0.5至500重量份的具有以下平均单元式的有机硅聚合物其中R表示不含脂族不饱和度的C1至C10单价烃基; R1表示选自基本上由C2〜C20亚烷基组成的组的有机基团和具有式-R3（OR3）y-和-R3-（R2SiO）zR2Si-R3-的有机基团（R定义如上，R3表示C2 至20个亚烷基，其可以相同或不同，y为1以上的整数，z为0或为1以上的整数）。 R2表示选自基本上由C1至C10单价烃基，氢原子，C1至C10烷氧基和羟基组成的组的基团; n = 3〜20; x = 1〜13; 和n> / = x。

公开(公告)号：US5504175A

公开(公告)日：1996-04-02

申请号：US428599

申请日：1995-04-25

申请人： Hideki Kobayashi

发明人： Hideki Kobayashi

IPC分类号： C08G77/06 ,  C08G77/20 ,  C08G77/22 ,  C08G77/42 ,  C08G77/44 ,  C08G77/50 ,  C08G77/08

CPC分类号： C08G77/50

摘要： A method for manufacturing, with high yield and without accompanying depolymerization, an organosilicon polymer with double-ended functionality which contains a bond between a silicon atom and a hydrogen atom or an alkenyl group at both ends of the molecular chain. The organosilicon polymer with double-ended functionality is expressed by the general formula:R.sup.3 R.sup.1.sub.2 SiO(R.sup.1.sub.2 SiO).sub.p R.sup.1.sub.2 Si {R.sup.4 R.sup.1.sub.2 SiO(R.sup.1.sub.2 SiO).sub.m SiR.sup.1 .sub.2 }.sub.n R.sup.3.wherein R.sup.1 is a C.sub.1-10 monovalent hydrocarbon group that does not contain an aliphatic unsaturated bond, R.sup.2 is a C.sub.2-10 alkenyl group, R.sup.3 in the same molecule is either only a hydrogen atom or only a C.sub.2-10 alkenyl group, R.sup.4 is a C.sub.2-10 alkylene group, m is an integer equal to or greater than 0, n is a positive integer and p is an integer equal to or greater than 0. This method is an addition polymerization of a diorganosiloxane expressed by the general formulaR.sup.3 R.sup.1.sub.2 SiO(R.sup.1.sub.2 SiO).sub.m SiR.sup.1.sub.2 Hand a diorganosiloxane expressed by the general formula:R.sup.3 R.sup.1.sub.2 SiO(R.sup.1.sub.2 SiO).sub.p SiR.sup.1.sub.2 R.sup.3in the presence of a catalyst for producing a hydrosilylation.

摘要翻译： 具有高收率且无伴随解聚的具有双端官能团的有机硅聚合物的方法，该方法在分子链的两端含有硅原子和氢原子或链烯基之间的键。 具有双端官能团的有机硅聚合物由以下通式表示：R3R12SiO（R12SiO）pR12Si {R4R12SiO（R12SiO）mSiR1 2} nR3。 其中R1是不含脂族不饱和键的C1-10一价烃基，R2是C2-10链烯基，同一分子中的R3只是氢原子或仅C2-10链烯基，R4是 C2-10亚烷基，m是等于或大于0的整数，n是正整数，p是等于或大于0的整数。该方法是由通式R3R12SiO表示的二有机硅氧烷的加成聚合 （R12SiO）mSiR12H和由用于产生氢化硅烷化的催化剂存在下由通式R3R12SiO（R12SiO）pSiR12R3表示的二有机硅氧烷。

公开(公告)号：US5446115A

公开(公告)日：1995-08-29

申请号：US287998

申请日：1994-08-09

申请人： Hideki Kobayashi

发明人： Hideki Kobayashi

IPC分类号： C09D5/00 ,  C07F7/08 ,  C09D4/00 ,  C09D5/08 ,  C09D183/04 ,  C09D183/08 ,  C09K3/00 ,  C09K3/18 ,  C08G77/08

CPC分类号： C07F7/0896 ,  C09D4/00 ,  Y10T428/31663

摘要： A curable composition suitable for treating substrates in order to render them oil repellent, water repellent and stain resistant, said composition comprising:(A) a fluorine-containing organosilicon compound having the general formula ##STR1## wherein R.sup.1 denotes a monovalent hydrocarbon group, excluding alkenyl groups, R.sup.2 denotes a divalent organic group, a is 2 or 3, and m is an integer having a value of 4 to 12, or a partial hydrolysis and condensation product thereof, and(B) a catalytic quantity of a condensation-reaction catalyst.

摘要翻译： 所述组合物包含：（A）具有通式“IMAGE”的含氟有机硅化合物，其中R1表示一价烃基，不包括 烯基，R 2表示二价有机基团，a为2或3，m为4〜12的整数或其部分水解缩合物，（B）催化量的缩合反应 催化剂。

公开(公告)号：US5445131A

公开(公告)日：1995-08-29

申请号：US212886

申请日：1994-03-14

申请人： Hideki Kusunoki ,  Masaki Fujii ,  Hideki Kobayashi

发明人： Hideki Kusunoki ,  Masaki Fujii ,  Hideki Kobayashi

IPC分类号： F02D41/04 ,  F02D41/12

CPC分类号： F02D41/123

摘要： A fuel control system causes a fuel injector to interrupt fuel injection during a continuous decrease in engine speed to a lower limit of a hysteresis range for fuel supply/fuel interruption and to resume the interruption of fuel supply after a continuous increase in engine speed beyond an upper limit of the hysteresis range and further causes a compulsory interruption of fuel supply when a transition of the engine from non-deceleration to deceleration while the engine operates at speeds between the lower and upper limits of the hysteresis range.

摘要翻译： 燃料控制系统使得燃料喷射器在将发动机转速连续降低到燃料供应/燃料中断的滞后范围的下限期间中断燃油喷射，并且在发动机转速连续增加超过 当发动机在滞后范围的下限和上限之间的速度下工作时，发动机从非减速到减速的转变时，进一步导致燃料供给的强制中断。

公开(公告)号：US5442083A

公开(公告)日：1995-08-15

申请号：US296060

申请日：1994-08-24

申请人： Hideki Kobayashi

发明人： Hideki Kobayashi

IPC分类号： C08G77/48 ,  C08G77/50 ,  C07F7/08

CPC分类号： C08G77/50

摘要： There is disclosed a method for the preparation of an organosilicon polymer having the structure ##STR1## wherein each R.sup.1 is a monovalent hydrocarbon group, R.sup.2 is an alkylene group, R.sup.3 is selected from hydrogen, an alkenyl group or a hydroxyl group, m is zero or greater and n is 1 or more, said method comprising:reacting(A) diorganosiloxane having the general formula ##STR2## (B) an unsaturated aliphatic hydrocarbon having 3 to 10 carbon atoms that contains 2 carbon-carbon double bonds and an unsaturated aliphatic hydrocarbon having 2 to 10 carbon atoms that contains 1 carbon-carbon triple bond, said reaction taking place in the presence of(C) a hydrosilylation-reaction catalyst.

摘要翻译： 公开了具有结构“IMAGE”的有机硅聚合物的制备方法，其中每个R 1是一价烃基，R 2是亚烷基，R 3选自氢，链烯基或羟基，m是0 或更大，n为1或更大，所述方法包括：（A）具有通式（B）的二有机硅氧烷（B）含有2个碳 - 碳双键的具有3至10个碳原子的不饱和脂族烃和不饱和脂肪族 所述反应在（C）氢化硅烷化反应催化剂存在下进行，所述碳原子数为2〜10。

公开(公告)号：US5428097A

公开(公告)日：1995-06-27

申请号：US220139

申请日：1994-03-30

申请人： Hideki Kobayashi

发明人： Hideki Kobayashi

IPC分类号： C08K3/36 ,  C04B28/02 ,  C08K5/14 ,  C08L83/04 ,  C08L83/07 ,  C08L83/06

CPC分类号： C08L83/04 ,  C04B28/02 ,  C08G77/12 ,  C08G77/16 ,  C08G77/20 ,  C08G77/24 ,  C08G77/44

摘要： A silicone rubber composition having good processability and good molding properties is disclosed, said composition comprising:(A) an organopolysiloxane containing vinyl groups;(B) a fluorine resin powder;(C) an organopolysiloxane containing units having the formulaF(CF.sub.2).sub.a CH.sub.2 CH.sub.2 Si(Me).sub.n O.sub.3-n/2in which a is an integer of at least 4, n is 0, 1 or 2 and Me denotes a methyl radical;(D) a reinforcing silica powder having a surface area of at least 50 m.sup.2 /g; and(E) a sufficient quantity of a curing agent to cure said composition.

摘要翻译： 公开了具有良好加工性和良好成型性能的硅橡胶组合物，所述组合物包含：（A）含有乙烯基的有机聚硅氧烷; （B）氟树脂粉末; （C）含有式F（CF2）aCH2CH2Si（Me）nO3-n / 2的单元的有机聚硅氧烷，其中a为至少4的整数，n为0,1或2，Me为甲基; （D）表面积为至少50m 2 / g的增强二氧化硅粉末; 和（E）足量的固化剂以固化所述组合物。

公开(公告)号：US5423392A

公开(公告)日：1995-06-13

申请号：US212808

申请日：1994-03-15

申请人： Hideki Kobayashi ,  Masaki Fujii ,  Hiroyuki Matsumoto

发明人： Hideki Kobayashi ,  Masaki Fujii ,  Hiroyuki Matsumoto

IPC分类号： B60T8/175 ,  B60K28/16 ,  F02B33/00 ,  F02D17/02 ,  F02D23/00 ,  F02D29/02 ,  F02D37/00 ,  F02D41/00 ,  F02D41/02 ,  F02D41/04 ,  F02D45/00 ,  F02P5/15

CPC分类号： B60K28/16 ,  F02D37/00 ,  F02D41/0007 ,  Y02T10/144

摘要： For an internal combustion engine with a supercharger, a slip of the driven wheel is controlled by reducing torque of the engine, when the extent of the slip becomes large in relation to a road surface. When the running status of the engine exists in a non-supercharging region, the slip is controlled by at least one of operations for reducing the amount of fuel to be supplied to the engine and for retarding the timing of ignition (first slip control). On the other hand, in a supercharging region, the slip is controlled by lowering the pressure to be supercharged (second slip control). In a transient period of time when the running status of the engine is caused to shift from the non-supercharging region to the supercharging region when the first slip control is being conducted in the non-supercharging region, the first slip control is allowed to be continued until the slip is caused to be converged, in place of the second slip control.

摘要翻译： 对于具有增压器的内燃机，当滑动程度相对于路面变大时，通过减小发动机的扭矩来控制从动轮的滑动。 当发动机的运行状态存在于非增压区域时，通过用于减少要供给到发动机的燃料量和用于延迟点火正时（第一滑差控制）的操作中的至少一个来控​​制滑差。 另一方面，在增压区域中，通过降低要进行增压的压力（第二滑移控制）来控制滑差。 在非增压区域进行第一滑移控制的情况下，在使非发动机的运转状态从非增压区域向增压区域移动的过渡期间，允许第一滑移控制为 继续直到使滑动收敛，代替第二滑移控制。

公开(公告)号：US5371155A

公开(公告)日：1994-12-06

申请号：US70062

申请日：1993-06-01

申请人： Hideki Kobayashi

发明人： Hideki Kobayashi

IPC分类号： C08G77/24 ,  C08G77/22 ,  C08K5/5419 ,  C08L83/04 ,  C08L83/08 ,  C09D183/08

CPC分类号： C08L83/08

摘要： A curable fluorosilicone resin composition is disclosed, which composition comprises(A) 100 parts by weight of a fluorosilicone resin consisting essentially of F(CF.sub.2)aCH.sub.2 CH.sub.2 SiO.sub.3/2) siloxane units and, optionally, R.sub.b SiO.sub.(4-b)/2 siloxane units, wherein R is a substituted or unsubstituted monovalent hydrocarbon group having 1 to 8 carbon atoms, a is an integer with a value of at least 4 and b is an integer with a value of 0 to 3, with the proviso that when said fluorosilicone resin contains said R.sub.b SiO.sub.(4-b)/2 siloxane units, the ratio of said F(CF.sub.2).sub.a CH.sub.2 CH.sub.2 SiO.sub.3/2 siloxane units to said R.sub.b SiO.sub.(4-b)/2 siloxane units is at least 1;(B) 1 to 90 parts by weight of a component selected from the group consisting of an organosilane and its partial hydrolysis product, said organosilane having the general formula R.sup.1.sub.c SiX.sub.4-c wherein R.sup.1 is a substituted or unsubstituted monovalent hydrocarbon group having 1 to 8 carbon atoms, c is 0, 1, or 2 and X is a hydrolyzable group; and(c) a sufficient amount of a condensation catalyst to accelerate the cure of said fluorosilicone resin composition.

摘要翻译： 公开了一种可固化的氟硅酮树脂组合物，该组合物包含（A）100重量份基本上由F（CF 2）aCH 2 CH 2 SiO 3/2）硅氧烷单元和任选的RbSiO（4-b）/ 2硅氧烷单元组成的氟硅树脂， 其中R是取代或未取代的具有1-8个碳原子的一价烃基，a是至少为4的整数，b是0-3的整数，条件是当所述含氟硅氧烷树脂含有 所述RbSiO（4-b）/ 2硅氧烷单元，所述F（CF2）aCH2CH2SiO3 / 2硅氧烷单元与所述RbSiO（4-b）/ 2硅氧烷单元的比例为至少1; （B）1〜90重量份选自有机硅烷及其部分水解产物的组分，所述有机硅烷具有通式R 1 c SiX 4-c，其中R 1是具有1至8个碳的取代或未取代的一价烃基 原子，c为0,1或2，X为可水解基团; 和（c）足够量的缩合催化剂以加速所述氟硅酮树脂组合物的固化。

公开(公告)号：US5350824A

公开(公告)日：1994-09-27

申请号：US79657

申请日：1993-06-18

申请人： Hideki Kobayashi

发明人： Hideki Kobayashi

IPC分类号： C08G77/16 ,  C08G77/06 ,  C08G77/08 ,  C08G77/22 ,  C08G77/24 ,  C08L83/08

CPC分类号： C08G77/24 ,  C08G77/08 ,  C08L83/08

摘要： The instant invention pertains to novel fluorosilicone polymers that have a very low surface tension, excellent oil resistance, excellent heat resistance, and so forth.The fluorosilicone polymers of the instant invention are fluorosilicone polymers comprised of siloxane unit with the following formula[F(CF.sub.2).sub.a C.sub.2 H.sub.4 ].sub.2 SiO.sub.2/2 (a)where a is an integer with a value of 1 to 10 and fluorosilicone polymers as represented by the following formula{[F(CF.sub.2).sub.a C.sub.2 H.sub.4 ].sub.2 SiO.sub.2/2 }.sub.x (R.sub.2 SiO.sub.2/2).sub.y (c)wherein a is an integer with a value of 1 to 10, x is an integer with a value of at least 2, y is an integer with a value of at least 1, x>y, and R is a monovalent hydrocarbon group.

摘要翻译： 本发明涉及具有非常低的表面张力，优异的耐油性，优异的耐热性等的新型氟硅氧烷聚合物。 本发明的氟硅聚合物是由以下式[F（CF 2）aC 2 H 4] 2 SiO 2/2（a）的硅氧烷单元组成的氟硅氧烷聚合物，其中a为值为1至10的整数，并且氟代硅氧烷聚合物由 以下式{[F（CF 2）aC 2 H 4] 2 SiO 2/2} x（R 2 SiO 2/2）y（c）其中a是值为1至10的整数，x是至少为2的整数，y 是值为至少1，x> y的整数，R是一价烃基。