公开(公告)号：US11488857B2

公开(公告)日：2022-11-01

申请号：US16906615

申请日：2020-06-19

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Yu-Shih Wang ,  Po-Nan Yeh ,  U-Ting Chiu ,  Chun-Neng Lin ,  Chia-Cheng Chen ,  Liang-Yin Chen ,  Ming-Hsi Yeh ,  Kuo-Bin Huang

IPC: H01L21/768 ,  H01L23/522 ,  H01L23/532

Abstract: Semiconductor devices and methods of manufacture are described herein. A method includes forming an opening through an interlayer dielectric (ILD) layer to expose a contact etch stop layer (CESL) disposed over a conductive feature in a metallization layer. The opening is formed using photo sensitive materials, lithographic techniques, and a dry etch process that stops on the CESL. Once the CESL is exposed, a CESL breakthrough process is performed to extend the opening through the CESL and expose the conductive feature. The CESL breakthrough process is a flexible process with a high selectivity of the CESL to ILD layer. Once the CESL breakthrough process has been performed, a conductive fill material may be deposited to fill or overfill the opening and is then planarized with the ILD layer to form a contact plug over the conductive feature in an intermediate step of forming a semiconductor device.

公开(公告)号：US11276571B2

公开(公告)日：2022-03-15

申请号：US16907634

申请日：2020-06-22

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Yu Shih Wang ,  Hong-Jie Yang ,  Chia-Ying Lee ,  Po-Nan Yeh ,  U-Ting Chiu ,  Chun-Neng Lin ,  Ming-Hsi Yeh ,  Kuo-Bin Huang

IPC: H01L21/027 ,  H01L21/8234 ,  H01L29/78 ,  H01L29/66 ,  H01L21/308

Abstract: A photo resist layer is used to protect a dielectric layer and conductive elements embedded in the dielectric layer when patterning an etch stop layer underlying the dielectric layer. The photo resist layer may further be used to etch another dielectric layer underlying the etch stop layer, where etching the next dielectric layer exposes a contact, such as a gate contact. The bottom layer can be used to protect the conductive elements embedded in the dielectric layer from a wet etchant used to etch the etch stop layer.

公开(公告)号：US20210375677A1

公开(公告)日：2021-12-02

申请号：US16887316

申请日：2020-05-29

Applicant: Taiwan Semiconductor Manufacturing Co. Ltd.

Inventor： Yu Shih Wang ,  Kuo-Bin Huang ,  Ming-Hsi Yeh ,  Po-Nan Yeh

IPC: H01L21/768 ,  H01L21/8238 ,  H01L29/66 ,  H01L21/28 ,  H01L21/3213 ,  H01L27/092 ,  H01L29/08 ,  H01L29/49 ,  H01L23/535

Abstract: A method for forming a semiconductor device includes forming a metal contact on a substrate, forming a first dielectric on the metal contact, forming a first opening in the first dielectric, and performing a wet etch on a bottom surface of the first opening through a first etch stop layer (ESL) over the metal contact. The wet etch forms a first recess in a top surface of the metal contact. An upper width of the first recess is smaller than a lower width of the first recess. A first conductive feature is formed in the first recess and the first opening.

公开(公告)号：US11189714B2

公开(公告)日：2021-11-30

申请号：US16928423

申请日：2020-07-14

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Ming-Chi Huang ,  Ying-Liang Chuang ,  Ming-Hsi Yeh ,  Kuo-Bin Huang

IPC: H01L29/66 ,  H01L29/78 ,  H01L21/285 ,  H01L29/06 ,  H01L21/02 ,  H01L21/8234 ,  H01L21/3115 ,  H01L21/311 ,  H01L29/49 ,  H01L29/08 ,  H01L29/165 ,  H01L29/51

Abstract: Embodiments of the present disclosure provide a method of cleaning a lanthanum containing substrate without formation of undesired lanthanum compounds during processing. In one embodiment, the cleaning method includes treating the lanthanum containing substrate with an acidic solution prior to cleaning the lanthanum containing substrate with a HF solution. The cleaning method permits using lanthanum doped high-k dielectric layer to modulate effective work function of the gate stack, thus, improving device performance.

公开(公告)号：US20210193469A1

公开(公告)日：2021-06-24

申请号：US17187176

申请日：2021-02-26

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Ju-Li Huang ,  Ying-Liang Chuang ,  Ming-Hsi Yeh ,  Kuo-Bin Huang

IPC: H01L21/28 ,  H01L27/092 ,  H01L29/49 ,  H01L29/51 ,  H01L21/8238 ,  H01L29/66 ,  H01L21/3213

Abstract: Semiconductor device structures having metal gate structures with tunable work function values are provided. In one example, a first gate structure and a second gate structure formed on a substrate, wherein the first gate structure includes a first work function metal having a first material, and the second gate structure includes a second work function metal having a second material, the first material being different from the second material, wherein the first gate structure further includes a gate dielectric layer, a self-protective layer having metal phosphate, and the first work function metal on the self-protective layer.

公开(公告)号：US20210134662A1

公开(公告)日：2021-05-06

申请号：US17120668

申请日：2020-12-14

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Yu Shih Wang ,  Shian Wei Mao ,  Ming-Hsi Yeh ,  Kuo-Bin Huang

IPC: H01L21/768 ,  H01L23/522

Abstract: In one exemplary aspect, a method comprises providing a semiconductor structure having a substrate, one or more first dielectric layers over the substrate, a first metal plug in the one or more first dielectric layers, and one or more second dielectric layers over the one or more first dielectric layers and the first metal plug. The method further comprises etching a via hole into the one or more second dielectric layers to expose the first metal plug, etching a top surface of the first metal plug to create a recess thereon, and applying a metal corrosion protectant comprising a metal corrosion inhibitor to the top surface of the first metal plug.

公开(公告)号：US10283503B2

公开(公告)日：2019-05-07

申请号：US15799555

申请日：2017-10-31

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Ming-Chi Huang ,  Ying-Liang Chuang ,  Ming-Hsi Yeh ,  Kuo-Bin Huang

IPC: H01L27/088 ,  H01L21/8234 ,  H01L21/311 ,  H01L21/3213 ,  H01L29/66 ,  H01L29/49 ,  H01L29/51 ,  H01L29/06 ,  H01L29/423

Abstract: Provided is a metal gate structure and related methods that include performing a metal gate cut process. The metal gate cut process includes a plurality of etching steps. For example, a first anisotropic dry etch is performed, a second isotropic dry etch is performed, and a third wet etch is performed. In some embodiments, the second isotropic etch removes a residual portion of a metal gate layer including a metal containing layer. In some embodiments, the third etch removes a residual portion of a dielectric layer.