公开(公告)号：US12015077B2

公开(公告)日：2024-06-18

申请号：US17676335

申请日：2022-02-21

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Ju-Li Huang ,  Chun-Sheng Liang ,  Ming-Chi Huang ,  Ming-Hsi Yeh ,  Ying-Liang Chuang ,  Hsin-Che Chiang

IPC: H01L29/66 ,  H01L21/311 ,  H01L21/3213 ,  H01L21/8234 ,  H01L29/78 ,  H01L21/02 ,  H01L21/027 ,  H01L21/3105 ,  H01L21/321

CPC classification number: H01L29/66545 ,  H01L21/31111 ,  H01L21/31144 ,  H01L21/32133 ,  H01L21/32139 ,  H01L21/823431 ,  H01L21/82345 ,  H01L29/66795 ,  H01L29/7851 ,  H01L21/0206 ,  H01L21/02068 ,  H01L21/0276 ,  H01L21/31053 ,  H01L21/3212 ,  H01L29/6656 ,  H01L29/66636

Abstract: Methods for, and structures formed by, wet process assisted approaches implemented in a replacement gate process are provided. Generally, in some examples, a wet etch process for removing a capping layer can form a first monolayer on the underlying layer as an adhesion layer and a second monolayer on, e.g., an interfacial dielectric layer between a gate spacer and a fin as an etch protection mechanism. Generally, in some examples, a wet process can form a monolayer on a metal layer, like a barrier layer of a work function tuning layer, as a hardmask for patterning of the metal layer.

公开(公告)号：US11810978B2

公开(公告)日：2023-11-07

申请号：US17339020

申请日：2021-06-04

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Ju-Li Huang ,  Hsin-Che Chiang ,  Yu-Chi Pan ,  Chun-Ming Yang ,  Chun-Sheng Liang ,  Ying-Liang Chuang ,  Ming-Hsi Yeh

IPC: H01L29/78 ,  H01L29/423 ,  H01L21/285 ,  H01L29/40 ,  H01L21/3213 ,  H01L29/49

CPC classification number: H01L29/785 ,  H01L21/28556 ,  H01L21/32134 ,  H01L29/401 ,  H01L29/42372 ,  H01L29/4966

Abstract: The present disclosure describes structure and method of a fin field-effect transistor (finFET) device. The finFET device includes: a substrate, a fin over the substrate, and a gate structure over the fin. The gate structure includes a work-function metal (WFM) layer over an inner sidewall of the gate structure. A topmost surface of the WFM layer is lower than a top surface of the gate structure. The gate structure also includes a filler gate metal layer over the topmost surface of the WFM layer. A top surface of the filler gate metal layer is substantially co-planar with the top surface of the gate structure. The gate structure further includes a self-assembled monolayer (SAM) between the filler gate metal layer and the WFM layer.

公开(公告)号：US11444173B2

公开(公告)日：2022-09-13

申请号：US15797973

申请日：2017-10-30

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Hsiang-Ku Shen ,  Jin-Mu Yin ,  Tsung-Chieh Hsiao ,  Chia-Lin Chuang ,  Li-Zhen Yu ,  Dian-Hau Chen ,  Shih-Wei Wang ,  De-Wei Yu ,  Chien-Hao Chen ,  Bo-Cyuan Lu ,  Jr-Hung Li ,  Chi-On Chui ,  Min-Hsiu Hung ,  Hung-Yi Huang ,  Chun-Cheng Chou ,  Ying-Liang Chuang ,  Yen-Chun Huang ,  Chih-Tang Peng ,  Cheng-Po Chau ,  Yen-Ming Chen

IPC: H01L29/66 ,  H01L21/8234 ,  H01L27/088 ,  H01L21/311 ,  H01L29/78 ,  H01L21/768 ,  H01L21/3065 ,  H01L29/45 ,  H01L29/08 ,  H01L29/165

Abstract: Structures and formation methods of a semiconductor device structure are provided. The method includes forming a fin structure over a substrate. The method also includes forming a gate structure over the fin structure. The method further includes forming fin spacers over sidewalls of the fin structure and gate spacers over sidewalls of the gate structure. In addition, the method includes forming a source/drain structure over the fin structure and depositing a dummy material layer to cover the source/drain structure. The dummy material layer is removed faster than the gate spacers during the removal of the dummy material layer. The method further includes forming a salicide layer over the source/drain structure and the fin spacers, and forming a contact over the salicide layer. The dummy material layer includes Ge, amorphous silicon or spin-on carbon.

公开(公告)号：US20190341317A1

公开(公告)日：2019-11-07

申请号：US16517767

申请日：2019-07-22

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Ju-Li Huang ,  Chih-Long Chiang ,  Kuo Bin Huang ,  Ming-Hsi Yeh ,  Ying-Liang Chuang

IPC: H01L21/8238 ,  H01L21/311 ,  H01L29/51 ,  H01L27/088 ,  H01L21/02 ,  H01L21/3105 ,  H01L21/8234 ,  H01L21/28

Abstract: Embodiments of the present disclosure provide wet process based methods for modifying threshold value (Vt) of high-k metal gate using self-assembled monolayer (SAM) on dedicated transistor. In one embodiment, the method includes forming a gate structure over a substrate, the gate structure comprising a gate dielectric layer, a barrier layer formed over the gate dielectric layer, and an oxide layer formed over the barrier layer, and forming a self-assembled monolayer on the oxide layer by exposing the oxide layer to an aqueous solution containing metal oxides in a metal dissolving acid.

公开(公告)号：US10170317B1

公开(公告)日：2019-01-01

申请号：US15718565

申请日：2017-09-28

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Ju-Li Huang ,  Ying-Liang Chuang ,  Ming-Hsi Yeh ,  Kuo-Bin Huang

IPC: H01L29/49 ,  H01L21/28 ,  H01L27/092 ,  H01L29/51 ,  H01L21/8238 ,  H01L29/66

Abstract: Semiconductor device structures having metal gate structures with tunable work function values are provided. In one example, a first gate structure and a second gate structure formed on a substrate, wherein the first gate structure includes a first work function metal having a first material, and the second gate structure includes a second work function metal having a second material, the first material being different from the second material, wherein the first gate structure further includes a gate dielectric layer, a self-protective layer having metal phosphate, and the first work function metal on the self-protective layer.

公开(公告)号：US20240153826A1

公开(公告)日：2024-05-09

申请号：US18410589

申请日：2024-01-11

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Yao-Wen Hsu ,  Ming-Chi Huang ,  Ying-Liang Chuang

IPC: H01L21/8238 ,  H01L21/28 ,  H01L21/3213

CPC classification number: H01L21/823842 ,  H01L21/28088 ,  H01L21/32134 ,  H01L21/32139 ,  H01L21/823821

Abstract: Semiconductor devices and methods which utilize a treatment process of a bottom anti-reflective layer are provided. The treatment process may be a physical treatment process in which material is added in order to fill holes and pores within the material of the bottom anti-reflective layer or else the treatment process may be a chemical treatment process in which a chemical reaction is used to form a protective layer. By treating the bottom anti-reflective layer the diffusion of subsequently applied chemicals is reduced or eliminated, thereby helping to prevent defects that arise from such diffusion.

公开(公告)号：US11854903B2

公开(公告)日：2023-12-26

申请号：US17073784

申请日：2020-10-19

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Ming-Chi Huang ,  Kuo-Bin Huang ,  Ying-Liang Chuang ,  Ming-Hsi Yeh

IPC: H01L29/66 ,  H01L29/78 ,  H01L27/092 ,  H01L21/8234 ,  H01L21/8238 ,  H01L21/3213 ,  H01L21/311

CPC classification number: H01L21/823481 ,  H01L21/32134 ,  H01L21/32135 ,  H01L21/32136 ,  H01L21/823437 ,  H01L21/823821 ,  H01L21/823828 ,  H01L21/823864 ,  H01L21/823878 ,  H01L29/66545 ,  H01L29/66795 ,  H01L29/7854 ,  H01L21/31133 ,  H01L27/0924

Abstract: A method includes forming a gate stack, which includes a first portion over a portion of a first semiconductor fin, a second portion over a portion of a second semiconductor fin, and a third portion connecting the first portion to the second portion. An anisotropic etching is performed on the third portion of the gate stack to form an opening between the first portion and the second portion. A footing portion of the third portion remains after the anisotropic etching. The method further includes performing an isotropic etching to remove a metal gate portion of the footing portion, and filling the opening with a dielectric material.

公开(公告)号：US20220173226A1

公开(公告)日：2022-06-02

申请号：US17676335

申请日：2022-02-21

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Ju-Li Huang ,  Chun-Sheng Liang ,  Ming-Chi Huang ,  Ming-Hsi Yeh ,  Ying-Liang Chuang ,  Hsin-Che Chiang

IPC: H01L29/66 ,  H01L29/78 ,  H01L21/311 ,  H01L21/3213 ,  H01L21/8234

Abstract: Methods for, and structures formed by, wet process assisted approaches implemented in a replacement gate process are provided. Generally, in some examples, a wet etch process for removing a capping layer can form a first monolayer on the underlying layer as an adhesion layer and a second monolayer on, e.g., an interfacial dielectric layer between a gate spacer and a fin as an etch protection mechanism. Generally, in some examples, a wet process can form a monolayer on a metal layer, like a barrier layer of a work function tuning layer, as a hardmask for patterning of the metal layer.

公开(公告)号：US11114436B2

公开(公告)日：2021-09-07

申请号：US16947758

申请日：2020-08-14

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Ming-Chi Huang ,  Ying-Liang Chuang ,  Ming-Hsi Yeh ,  Kuo-Bin Huang

IPC: H01L27/088 ,  H01L21/3213 ,  H01L21/8234 ,  H01L29/66 ,  H01L29/49 ,  H01L21/311 ,  H01L29/51 ,  H01L29/06 ,  H01L29/423 ,  H01L21/8238 ,  H01L27/092

Abstract: Provided is a metal gate structure and related methods that include performing a metal gate cut process. The metal gate cut process includes a plurality of etching steps. For example, a first anisotropic dry etch is performed, a second isotropic dry etch is performed, and a third wet etch is performed. In some embodiments, the second isotropic etch removes a residual portion of a metal gate layer including a metal containing layer. In some embodiments, the third etch removes a residual portion of a dielectric layer.

公开(公告)号：US20210125877A1

公开(公告)日：2021-04-29

申请号：US16889160

申请日：2020-06-01

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Yao-Wen Hsu ,  Ming-Chi Huang ,  Ying-Liang Chuang

IPC: H01L21/8238 ,  H01L21/3213 ,  H01L21/28

Abstract: Semiconductor devices and methods which utilize a treatment process of a bottom anti-reflective layer are provided. The treatment process may be a physical treatment process in which material is added in order to fill holes and pores within the material of the bottom anti-reflective layer or else the treatment process may be a chemical treatment process in which a chemical reaction is used to form a protective layer. By treating the bottom anti-reflective layer the diffusion of subsequently applied chemicals is reduced or eliminated, thereby helping to prevent defects that arise from such diffusion.