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    Organo-metallo-carbonyl complexes prepared by the reaction of acetylene with a metalcarbonyl
    52.
    发明授权
    Organo-metallo-carbonyl complexes prepared by the reaction of acetylene with a metalcarbonyl 失效
    通过乙炔与金属羰基反应制备的有机金属羰基络合物

    公开(公告)号：US3188335A

    公开(公告)日：1965-06-08

    申请号：US21910262

    申请日：1962-08-24

    申请人： UNION CARBIDE CORP

    发明人： HUBEL KARL W

    IPC分类号： C07C1/32 ,  C07C45/00 ,  C07C46/00 ,  C07C50/02 ,  C07C50/06 ,  C07F7/08 ,  C07F17/00 ,  C10L1/30 ,  C23C16/16

    CPC分类号： C23C16/16 ,  C07C1/325 ,  C07C45/00 ,  C07C46/00 ,  C07C50/02 ,  C07C50/06 ,  C07F7/0818 ,  C07F7/0827 ,  C07F17/00 ,  C10L1/30 ,  C10L1/305 ,  Y10S585/931 ,  C07C15/02

    摘要： The invention comprises the product of reacting under neutral non-aqueous conditions a transition metal carbonyl or a derivative thereof with an acetylene compound the product having the formula where M is a transition metal, N is a carbonyl group or a substituted carbonyl group, R1 and R11 each represent hydrogen or an organic group or substituted derivatives thereof or an organo substituted hydride group, C2 represents direct carbon to carbon bonding, x is an integer from 1 to 3, y is an integer from 2 to 12 and z is an integer from 1 to 5. M may be iron, znickel, ruthenium, rhodium, palladium, osmium iridium, manganese, rhenium, chromium, molybdenum or tungsten. The triple bond in the acetylene compound is converted into a double or single bond. If desired, the transition metal carbonyl may be prepared in situ from the metal and carbon monoxide; alternatively, a metal salt and a reducing agent may be used. The acetylene compound may be substituted by an organic group such as an alkyl, alkenyl, alkynyl, cycloaliphatic, aryl or alkylaryl group or a functional group such as -COH, -CN, -halogen, -OH, -NR2, -COOR wherein R is hydrogen, an aliphatic or aromatic radical or a hydrocarbon group substituted by such a functional group. The products may be separated by chromatography or by fractional crystallisation. From 2.5 to 6.0 moles of acetylenic compound may be used per mol of metal carbonyl. The temperature of reaction varies from room temperature up to 300 DEG C. If desired, the carbonyl groups on the metal may be partially substituted by radicals such as nitrosyl, substituted isonitrile, substituted phosphines, substituted arsines, substituted stibines and their halides and fully substituted aromatic systems. Complicated ring systems may be formed by heating the compounds of the invention, thus 1,3,5-triphenylbenzene is obtained by heating Fe2(CO)6(C6H5.C2H)3 or Fe(CO)4(C6H5.C2H)3 to about 170 DEG C. Heating Fe(CO)4(C6H5.C2.C6H5)2 to about 200 DEG C. yields tetraphenylcyclopentadienone, and heating Fe(CO)2(CH3OOC.C2.COOCH3)3 to 180 DEG C. yields the hexamethyl ester of mellitic acid.ALSO:Complexes obtained by heating a transition metal carbonyl and an acetylenic compound (see Group IV(b)) may be decomposed thermally to produce metal mirrors and films. Thus glass cloth may be coated with iron by heating the cloth in a sealed tube containing Fe2(CO)6-(C6H5.C2.C6H5) 2.

    MONOMER COMPOSITION AND METHOD FOR PRODUCING FLUORINATED POLYMER
    56.
    发明申请
    MONOMER COMPOSITION AND METHOD FOR PRODUCING FLUORINATED POLYMER 审中-公开

    公开(公告)号：US20190185600A1

    公开(公告)日：2019-06-20

    申请号：US16282377

    申请日：2019-02-22

    申请人： AGC Inc.

    发明人： Susumu SAITO ,  Wakako Hashimoto

    IPC分类号： C08F216/14 ,  H01M8/1032 ,  H01M8/1004 ,  H01M4/90 ,  H01M8/1027

    CPC分类号： C08F216/1466 ,  C07C13/20 ,  C07C39/06 ,  C07C50/02 ,  C08F34/02 ,  C08F2216/1475 ,  C08F2800/20 ,  H01M4/9008 ,  H01M8/1004 ,  H01M8/1027 ,  H01M8/1032 ,  H01M2008/1095 ,  H01M2300/0082

    摘要： To provide a monomer composition in which the solubility of the polymerization inhibitor in the cyclic monomer is good, the stability of the cyclic monomer during storage is good, and the cyclic monomer and the polymerization inhibitor are easily separated by distillation; and a method for producing a high molecular weight fluorinated polymer from the monomer composition.A monomer composition which comprises a specific cyclic monomer and a polymerization inhibitor, wherein the polymerization inhibitor is a polymerization inhibitor which satisfies (a) it is a 6-membered unsaturated cyclic hydrocarbon having from 1 to 4 substituents, (b) it has, as the substituent, at least one type selected from the group consisting of a t-butyl group, a methyl group, an isopropenyl group, an oxo group and a hydroxy group, (c) in a case where it has an oxo group as one type of the substituent, it has, as the substituent other than the oxo group, either one or both of a t-butyl group and a methyl group, and (d) in a case where it has a hydroxy group as the substituent, the number of the hydroxy group is only one.