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    Aliphatic polyurethanes containing acryloyl groups and a process for their preparation
    53.
    发明授权
    Aliphatic polyurethanes containing acryloyl groups and a process for their preparation 失效
    含有丙烯酸酯的聚氨酯和其制备方法

    公开(公告)号：US5128432A

    公开(公告)日：1992-07-07

    申请号：US749235

    申请日：1991-08-23

    申请人： Jurgen Meixner ,  Wolfgang Fischer ,  Josef Pedain

    发明人： Jurgen Meixner ,  Wolfgang Fischer ,  Josef Pedain

    IPC分类号： C08F299/06 ,  C08G18/28 ,  C08G18/32 ,  C08G18/48 ,  C08G18/67 ,  C08G18/73 ,  C09D175/14 ,  C09D175/16

    CPC分类号： C08G18/4887 ,  C08G18/284 ,  C08G18/3221 ,  C08G18/672 ,  C08G18/673 ,  C08G18/73 ,  C09D175/16

    摘要： The present invention relates to aliphatic polyurethanes which contain acryloyl groups and are based on the reaction product (at an NCO/OH equivalent ratio of 0.5:1 to 1:1) ofa) 1.0 mole of a diisocyanate component containing at least 50 equivalent percent, based on NCO equivalents, of hexamethylene diisocyanate withb) 0.5 to 0.85 moles of at least one monohydric alcohol having a molecular weight of 116 to 144 and containing acryloyl groups.c) 0.15 to 0.5 moles of a monohydric alcohol having a molecular weight of 154 to 2000 and containing ester groups or a mixture of alcohols having an average molecular weight of 154 to 2000 and an average hydroxyl functionality of 0.8 to 1.5 and containing ester groups andd) 0.3 to 0.5 moles of at least one polyhydric alcohol having a molecular weight of 62 to 2000.The present invention also relates to a process for the preparation of these polyurethanes.

    摘要翻译： 本发明涉及含有丙烯酰基并基于反应产物（以NCO / OH当量比为0.5:1至1:1）的a）1.0摩尔含至少50当量％的二异氰酸酯组分的脂族聚氨酯 基于NCO当量，六亚甲基二异氰酸酯与b）0.5至0.85摩尔的至少一种分子量为116至144的一元醇并含有丙烯酰基。 c）0.15至0.5摩尔分子量为154至2000的一元醇，并且含有酯基或平均分子量为154至2000的醇和0.8至1.5的平均羟基官能度的混合物，并且含有酯基和 d）0.3至0.5摩尔的至少一种分子量为62至2000的多元醇。本发明还涉及制备这些聚氨酯的方法。

    Hydroxy acid ester plasticized urethane elastomers
    55.
    发明授权
    Hydroxy acid ester plasticized urethane elastomers 失效
    羟基酸酯增塑聚氨酯弹性体

    公开(公告)号：US4766167A

    公开(公告)日：1988-08-23

    申请号：US100290

    申请日：1987-09-23

    申请人： Lawrence F. Marnett ,  Joseph B. Kubec

    发明人： Lawrence F. Marnett ,  Joseph B. Kubec

    IPC分类号： C08G18/32 ,  C08K5/103 ,  C08L75/04

    CPC分类号： C08G18/3221 ,  C08K5/103

    摘要： A plasticized polyurethane elastomer prepared from the combination of a polyol and an isocyanate is disclosed wherein a sufficient amount of an alpha hydroxy acid ester of a hydroxy polyol plasticizer is incorporated in the elastomer to improve the physical properties of the elastomer. The plasticizing agent is represented by the formulaR--[O--CH.sub.2 --CH.sub.2 ].sub.n --O--[CH(V)]m--CH(Y)--O--ZwhereinR=HO--CH(X)--C(O)X=H.sub.3 or HY=H or CH.sub.3 or CH.sub.2 OH or CH.sub.2 OR or CH.sub.2 OW or CH.sub.3 CH.sub.2Z=H or R or WW=CH.sub.3 --[CH.sub.2 ].sub.1 --[CH.dbd.C].sub.p --C(O)V=H or CH.sub.3n=0 or 2m=1 to 31=4 to 20p=0 to 31+2p=4 to 20.The acid ester plasticizer may be added either to the polyol reactant component, a prepolymer prepared from a polyol and an isocyanate, the curing agent for the prepolymer, the prepolymer and curing agent combination, or to a one shot system containing an isocyanate, a polyol and a curing catalyst capable of effecting cross-linking of the poly and isocyanate upon application of heat thereto.

    摘要翻译： 公开了由多元醇和异氰酸酯的组合制备的增塑聚氨酯弹性体，其中将足够数量的羟基多元醇增塑剂的α羟基酸酯引入到弹性体中以改善弹性体的物理性能。 增塑剂由式R- [O-CH 2 -CH 2] n O- [CH（V）] m -CH（Y）-OZ表示，其中R = HO-CH（X）-C（O）X = H3 或HY = H或CH 3或CH 2 OH或CH 2 OR或CH 2 O或CH 3 CH 2 Z = H或R或WW = CH 3 - [CH 2] 1 - [CH = C] p C（O）V = H或CH 3 n = 0或2 m = 1至3 1 = 4至20 p = 0至3 1 + 2p = 4至20.酸酯增塑剂可以加入到多元醇反应物组分中，由多元醇和异氰酸酯制备的预聚物， 预聚物，预聚物和固化剂组合，或含有异氰酸酯，多元醇和固化催化剂的一次性体系，其能够在施加热量时实现聚异氰酸酯与异氰酸酯的交联。

    Process for the preparation of optionally cellular polyurethane polyurea molded parts
    56.
    发明授权
    Process for the preparation of optionally cellular polyurethane polyurea molded parts 失效
    制备任选细胞聚氨酯聚脲模制件的方法

    公开(公告)号：US4595705A

    公开(公告)日：1986-06-17

    申请号：US700758

    申请日：1985-02-13

    申请人： Frank Werner ,  Matthias Marx ,  Peter Horn ,  Hans U. Schmidt

    发明人： Frank Werner ,  Matthias Marx ,  Peter Horn ,  Hans U. Schmidt

    IPC分类号： C08G18/32 ,  C08G18/40 ,  C08G18/65 ,  C08G18/14 ,  C08G18/30

    CPC分类号： C08G18/6529 ,  C08G18/3221 ,  C08G18/4009 ,  C08G18/4018 ,  C08G2101/0033 ,  C08G2120/00 ,  Y10T428/249989

    摘要： The invention relates to a one-shot process for the preparation of cellular or noncellular polyurethane polyurea parts having a modulus of flexural elasticity greater than 600 N/mm.sup.2 and densities of from 0.8 to 1.2 g/cm.sup.3 using the reaction injection molding technique, by reacting organic polyisocyanates, a polyol component, aromatic diamines, additional chain extenders and/or cross-linking agents in the presence of catalysts and optionally blowing agents, auxiliaries and/or additives, wherein the polyol component is a mixture containing(i) from 95 to 60 percent by weight of at least one compound selected from the group consisting of polyols, polyether polyamines, polyesteramides, and their mixtures having functionalities of from 2 to 6 and a molecular weight of from 1000 to 8000 and(ii) from 5 to 40 percent by weight of a least one aromatic and/or aromatic-aliphatic polyester polyol having a functionality of from 2 to 3 and a molecular weight of from 254 to 700, wherein the percents by weight are based on the total weight of the polyol component.

    摘要翻译： 本发明涉及使用反应注射成型技术制备具有大于600N / mm2的弯曲弹性模量和0.8至1.2g / cm 3的密度的细胞或非细胞聚氨酯聚脲部件的一步法，通过使 有机多异氰酸酯，多元醇组分，芳族二胺，另外的增链剂和/或交联剂，在催化剂和任选的发泡剂，助剂和/或添加剂的存在下，其中多元醇组分是含有（i）95至 60重量％的至少一种选自多元醇，聚醚多胺，聚酯酰胺及其混合物的至少一种化合物，其官能度为2至6，分子量为1000至8000，（ii）5至40％ 的至少一种官能度为2至3且分子量为254至700的至少一种芳族和/或芳族 - 脂族聚酯多元醇，其中百分比 基于多元醇组分的总重量。

    Polyol blend and polyisocyanurate foam produced therefrom
    57.
    发明授权
    Polyol blend and polyisocyanurate foam produced therefrom 失效
    由此产生的多元醇共混物和聚异氰脲酸酯泡沫

    公开(公告)号：US4544679A

    公开(公告)日：1985-10-01

    申请号：US703849

    申请日：1985-02-21

    申请人： Richard B. Tideswell ,  Neil H. Nodelman ,  Barry A. Phillips

    发明人： Richard B. Tideswell ,  Neil H. Nodelman ,  Barry A. Phillips

    IPC分类号： C08G18/00 ,  C08G18/02 ,  C08G18/06 ,  C08G18/09 ,  C08G18/28 ,  C08G18/32 ,  C08G18/40 ,  C08G18/42 ,  C08G18/66 ,  C08G18/14 ,  C08G18/30 ,  C08G18/48 ,  C08G18/79

    CPC分类号： C08G18/3221 ,  C08G18/092 ,  C08G18/283 ,  C08G18/4018 ,  C08G18/4247 ,  C08G18/6644 ,  C08G2101/00 ,  C08G2101/0025 ,  C08G2101/005 ,  C08G2105/02 ,  C08G2170/60 ,  Y10S521/902 ,  Y10T428/249991 ,  Y10T428/31547

    摘要： The present invention is directed to a polyol blend comprising:(a) from about 30 to about 90 percent by weight of a polyester diol having an OH number of from about 50 to about 500 and having the structure: ##STR1## wherein each R may be the same or different and represents a radical of the formula: ##STR2## where R" represents H or CH.sub.3 with the proviso that both R"s cannot be CH.sub.3, and y represents a number of from 1 to 5,wherein R' represents an aromatic radical having from 6 to 12 carbon atoms, and wherein x represents a number of from 0 to 5,(b) from about 2 to about 40 percent by weight of an organic compound containing from 3 to 8 hydroxyl groups and being selected from the group consisting of(i) compounds having OH numbers of from about 250 to about 1830 and being free of carboxylic acid ester groups,(ii) compounds having OH numbers of from about 150 to about 1000 and containing at least one carboxylic acid ester group, and(iii) mixtures thereof,(c) from about 5 to about 30 percent by weight of a condensation product formed from 1 mole of a phenol and from 4 to 15 moles of ethylene oxide, and(d) from 0 to about 40 percent by weight of at least one diol of the structure: ##STR3## where R" and y are as defined above, and to an isocyanurate foam prepared therefrom.

    摘要翻译： 本发明涉及多元醇共混物，其包含：（a）约30至约90重量％的OH数为约50至约500的聚酯二醇，并具有以下结构：其中每个R可以 相同或不同，表示下式的基团：其中R“表示H或CH 3，条件是两个R'不能为CH3，y表示1至5的数，其中R “表示具有6至12个碳原子的芳族基团，其中x表示0至5的数，（b）约2至约40重量％的含有3至8个羟基的有机化合物，并且为 选自（i）具有约250至约1830的OH数的化合物和不含羧酸酯基的化合物，（ii）OH值为约150至约1000的化合物，并含有至少一种羧酸 酯基，和（iii）它们的混合物，（c）约5至约3 0重量％由1摩尔酚和4至15摩尔环氧乙烷形成的缩合产物，和（d）0至约40重量％的至少一种以下结构的二醇：其中 R“和y如上所定义，和由其制备的异氰脲酸酯泡沫。

    Polyol blends of phthalate/trimellitate esters for polyurethane-polyisocyanurate foams
    59.
    发明授权
    Polyol blends of phthalate/trimellitate esters for polyurethane-polyisocyanurate foams 失效
    用于聚氨酯 - 聚异氰脲酸酯泡沫的邻苯二甲酸酯/偏苯三酸酯的多元醇共混物

    公开(公告)号：US4526908A

    公开(公告)日：1985-07-02

    申请号：US619134

    申请日：1984-06-14

    申请人： George Magnus ,  Norman Smith ,  Bonnie Keyes

    发明人： George Magnus ,  Norman Smith ,  Bonnie Keyes

    IPC分类号： C08G18/32 ,  C08G18/42 ,  C08G18/14

    CPC分类号： C08G18/4208 ,  C08G18/3221 ,  C08G2105/02

    摘要： Homogenous liquid polyol blend compositions containing (a) certain aliphatic polyols, (b) phthalate diester polyols of said aliphatic polyols, and (c) trimellitate polyols of said aliphatic polyols. Such polyol blend compositions are useful in making homogenous liquid resin prepolymer blends compositions containing, in addition to such a polyol blend, fluorocarbon blowing agent, cell stabilizing surfactant, and urethane and/or isocyanurate catalyst. Such a resin prepolymer blend composition is suitable for reaction with organic isocyanates to produce cellular polyurethane and/or polyisocyanurate polymers.

    摘要翻译： 含有（a）某些脂族多元醇，（b）所述脂族多元醇的邻苯二甲酸二酯多元醇和（c）所述脂族多元醇的偏苯三酸酯多元醇的均匀液体多元醇共混物组合物。 这种多元醇共混物组合物可用于制备均匀的液体树脂预聚物共混物组合物，其包含除了这种多元醇共混物，氟碳发泡剂，细胞稳定表面活性剂和氨基甲酸酯和/或异氰脲酸酯催化剂之外。 这种树脂预聚物共混物组合物适于与有机异氰酸酯反应以产生多孔聚氨酯和/或聚异氰脲酸酯聚合物。

    Water-dispersible urethane polymers, aqueous polymer dispersions and half-esters useful therein
    60.
    发明授权
    Water-dispersible urethane polymers, aqueous polymer dispersions and half-esters useful therein 失效
    水分散性聚氨酯聚合物，聚合物水分散体和在其中有用的半酯

    公开(公告)号：US4329490A

    公开(公告)日：1982-05-11

    申请号：US141983

    申请日：1980-04-21

    申请人： Roy C. Williams ,  David R. Rogemoser

    发明人： Roy C. Williams ,  David R. Rogemoser

    IPC分类号： C08G18/08 ,  C08G18/32 ,  C07C69/76

    CPC分类号： C08G18/0823 ,  C08G18/3221

    摘要： Aqueous dispersions of oil-modified, carboxyl-containing, urethane polymers are prepared by reacting diisocyanates or their isocyanate-terminated prepolymers, with half-esters of hindered diols, especially 2,2,4-trimethyl-1,3-pentanediol, and anhydrides of polycarboxylic acids, preferably aromatic acids having at least three carboxylic groups, especially trimellitic anhydride. The urethane polymers are "oil-modified", i.e., extended with unsaturated fatty acid esterpolyols; and when neutralized with ammonia or amines can be dispersed in water to form especially desirable coating compositions. An organic phosphite may be incorporated in the compositions to control the development of hardness in films made from the aqueous dispersions and thereby avoid the formation of wrinkles in films that are made from the compositions.

    摘要翻译： 油改性的含羧基聚氨酯聚合物的水分散体是通过二异氰酸酯或其异氰酸酯封端的预聚物与受阻二醇的半酯，特别是2,2,4-三甲基-1,3-戊二醇和酸酐 的多羧酸，优选具有至少三个羧基的芳族酸，特别是偏苯三酸酐。 氨基甲酸酯聚合物是“油改性的”，即用不饱和脂肪酸酯多元醇延伸; 并且当用氨或胺中和时可以分散在水中以形成特别理想的涂料组合物。 可以在组合物中引入有机亚磷酸酯以控制由水性分散体制成的膜中的硬度的发展，从而避免在由组合物制成的膜中形成褶皱。