公开(公告)号：US4786713A

公开(公告)日：1988-11-22

申请号：US117722

申请日：1987-11-06

Applicant: Mark Rule ,  David R. Fagerburg ,  Joseph J. Watkins ,  Jerry S. Fauver

Inventor： Mark Rule ,  David R. Fagerburg ,  Joseph J. Watkins ,  Jerry S. Fauver

IPC: C08G75/02 ,  C08G75/14

CPC classification number: C08G75/0236 ,  C08G75/0222 ,  C08G75/0227 ,  C08G75/0263 ,  C08G75/0295 ,  C08G75/14

Abstract: A copoly(arylene sulfide) corresponding to the structure[(--A--S--).sub.1-x (--A--S--S--).sub.x ].sub.nwherein x is in the range of 0.5 to 0.001 prepared by reacting a mixture of a diiodoaromatic compound and elemental sulfur.

Abstract translation: 对应于[（-A-S-）1-x（-A-S-S-）x] n结构的共聚（亚芳基硫醚），其中x在0.5至0.001的范围内，通过使二碘芳族化合物和元素硫的混合物反应制备。

公开(公告)号：US4778940A

公开(公告)日：1988-10-18

申请号：US29897

申请日：1987-03-25

Applicant: Mark Rule ,  Gerald C. Tustin ,  Donald W. Lane ,  Thomas H. Larkins

Inventor： Mark Rule ,  Gerald C. Tustin ,  Donald W. Lane ,  Thomas H. Larkins

IPC: C07D215/18 ,  B01J29/08 ,  C07B31/00 ,  C07B39/00 ,  C07B61/00 ,  C07C17/00 ,  C07C17/15 ,  C07C17/156 ,  C07C17/158 ,  C07C25/00 ,  C07C25/02 ,  C07C25/18 ,  C07C25/22 ,  C07C37/62 ,  C07C41/00 ,  C07C41/22 ,  C07C43/29 ,  C07C45/00 ,  C07C45/63 ,  C07C49/813 ,  C07C67/00 ,  C07C313/00 ,  C07C317/14 ,  C07C319/20 ,  C07C323/09 ,  C07D213/00 ,  C07D213/61 ,  C07D217/22 ,  C07D333/00 ,  C07D521/00

CPC classification number: C07C253/30 ,  C07B39/00 ,  C07C17/156 ,  C07C17/158 ,  C07C37/62 ,  C07C45/63 ,  C07D213/61

Abstract: A process for iodinating an aromatic compound in which a source of iodine is reacted with the aromatic compound in the presence of oxygen over a non-acid catalyst wherein the aromatic compound has a fluoro, chloro, bromo, iodo, hydroxy or cyano group.

Abstract translation: 将碘源与芳族化合物在氧气存在下与非酸性催化剂进行碘化的芳族化合物的方法，其中芳族化合物具有氟，氯，溴，碘，羟基或氰基。

公开(公告)号：US4654436A

公开(公告)日：1987-03-31

申请号：US887488

申请日：1986-07-21

Applicant: Donald W. Lane ,  Thomas H. Larkins, Jr. ,  Mark Rule

Inventor： Donald W. Lane ,  Thomas H. Larkins, Jr. ,  Mark Rule

IPC: C07C51/10 ,  C07C67/36

CPC classification number: C07C51/10 ,  C07C67/36

Abstract: This invention relates to a novel carbonylation process for the production of aromatic carboxylic acids or esters of aromatic. More particularly, this invention relates to a process for the carbonylation of aromatic iodides or bromides with carbon monoxide in the presence of a palladium catalyst promoted with a Group VIB carbonyl and in the presence of an alcohol or water in a base reaction medium having a pKa greater than about 8. When the alcohol is used the product is the ester. When water is used the product is the carboxylic acid.

Abstract translation: 本发明涉及用于生产芳族羧酸或芳香族酯的新型羰基化方法。 更具体地说，本发明涉及在用VIB羰基化合物促进的钯催化剂存在下，在醇或水存在下，在具有pKa的碱性反应介质中，用一氧化碳羰基化芳族碘化物或溴化物的方法 大于约8.当使用醇时，产物是酯。 当使用水时，产物是羧酸。

公开(公告)号：US4391985A

公开(公告)日：1983-07-05

申请号：US321948

申请日：1981-11-16

Applicant: Richard J. Hook ,  Mark Rule

Inventor： Richard J. Hook ,  Mark Rule

IPC: C07C51/42 ,  C07C51/16

CPC classification number: C07C51/42

Abstract: The present invention provides a process whereby by-product isophthalic acid is easily removed from terephthalic acid. The process thus provides a terephthalic acid product of improved purity. The process involves cooling at least a portion of a hot acetic acid production stream from which precipitated terephthalic acid has been removed so as to precipitate at least a portion of the isophthalic acid dissolved therein. The precipitated isophthalic acid is then removed and the production stream is recycled to a reactor from the production of terephthalic acid. The total production stream is thereby rendered unsaturated in isophthalic acid. Following the reaction in the terephthalic acid reactor, pure terephthalic acid in the substantial absence of isophthalic acid is recovered from the production stream as a precipitate. In a preferred embodiment, the cooling step involves cooling about 15 to 75%, and, at times, perhaps up to 100%, of the total hot acetic acid production stream to a temperature below about 50.degree. C.

Abstract translation: 本发明提供了一种方法，其中副产物间苯二甲酸容易从对苯二甲酸中除去。 因此该方法提供了改进纯度的对苯二甲酸产物。 该方法包括冷却至少一部分已经除去沉淀的对苯二甲酸的热乙酸生产物流，以使至少一部分溶解在其中的间苯二甲酸沉淀。 然后除去沉淀的间苯二甲酸，并从生产对苯二甲酸将生产流循环到反应器中。 总生产物流在间苯二甲酸中变得不饱和。 在对苯二甲酸反应器中反应后，基本上不存在间苯二甲酸的纯对苯二甲酸作为沉淀物从生产物流中回收。 在优选的实施方案中，冷却步骤包括将总热乙酸生产流的约15至75％，有时可能高达100％，冷却至低于约50℃的温度。

公开(公告)号：US08552099B2

公开(公告)日：2013-10-08

申请号：US13471683

申请日：2012-05-15

Applicant: Anthony Jarvis ,  Mark Frost ,  Mark Rule

Inventor： Anthony Jarvis ,  Mark Frost ,  Mark Rule

IPC: C08K3/00 ,  C08L67/00

CPC classification number: C08L67/02 ,  B29B2911/1402 ,  B29B2911/14026 ,  B29B2911/14033 ,  B29B2911/1404 ,  B29B2911/14106 ,  B29B2911/14133 ,  B29C49/0005 ,  B29C49/06 ,  B29C51/002 ,  B29C2035/0822 ,  B29K2025/00 ,  B29K2033/08 ,  B29K2067/00 ,  B29K2069/00 ,  B29K2077/00 ,  B29K2105/16 ,  C08K3/01 ,  Y10T428/1321 ,  C08L2666/54

Abstract: A polymer additive for improving the reheat characteristics of a polymer or polymeric composition comprises an inorganic material which is such that a 2.5 mm thick polyethylene terephthalate plaque incorporating the inorganic material has, when tested, an absorption ratio of less than 0.9, wherein the absorption ratio is either the ratio of A1/A2 or the ratio A1/A3, wherein: A1 is the maximum absorption between 400 nm and 550 nm; A2 is the maximum absorption between 700 to 1100 nm; A3 is the maximum absorption between 700 to 1600 nm. Preferred inorganic materials are titanium nitride, indium tin oxide and lanthanum hexaboride.

Abstract translation: 用于改善聚合物或聚合物组合物的再热特性的聚合物添加剂包括无机材料，其使得当测试时，包含无机材料的2.5mm厚的聚对苯二甲酸乙二醇酯板具有小于0.9的吸收比，其中吸收比 是A1 / A2的比例或A1 / A3比，其中：A1是400nm和550nm之间的最大吸收; A2是700至1100nm之间的最大吸收; A3是700至1600nm之间的最大吸收。 优选的无机材料是氮化钛，氧化铟锡和六硼化镧。

公开(公告)号：US08445086B2

公开(公告)日：2013-05-21

申请号：US12519444

申请日：2007-12-19

Applicant: Mark Frost ,  Mark Rule

Inventor： Mark Frost ,  Mark Rule

IPC: B29D22/00

CPC classification number: C08J3/226 ,  C08J3/203 ,  C08J2367/02 ,  C08J2467/00 ,  C08K3/28 ,  C23C14/0036 ,  C23C14/0641 ,  C23C14/35 ,  Y10T428/1352 ,  Y10T428/1397 ,  Y10T428/2982 ,  C08L67/02

Abstract: Polymer compositions, for example of polyethyleneterephthalate bottles or preforms, include a reheat additive which has reducing transmission/increasing absorbance across the IR region as the wavelength increases. The reheat additive may be a titanium nitride, made by a plasma vapor deposition technique. Advantageously, the material may be used at a lower level than hitherto known materials or may be used at the same levels as hitherto but provide a greater reheat effect. Example 3a shown in the figure illustrates the absorbance of a preferred material.

Abstract translation: 聚合物组合物，例如聚对苯二甲酸乙二醇酯瓶或预型件，包括再加热添加剂，随着波长的增加，其具有降低的透射/增加的IR区域的吸光度。 再加热添加剂可以是通过等离子体气相沉积技术制成的氮化钛。 有利地，该材料可以比迄今为止已知的材料更低的水平使用，或者可以以与迄今相同的水平使用，但是提供更大的再热效果。 图中所示的实施例3a示出了优选材料的吸光度。

公开(公告)号：US07820781B2

公开(公告)日：2010-10-26

申请号：US10599403

申请日：2005-03-30

Applicant: Anthony Jarvis ,  Mark Frost ,  Mark Rule

Inventor： Anthony Jarvis ,  Mark Frost ,  Mark Rule

IPC: C08K3/22 ,  C08J3/20 ,  C08L67/00 ,  B29C49/00

CPC classification number: C08L67/02 ,  B29B2911/1402 ,  B29B2911/14026 ,  B29B2911/14033 ,  B29B2911/1404 ,  B29B2911/14106 ,  B29B2911/14133 ,  B29C49/0005 ,  B29C49/06 ,  B29C51/002 ,  B29C2035/0822 ,  B29K2025/00 ,  B29K2033/08 ,  B29K2067/00 ,  B29K2069/00 ,  B29K2077/00 ,  B29K2105/16 ,  C08K3/01 ,  Y10T428/1321 ,  C08L2666/54

Abstract: A polymer additive for improving the reheat characteristics of a polymer or polymeric composition comprises an inorganic material which is such that a 2.5 mm thick polyethylene terephthalate plaque incorporating the inorganic material has, when tested, an absorption ratio of less than 0.9, wherein the absorption ratio is either the ratio of A1/A2 or the ratio A1/A3, wherein: A1 is the maximum absorption between 400 nm and 550 nm; A2 is the maximum absorption between 700 to 1100 nm; A3 is the maximum absorption between 700 to 1600 nm. Preferred inorganic materials are titanium nitride, indium tin oxide and lanthanum hexaboride.

Abstract translation: 用于改善聚合物或聚合物组合物的再热特性的聚合物添加剂包括无机材料，其使得当测试时，包含无机材料的2.5mm厚的聚对苯二甲酸乙二醇酯板具有小于0.9的吸收比，其中吸收比 是A1 / A2的比例或A1 / A3比，其中：A1是400nm和550nm之间的最大吸收; A2是700至1100nm之间的最大吸收; A3是700至1600nm之间的最大吸收。 优选的无机材料是氮化钛，氧化铟锡和六硼化镧。

公开(公告)号：US20070020422A1

公开(公告)日：2007-01-25

申请号：US11527005

申请日：2006-09-26

Applicant: Mark Rule

Inventor： Mark Rule

IPC: B65D1/02

CPC classification number: C08K5/0091 ,  C08K5/5317 ,  C08L67/02 ,  C09K15/32 ,  Y10T428/1397

Abstract: Methods to decrease aldehyde content of a polymer are provided. An effective amount of an additive that contains a P—H functionality is incorporated into the polymer in the presence of an acidic of basic catalyst compositions are also provided.

公开(公告)号：US06911523B2

公开(公告)日：2005-06-28

申请号：US10621636

申请日：2003-07-17

Applicant: Mark Rule

Inventor： Mark Rule

IPC: C08G63/183 ,  C08K3/22 ,  C08F6/00

CPC classification number: C08K3/22 ,  C08G63/183 ,  Y10S220/906 ,  Y10T428/1352

Abstract: A method to decrease an aldehyde content of a polyester. The method comprises incorporating an effective amount of an additive that is capable of catalyzing a hydride-transfer reaction between an organic donor molecule and an aldehyde in the polyester.

Abstract translation: 降低聚酯醛含量的方法。 该方法包括加入有效量的能够在聚酯中催化有机供体分子和醛之间的氢化物转移反应的添加剂。

公开(公告)号：US20050118371A1

公开(公告)日：2005-06-02

申请号：US10967803

申请日：2004-10-18

Applicant: Yu Shi ,  Mark Rule ,  Christopher Kjorlaug ,  Linda Anthony ,  Thomas Milton

Inventor： Yu Shi ,  Mark Rule ,  Christopher Kjorlaug ,  Linda Anthony ,  Thomas Milton

IPC: B29C49/00 ,  B29C49/06 ,  B65D1/02 ,  C08G63/183 ,  C08G63/672 ,  B65D1/00

CPC classification number: B65D1/0207 ,  B29B2911/1402 ,  B29B2911/14026 ,  B29B2911/14033 ,  B29B2911/1404 ,  B29B2911/14106 ,  B29B2911/14133 ,  B29B2911/14593 ,  B29B2911/14653 ,  B29B2911/14713 ,  B29B2911/14906 ,  B29B2911/1498 ,  B29B2911/14986 ,  B29C49/0005 ,  B29C49/06 ,  B29K2067/00 ,  B29K2105/253 ,  B29K2667/00 ,  B29K2995/0017 ,  B29K2995/004 ,  B29K2995/0041 ,  B29K2995/0067 ,  B29K2995/0077 ,  B29L2031/565 ,  B29L2031/7158 ,  C08G63/183 ,  C08G63/672 ,  Y10T428/1352

Abstract: A container is made from a preform comprising a PET Copolymer comprising a diol component having repeat units from ethylene glycol and a non-ethylene glycol diol component and a diacid component having repeat units from terephthalic acid and a non-terephthalic acid diacid component. The total amount of non-ethylene glycol diol component and non-terephthalic acid diacid component is present in the poly(ethylene terephthalate) copolymer in an amount from about 0.2 mole percent to less than 2.2 mole percent. The container is useful in packaging beverages and corresponding methods are disclosed.

Abstract translation: 容器由包含PET共聚物的PET共聚物制成，所述PET共聚物包含具有来自乙二醇和非乙二醇二醇组分的重复单元的二醇组分和具有来自对苯二甲酸和非对苯二甲酸二酸组分的重复单元的二酸组分。 聚对苯二甲酸乙二醇酯共聚物中非乙二醇二醇组分和非对苯二甲酸二酸组分的总量以约0.2摩尔％至小于2.2摩尔％的量存在。 该容器在包装饮料中是有用的，并且公开了相应的方法。