摘要:
Process for manufacturing chlorolactones by reacting, within an ahydrous organic solvent, a metal N-chlorosulfonamidate of the formula ##STR1## wherein R is a hydrogen or halogen atom or an alkyl radical, Ar is a mono- or polycyclic divalent aromatic radical and M is an alkali metal, with a substantially stoichiometrical proportion of an aliphatic or alicyclic carboxylic acid having at least one double bond separated from the COOH group by at least 2 carbon atoms, in the presence of a substantially stoichiometrical amount of a strong acid whose conjugate base is weakly nucleophilic.
摘要:
An improved catalytic composition for oligomerization, in particular dimerization, of monoolefins comprises the product resulting from bringing the following three constituents into contact in any order: a) at least one divalent nickel compound; b) at least one hydrocarbylaluminium dihalide, optionally enriched with an aluminum trihalide; and c) at least one organic Bronsted acid; the catalytic composition being pre-conditioned in a solvent before using it for oligomerization.
摘要:
The invention concerns a process for preparing a hybrid organic-inorganic material (HOIM) with phosphorus-containing bridges between the surface of an inorganic substrate containing an element M and one or more organic groups of the covalent M-O-P-R type, said process using, as a precursor for said organic group or groups, at least one organophosphorus acid halide with formula RxP(O)Xy in which x=1 or 2, y=3−x, X being a halogen and R designating at least one organic alkyl, aryl or aryl-alkyl group.Non-exhaustive applications for the hybrid organic-inorganic material obtained by the process of the invention are in the fields of anti-corrosion, lubrication, microelectronics, nanotechnologies, composite materials, heterogeneous catalysis, supported catalysis, depollution and biomedical applications.
摘要:
Process for desulfurization of an effluent for cracking or steam-cracking hydrocarbons, more particularly a gasoline for example for catalytic cracking that comprises the elimination of thiophenic compounds by alkylation of these compounds, followed by a distillation, a hydrocracking of said alkyl-thiophenic compounds, then a hydrodesulfurization of the effluent that is obtained from the hydrocracking zone. In a preferred embodiment, this process comprises a preliminary stage for separating the cracking or steam-cracking effluent into three fractions, and proposes sending to the alkylation stage only the intermediate fraction that is low in heavy basic nitrogen-containing compounds that are initially present in the effluents that are to be alkylated.
摘要:
An improved catalytic composition for oligomerization, in particular dimerization, of monoolefins comprises the product resulting from bringing the following three constituents into contact in any order: a) at least one divalent nickel compound; b) at least one hydrocarbylaluminium dihalide, optionally enriched with an aluminium trihalide; and c) at least one organic Bronsted acid; the catalytic composition being pre-conditioned in a solvent before using it for oligomerization.
摘要:
The invention relates to a method for pretreatment of a solid catalyst that is obtained by a reaction between an inorganic binder and phosphoric acid, whereby said method comprises a stage in which said catalyst is brought into contact with a mixture of hydrocarbons under swelling conditions of the catalyst up to a predetermined volume increase, with no significant volume constraint on said catalyst. The invention also relates to an operating process of said catalyst in an alkylation or oligomerization reactor.
摘要:
A process is described for the valorization of a charge of hydrocarbons and for reducing the vapour pressure of said charge, comprising three steps: a step a) consisting of separating said charge of hydrocarbons into a fraction (O1) comprising essentially compounds containing 5 carbon atoms, including at least 2% by weight of pentenes, a step b) consisting of placing said fraction (O1) in contact with a cut of hydrocarbons (O2) at least partly comprising hydrocarbons having a number of carbon atoms between 6 and 10, including at least 2% by weight of olefins, and a step c) consisting of separating the effluents originating from step b) into a gasoline cut (α) the upper distillation point of which is less than 100° C. and a kerosene cut (β) having a distillation range between 100° C. and 300° C.
摘要:
An improved catalytic composition for oligomerization, in particular dimerization, of monoolefins comprises the product resulting from bringing the following three constituents into contact in any order: a) at least one divalent nickel compound; b) at least one hydrocarbylaluminium dihalide, optionally enriched with an aluminium trihalide; and c) at least one organic Bronsted acid; the catalytic composition being pre-conditioned in a solvent before using it for oligomerization.
摘要:
The present invention relates to a process for continuous metathesis or disproportionation of olefins, comprising at least 2 phases, a reaction phase a) carried out in a zone comprising at least one reactor containing at least one fixed bed of catalyst and a regeneration phase b) carried out in a zone comprising at least one reactor containing at least one fixed bed of catalyst, characterized in that at least one reactor passes from one phase to the other in alternation. In FIG. 1, the feed containing olefins traverses reactor R1 in riser mode. The feed to be treated containing olefins is introduced into reactor R1 via line 1a. In this reactor, the olefins contained in the feed undergo metathesis or disproportionation, then the effluent leaves the circuit via line 11. Simultaneously, reactor R2 is placed in catalyst regeneration phase, the different regeneration gases are introduced into reactor R2 via line 2b and leave this reactor via line 2c. Passage from the operating phase of a reactor to the catalyst regeneration phase thereof is carried out as follows: the reactor for which the catalyst is to be regenerated is isolated from the remainder of the apparatus, the hydrocarbons contained in the reactor are evacuated, then the reactor is purged. Said reactor is then connected to a regeneration loop and undergoes regeneration of its catalyst, and at the end of the regeneration phase, the reactor and the regeneration loop are purged.
摘要:
For obtaining butene-1 from butene-2, a charge containing at least one of the isomers of butene-2 is introduced into a distillation zone linked to a hydro-isomerization zone. Part of the effluent from the bottom of the distillation column is removed from the distillation zone, heated in a heat exchanger and passed into an external hydro-isomerization zone. The hydro-isomerization effluent is removed from the hydro-isomerization zone, cooled in a heat exchanger, and then reintroduced into the distillation zone. Effluent containing butene-1 is withdrawn from the top of the column of the distillation zone.