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61.发明申请Process for the production of 2-hydroxy-4-methythiobutyric acid ammonium salt 有权2-羟基-4-亚甲基丁酸铵盐的制备方法公开(公告)号：US20060178529A1
公开(公告)日：2006-08-10
申请号：US10547280
申请日：2004-03-26
IPC分类号： C07C319/12
CPC分类号： C07C319/20 , C07C323/60 , C07C323/52
摘要： The invention relates to a process for the production of 2-hydroxy-4-methylthiobutyric acid ammonium salt from 2-hydroxy-4-methylthiobutyronitrile, and to the use of the 2-hydroxy-4-methylthiobutyric acid ammonium salt produced by this process.
摘要翻译： 本发明涉及由2-羟基-4-甲硫基丁腈生产2-羟基-4-甲硫基丁酸铵盐的方法，以及由该方法生产的2-羟基-4-甲硫基丁酸铵盐的用途。
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公开(公告)号：US20060063238A1
公开(公告)日：2006-03-23
申请号：US11056165
申请日：2005-02-14
CPC分类号： C12P13/04 , C12N9/0016 , C12N9/0024 , C12N9/0065 , C12P13/06 , C12P13/12
摘要： The invention relates to recombinant microorganisms which, in comparison to the starting organism, have a higher concentration or activity of a D-amino acid oxidase, of an L-amino acid dehydrogenase, of an NADH cosubstrate regenerating enzyme and, if necessary, of a catalase. The invention also includes methods for preparing L-amino acids from D-amino acids using of these microorganisms.
摘要翻译： 本发明涉及重组微生物，其与起始生物体相比，具有较高浓度或活性的L-氨基酸脱氢酶，NADH辅助底物再生酶，以及必要时具有 过氧化氢酶。 本发明还包括使用这些微生物从D-氨基酸制备L-氨基酸的方法。
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公开(公告)号：US20060030739A1
公开(公告)日：2006-02-09
申请号：US11198609
申请日：2005-08-05
申请人： Frank Dubner , Christoph Weckbecker
发明人： Frank Dubner , Christoph Weckbecker
IPC分类号： C07C319/18
CPC分类号： C07C319/20 , C07C319/18 , C07C323/22 , C07C323/60
摘要： A method for preparing 3-(methylthio)propanal and 2-hydroxy-4-(methylthio)butanenitrile by catalyzed addition of methylmercaptan to acrolein and hydrogen cyanide to 3-(methylthio)propanal.
摘要翻译： 通过催化将甲硫醇加入丙烯醛和氰化氢至3-（甲硫基）丙醛来制备3-（甲硫基）丙醛和2-羟基-4-（甲硫基）丁腈的方法。
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64.发明授权Process for the preparation of alpha-amino acids by hydrolysis of hydantoins at elevated pressure and elevated temperature 有权通过在升高的压力和升高的温度下水解乙内酰脲来制备α-氨基酸的方法公开(公告)号：US06797827B2
公开(公告)日：2004-09-28
申请号：US10630094
申请日：2003-07-30
申请人： Martin Körfer , Dieter Buss , Horst Weigel , Christoph Weckbecker , Hans Joachim Hasselbach , Klaus Huthmacher
发明人： Martin Körfer , Dieter Buss , Horst Weigel , Christoph Weckbecker , Hans Joachim Hasselbach , Klaus Huthmacher
IPC分类号： C07D23386
CPC分类号： C07C319/20 , C07C227/24 , C07C323/58 , C07C229/08 , C07C229/36
摘要： A process for the preparation of &agr;-amino acids by hydrolysis of hydantoins in the presence of water and at least one metallic oxide under conditions such that all the starting materials are completely dissolved in the water as a result of high pressure and high temperature and only one further phase is present in the reactor in addition to the metallic oxide phase.
摘要翻译： 一种在水和至少一种金属氧化物的存在下水解乙内酰脲来制备α-氨基酸的方法，使得所有起始物质由于高压和高温而完全溶解在水中，只有在 除了金属氧化物相之外，在反应器中还存在一个相。
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公开(公告)号：US06475370B2
公开(公告)日：2002-11-05
申请号：US09931165
申请日：2001-08-17
IPC分类号： C25B300
CPC分类号： C25B3/04
摘要： A process for the production of 2-hydroxy-4-methylmercaptobutyric acid (MHA) by electrochemical carboxylation of 3-methylmercapto-propionaldehyde in an undivided electrolytic cell containing a sacrificial anode, in an aprotic solvent in the presence of a supporting electrolyte. Preferred anode/cathode combinations are Mg/Mg and Mg/carbon. MHA is obtainable in a high yield.
摘要翻译： 在含有牺牲阳极的未分裂电解槽中，在非支质溶剂中，在支持电解质存在下，通过电化学羧化3-甲基巯基丙醛生产2-羟基-4-甲基巯基丁酸（MHA）的方法。 优选的阳极/阴极组合是Mg / Mg和Mg /碳。 MHA可以高产率获得。
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公开(公告)号：US09764309B2
公开(公告)日：2017-09-19
申请号：US14365801
申请日：2012-11-27
IPC分类号： B01J23/30 , C07C319/02 , B01J35/00 , B01J35/02 , B01J35/10 , B01J37/00 , C07C319/08 , B01J37/02
CPC分类号： B01J23/30 , B01J35/0026 , B01J35/023 , B01J35/1019 , B01J35/1042 , B01J37/0036 , B01J37/0205 , C07C319/02 , C07C319/08 , C07C321/04
摘要： The present invention relates to a catalyst which comprises a support material and an oxidic composition containing at least one alkali metal and tungsten, a process for producing such catalysts and also a process for preparing alkyl mercaptans by reaction of alkanols with hydrogen sulphide in the presence of such a catalyst.
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公开(公告)号：US09464045B2
公开(公告)日：2016-10-11
申请号：US14850207
申请日：2015-09-10
申请人： Martin Koerfer , Hans Joachim Hasselbach , Stefan Reichert , Harald Jakob , Christoph Weckbecker , Klaus Huthmacher , Horst Krull , Bernd Drapal , Rainer Peter
发明人： Martin Koerfer , Hans Joachim Hasselbach , Stefan Reichert , Harald Jakob , Christoph Weckbecker , Klaus Huthmacher , Horst Krull , Bernd Drapal , Rainer Peter
IPC分类号： C07C319/28 , C07C319/20 , C07C319/26 , C07C319/12 , C07C323/52
CPC分类号： C07C319/28 , C07C319/12 , C07C319/20 , C07C319/26 , C07C323/52 , Y02P20/142 , C07C323/58
摘要： This disclosure relates to a process for preparing D,L-methionine by feeding carbon dioxide to an aqueous potassium methioninate solution obtained by hydrolysis of 5-(2-methylmercaptoethyl)hydantoin, in order to precipitate out crude methionine, which is separated off and purified. In this process an aqueous solution of the separated-off crude methionine is purified by recrystallization from a solution containing potassium ions and also a crystallization additive. The crystallization additive is a nonionic or anionic surfactant, or a mixture of different nonionic or anionic surfactants. The recrystallization occurs by introducing a 60 to 110° C.-hot methionine solution into a 35 to 80° C.-warm methionine suspension, a temperature of which is lower than that of the introduced solution, such that the temperature of the methionine suspension being maintained between 35 and 80° C. during the addition. The crystallization additive is a sorbitan fatty acid ester or a mixture of different sorbitan fatty acid esters.
摘要翻译： 本公开涉及通过将二氧化碳供给到通过水解5-（2-甲基巯基乙基）乙内酰脲获得的甲硫氨酸钾水溶液以便沉淀出粗蛋氨酸的方法来制备D，L-甲硫氨酸，其分离和纯化 。 在该方法中，分离的粗甲硫氨酸的水溶液通过从含有钾离子的溶液和结晶添加剂中重结晶来纯化。 结晶添加剂是非离子或阴离子表面活性剂，或不同的非离子或阴离子表面活性剂的混合物。 通过将60〜110℃的甲硫氨酸溶液导入35〜80℃的甲硫氨酸悬浮液中，其温度低于引入的溶液的温度，使得甲硫氨酸悬浮液的温度 在添加期间保持在35和80℃之间。 结晶添加剂是脱水山梨糖醇脂肪酸酯或不同脱水山梨糖醇脂肪酸酯的混合物。
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公开(公告)号：US09078459B2
公开(公告)日：2015-07-14
申请号：US13616533
申请日：2012-09-14
IPC分类号： A23K1/18 , A23K1/16 , C07C319/20 , C07D241/08
CPC分类号： A23K1/1634 , A23K20/142 , A23K50/80 , C07C319/20 , C07D241/08 , Y02A40/818 , Y02P20/582 , C07C323/60
摘要： An animal feed mixture containing DL-methionyl-DL-methionine and salts thereof for animals kept in aquacultures is provided. Methods for preparing DL-methionyl-DL-methionine of formula (I) and methods to fractionate the diasteriomeric forms obtained are also provided.
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69.发明申请CATALYST FOR THE SYNTHESIS OF ALKYL MERCAPTANS AND PROCESS FOR PRODUCING IT 有权用于合成阿尔茨海默氏菌的催化剂及其生产工艺公开(公告)号：US20140357897A1
公开(公告)日：2014-12-04
申请号：US14365801
申请日：2012-11-27
IPC分类号： B01J23/30 , C07C319/02
CPC分类号： B01J23/30 , B01J35/0026 , B01J35/023 , B01J35/1019 , B01J35/1042 , B01J37/0036 , B01J37/0205 , C07C319/02 , C07C319/08 , C07C321/04
摘要： The present invention relates to a catalyst which comprises a support material and an oxidic composition containing at least one alkali metal and tungsten, a process for producing such catalysts and also a process for preparing alkyl mercaptans by reaction of alkanols with hydrogen sulphide in the presence of such a catalyst.
摘要翻译： 本发明涉及一种催化剂，其包括载体材料和含有至少一种碱金属和钨的氧化组合物，制备这种催化剂的方法，还涉及通过链烷醇与硫化氢在存在下反应制备烷基硫醇的方法 这样的催化剂。
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70.发明授权Mo containing catalyst, a preparation method and a method for preparing methyl mercaptan 有权含钼催化剂，制备方法和制备甲硫醇的方法公开(公告)号：US08883670B2
公开(公告)日：2014-11-11
申请号：US12439926
申请日：2007-05-25
申请人： Yiquan Yang , Aiping Chen , Qi Wang , Jan-Olaf Barth , Christoph Weckbecker , Klaus Huthmacher
发明人： Yiquan Yang , Aiping Chen , Qi Wang , Jan-Olaf Barth , Christoph Weckbecker , Klaus Huthmacher
IPC分类号： B01J27/057 , B01J21/04 , B01J21/08 , B01J39/14 , B01J23/28 , B01J37/02 , B01J23/887 , C07C319/02 , B01J35/00 , B01J37/20
CPC分类号： B01J23/28 , B01J21/08 , B01J23/8872 , B01J27/0576 , B01J35/002 , B01J37/0201 , B01J37/0203 , B01J37/0205 , B01J37/20 , C07C319/02 , C07C321/04
摘要： A method is described to prepare a Mo containing supported catalyst comprising TeO2 as active promoter and a process for preparing methanethiol in the presence of said catalyst.
摘要翻译： 描述了一种制备包含TeO 2作为活性促进剂的Mo载体催化剂的方法和在所述催化剂存在下制备甲硫醇的方法。
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