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公开(公告)号：US09382420B2
公开(公告)日：2016-07-05
申请号：US13542121
申请日：2012-07-05
IPC分类号： C08L71/08 , C09D177/00 , C08L77/10 , C08J7/04 , C09D177/10
CPC分类号： C08L71/08 , B33Y70/00 , C08J7/047 , C08J2377/00 , C08J2477/00 , C08L77/10 , C09D177/00 , C09D177/10 , Y10T428/2998
摘要： The invention relates to powder, comprising composite particles comprising core particles completely or partially coated with a precipitated first polymer, where the core particles comprise a second polymer which differs from the precipitated first polymer, and where the ratio of the d50 median diameter of the composite particles to the d50 median diameter of the core particles is 1.15 or greater. The invention further relates to processes of using the powders of the present invention to making moldings.
摘要翻译： 本发明涉及粉末，其包含复合颗粒，其包含完全或部分涂覆有沉淀的第一聚合物的芯颗粒，其中芯颗粒包含与沉淀的第一聚合物不同的第二聚合物，并且其中复合材料的d50中值直径 颗粒与核心颗粒的d50中值直径为1.15或更大。 本发明还涉及使用本发明的粉末来制造模制品的方法。
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公开(公告)号：US09057466B2
公开(公告)日：2015-06-16
申请号：US13128297
申请日：2009-10-07
CPC分类号： F16L11/083 , B29C47/0023 , C08L77/00 , C08L77/06 , C08L77/12 , C08L2205/02 , F16L9/147 , F16L11/06 , Y02P20/544 , Y10T137/0318 , C08L2666/20
摘要： A molding composition which comprises at least 50% by weight of the following constituents: a) from 0 to 99 parts by weight of polyamide, and b) from 1 to 100 parts by weight of polyamide elastomer, selected from the group of polyetheresteramide and polyetheramide, where the total of the parts by weight is 100 and where the molding composition comprises from 0 to 9% by weight of plasticizer, is used for the production of a molding for contact with a supercritical medium, and preferably for the production of an inner thermoplastics layer in a flexible pipe or rigid pipe, in which a supercritical medium is conveyed. Low or zero plasticizer content eliminates any significant occurrence of problems such as increased stiffness and longitudinal shrinkage.
摘要翻译： 一种模塑组合物，其包含至少50重量％的以下组分：a）0至99重量份的聚酰胺，和b）1至100重量份的选自聚醚酯酰胺和聚醚酰胺的聚酰胺弹性体 ，其中重量份的总量为100，并且其中模塑组合物包含0至9重量％的增塑剂，用于生产与超临界介质接触的模制品，并且优选用于生产内部 柔性管或刚性管中的热塑性塑料层，其中传送超临界介质。 低或零增塑剂含量消除了任何显着的问题，例如增加刚度和纵向收缩。
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63.发明授权Molding compound on the basis of a copolyamide containing terephthalic acid and trimethylhexamethylene diamine units 有权基于含有对苯二甲酸和三甲基六亚甲基二胺单元的共聚酰胺的成型化合物公开(公告)号：US08871862B2
公开(公告)日：2014-10-28
申请号：US13377949
申请日：2010-07-08
CPC分类号： C08G69/265 , C08L77/06
摘要： A molding compound, containing at least 30% by weight of a copolyamide, which is derived from the following monomers: a) 50 to 95 mole percent of the combination of a diamine, selected from the group consisting of 1,9-nonane diamine, 1,10-decane diamine, 1,11-undecane diamine and 1,12-dodecane diamine, and terephthalic acid, and b) 5 to 50 mole percent of the combination of a diamine, selected from the group consisting of 2,2,4-trimethylhexamethylene diamine, 2,4,4-trimethylhexamethylene diamine, and mixtures thereof, and terephthalic acid. The copolyamide is crystalline and has low water absorption.
摘要翻译： 含有至少30重量％的共聚酰胺的模制化合物，其衍生自以下单体：a）50-95摩尔％的二胺的组合，其选自1,9-壬二胺， 1,10-癸烷二胺，1,11-十一烷二胺和1,12-十二烷二胺和对苯二甲酸，以及b）5至50摩尔％的二胺的组合，其选自2,2， 4-三甲基六亚甲基二胺，2,4,4-三甲基六亚甲基二胺及其混合物和对苯二甲酸。 共聚酰胺是结晶的，吸水率低。
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64.发明授权Copolyamide powder and its preparation, use of copolyamide powder in a shaping process and mouldings produced from this copolyamide powder 有权共聚酰胺粉末及其制备方法，在成型工艺中使用共聚酰胺粉末，并由该共聚酰胺粉末制备成型品公开(公告)号：US08591797B2
公开(公告)日：2013-11-26
申请号：US12407065
申请日：2009-03-19
申请人： Sylvia Monsheimer , Maik Grebe , Stefan Altkemper , Sigrid Hessel-Geldmann , Franz-Erich Baumann , Kristiane Warnke , Heike Stemmer , Joachim Muegge , Michael Tuerke , Ulrich Simon
发明人： Sylvia Monsheimer , Maik Grebe , Stefan Altkemper , Sigrid Hessel-Geldmann , Franz-Erich Baumann , Kristiane Warnke , Heike Stemmer , Joachim Muegge , Michael Tuerke , Ulrich Simon
IPC分类号： B29C35/08
CPC分类号： C08G69/36 , B29C64/153 , B33Y70/00
摘要： A task often encountered in very recent times is the rapid provision of prototypes. Particularly suitable processes are those based on pulverulent materials and in which the desired structures are produced layer-by-layer through selective melting and solidification. The invention provides the constitution, production and use of a copolyamide powder which was produced using the following monomer units: a) laurolactam or ω-aminoundecanoic acid, and also b) dodecanedioic acid, and either c) decanediamine or dodecanediamine, in shaping processes, and also to moldings produced through a layer-by-layer process which selectively melts regions of a powder layer, using this specific powder. Once the regions previously melted layer-by-layer have been cooled and solidified, the molding can be removed from the powder bed. The moldless layer-by-layer processes for the production of components using the copolyamide powder result in simplified and more reliable conduct of the process and better recyclability.
摘要翻译： 最近经常遇到的任务是快速提供原型。 特别合适的方法是基于粉末材料的方法，其中通过选择性熔融和凝固逐层地制备所需的结构。 本发明提供了使用以下单体单元制备的共聚酰胺粉末的构成，生产和使用：a）月桂内酰胺或ω-氨基十一烷酸，以及b）十二烷二酸，和c）癸二胺或十二烷二胺在成型过程中， 并且还涉及通过使用该特定粉末选择性地熔化粉末层的区域的逐层方法制备的成型体。 一旦先前已经逐层熔化的区域已被冷却和固化，则可以从粉末床中除去模制物。 用于使用共聚酰胺粉末制备组分的无霉变的逐层方法导致方法的简化和更可靠的进行和更好的可再循环性。
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公开(公告)号：US08574697B2
公开(公告)日：2013-11-05
申请号：US12676752
申请日：2008-09-30
CPC分类号： B29C63/34 , B29C63/46 , B29K2077/00 , F16L55/1656 , Y10T29/49826 , Y10T428/139 , Y10T428/1393
摘要： In a method for the introduction of an inliner into a pipe or a pipeline, where the external diameter of the inliner is greater than the internal diameter of the pipe or of the pipeline, and where the action of an external force is used to reduce the cross section of the inliner prior to the introduction, the inliner is composed of a polyamide moulding composition which comprises at least 50% by weight of polyamide which is not PA11. The recovery behavior of said polyamides is similar to that of polyethylene usually used for this purpose.
摘要翻译： 在将内衬引入管道或管道的方法中，其中内衬的外径大于管道或管道的内径，并且其中使用外力的作用来减少 在引入之前内衬的横截面由内衬构成，该聚酰胺模塑组合物包含至少50重量％的不是PA11的聚酰胺。 所述聚酰胺的回收行为类似于通常用于该目的的聚乙烯的回收行为。
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公开(公告)号：US20130274435A1
公开(公告)日：2013-10-17
申请号：US13859896
申请日：2013-04-10
CPC分类号： C08G69/26 , B29C64/153 , B33Y70/00 , C08J3/124 , C08J3/14 , C08J2377/06 , C08L77/06
摘要： The present invention provides precipitated polymer powders based on a polyamide of the AABB type, obtained by the reprecipitation of the polyamides by at least partial dissolution followed by continuous cooling of the solution to below the precipitation temperature. The polyamides are prepared by polycondensation of diamines with dicarboxylic acids. The precipitated polyamides obtained are used in layer-by-layer shaping processes such as selective laser sintering.
摘要翻译： 本发明提供了基于AABB型聚酰胺的沉淀聚合物粉末，其通过至少部分溶解再次沉淀而获得，随后将溶液连续冷却至低于沉淀温度。 聚酰胺通过二胺与二羧酸的缩聚制备。 所得到的沉淀聚酰胺用于逐层成型方法如选择性激光烧结。
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公开(公告)号：US08535811B2
公开(公告)日：2013-09-17
申请号：US13150683
申请日：2011-06-01
申请人： Kirsten Luetzeler , Franz-Erich Baumann , Sonja Bollmann , Andreas Dowe , Roland Wursche , Georg Schaefer
发明人： Kirsten Luetzeler , Franz-Erich Baumann , Sonja Bollmann , Andreas Dowe , Roland Wursche , Georg Schaefer
CPC分类号： A63C5/124 , C08L77/02 , C08L77/06 , C08L2205/02 , C09D177/02 , C09D177/06 , Y10T428/13 , Y10T428/1352 , Y10T428/1386 , Y10T428/139 , Y10T428/26 , Y10T428/31562 , Y10T428/31725 , Y10T428/31728 , Y10T428/31732 , Y10T428/31739 , Y10T428/31765 , C08L77/00 , C08L2666/20
摘要： A polyamide molding composition which can be used for production of a printable or printed item contains a) at most 90 parts by weight of a polyamide obtained from a lactam or from an amino carboxylic acid having at least 10 carbon atoms; and b) from 10 to 100 parts by weight of PA1010, wherein a total of components a) and b) is 100 parts by weight.
摘要翻译： 可用于制造可印刷或印刷品的聚酰胺模塑组合物包含：a）至多90重量份由内酰胺获得的聚酰胺或具有至少10个碳原子的氨基羧酸; 和b）10-100重量份的PA1010，其中组分a）和b）的总量为100重量份。
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68.发明授权Process for producing ultrafine powders based on polyamides, ultrafine polyamide powders and their use 有权用于生产基于聚酰胺，超细聚酰胺粉末的超细粉末及其用途的方法公开(公告)号：US08232333B2
公开(公告)日：2012-07-31
申请号：US12089998
申请日：2006-10-12
CPC分类号： C08J3/12 , C08J3/128 , C08J3/14 , C08J2377/00 , C09D177/00 , Y10S524/904
摘要： Process for preparing ultrafine powders based on polyamides by contacting polyamides having a relative solution viscosity ηrel in the range from 1.5 to 2.0, measured in 0.5% m-cresol solution at 25° C., with an alcoholic medium in the presence of inorganic particles under the action of pressure and/or temperature to generate an at least partial solution, and then precipitating the polyamide from the at least partial solution, characterized in that a suspension of the inorganic particles suspended in the alcoholic medium is used. The resulting ultrafine polyamide powders have a specific BET surface area in the range of 5-100 m2/g; a fineness d50 of less than 70 μm; an apparent density AD in the range from 250 to 1000 g/l; and a particle content of 0.1 to 80% by weight of inorganic particles based on the total weight of the polyamide powder. They are equally suitable for coatings and for moldings and components with improved mechanical properties.
摘要翻译： 通过使具有相对溶液粘度和相对浓度的相对比例在1.5至2.0的范围内的聚酰胺制备基于聚酰胺制备的超细粉末的方法，其在25℃的0.5％间甲酚溶液中，在无机物存在下用醇介质 颗粒在压力和/或温度的作用下产生至少部分溶液，然后从至少部分溶液沉淀聚酰胺，其特征在于使用悬浮在醇介质中的无机颗粒的悬浮液。 所得的超细聚酰胺粉末的比BET比表面积在5-100m 2 / g的范围内; 细度d50小于70μm; 在250〜1000g / l范围内的表观密度AD; 和基于聚酰胺粉末的总重量的无机颗粒的0.1〜80重量％的颗粒含量。 它们同样适用于具有改善的机械性能的涂料和模制品和组分。
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公开(公告)号：US08167983B2
公开(公告)日：2012-05-01
申请号：US12517372
申请日：2007-12-17
CPC分类号： B01D53/228 , B01D67/0011 , B01D71/64 , B01D2256/10 , B01D2256/12 , B01D2323/12 , B01D2325/20 , B01D2325/34
摘要： The present invention relates to compositions for producing membranes, the compositions comprising at least 0.1% by weight of highly branched polymer, at least 0.5% by weight of linear polymer and at least 30% by weight of solvent. The present invention additionally describes membranes obtainable from the compositions, and methods of producing these membranes.
摘要翻译： 本发明涉及用于生产膜的组合物，该组合物包含至少0.1重量％的高支化聚合物，至少0.5重量％的线性聚合物和至少30重量％的溶剂。 本发明另外描述了可从组合物获得的膜以及制备这些膜的方法。
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70.发明申请MOLDING COMPOUND ON THE BASIS OF A COPOLYAMIDE CONTAINING TEREPHTHALIC ACID AND TRIMETHYLHEXAMETHYLENE DIAMINE UNITS 有权含有十五烷酸和三甲基乙酰胺二胺单体的共聚酰胺的成型化合物公开(公告)号：US20120095161A1
公开(公告)日：2012-04-19
申请号：US13377949
申请日：2010-07-08
CPC分类号： C08G69/265 , C08L77/06
摘要： A molding compound, containing at least 30% by weight of a copolyamide, which is derived from the following monomers: a) 50 to 95 mole percent of the combination of a diamine, selected from the group consisting of 1,9-nonane diamine, 1,10-decane diamine, 1,11-undecane diamine and 1,12-dodecane diamine, and terephthalic acid, and b) 5 to 50 mole percent of the combination of a diamine, selected from the group consisting of 2,2,4-trimethylhexamethylene diamine, 2,4,4-trimethylhexamethylene diamine, and mixtures thereof, and terephthalic acid. The copolyamide is crystalline and has low water absorption.
摘要翻译： 含有至少30重量％的共聚酰胺的模制化合物，其衍生自以下单体：a）50-95摩尔％的二胺的组合，其选自1,9-壬二胺， 1,10-癸烷二胺，1,11-十一烷二胺和1,12-十二烷二胺和对苯二甲酸，以及b）5至50摩尔％的二胺的组合，其选自2,2， 4-三甲基六亚甲基二胺，2,4,4-三甲基六亚甲基二胺及其混合物和对苯二甲酸。 共聚酰胺是结晶的，吸水率低。
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