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161 条记录 (耗时 0.027 秒)

    Preparation of carboxyl-containing polymers
    62.
    发明授权
    Preparation of carboxyl-containing polymers 失效
    含羧基聚合物的制备

    公开(公告)号：US4621127A

    公开(公告)日：1986-11-04

    申请号：US777328

    申请日：1985-09-18

    申请人： Walter Denzinger ,  Heinrich Hartmann ,  Johannes Perner ,  Hans-Juergen Raubenheimer

    发明人： Walter Denzinger ,  Heinrich Hartmann ,  Johannes Perner ,  Hans-Juergen Raubenheimer

    IPC分类号： C08F2/00 ,  C08F2/10 ,  C08F2/38 ,  C08F2/44 ,  C08F20/00 ,  C08F20/04 ,  C08F20/06 ,  C08F22/00 ,  C08F22/02 ,  C08F120/04 ,  C08F22/04

    CPC分类号： C08F20/04 ,  C08F2/10

    摘要： Carboxyl-containing polymers which are water-soluble at least in the neutralized form are prepared by a method in which a monoethylenically unsaturated C.sub.3 -C.sub.5 -carboxylic acid is polymerized in the presence or absence of a carboxyl-free copolymerizable ethylenically unsaturated monomer in aqueous solution in the presence of polymerization initiator and of from 0.01 to 5% by weight, based on the monomers, of an inorganic acid of phosphorus in which the phosphorus has an oxidation state of from 1 to 4, its water-soluble salts, a water-soluble --PO(OH).sub.2 -containing compound and/or its water-soluble salts and, if required, a polymerization regulator. Virtually colorless or only slightly colored polymer solutions are obtained.

    摘要翻译： 至少以中和形式具有水溶性的含羧基聚合物是通过在存在或不存在无羧基的可共聚烯键式不饱和单体的水溶液中聚合单烯属不饱和C3-C5-羧酸的方法制备的 在聚合引发剂存在下，基于单体为0.01〜5重量％的磷的氧化态为1〜4的磷的无机酸，其水溶性盐，水溶性盐， 可溶性的含PO（OH）2的化合物和/或其水溶性盐，如果需要，可以使用聚合调节剂。 获得几乎无色或仅有微量的聚合物溶液。

    Agglomerated particles of water-swellable addition polymers, preparation thereof and use thereof
    65.
    发明授权
    Agglomerated particles of water-swellable addition polymers, preparation thereof and use thereof 失效
    水溶胀性加成聚合物的聚集颗粒，其制备及其用途

    公开(公告)号：US06174946B1

    公开(公告)日：2001-01-16

    申请号：US08894373

    申请日：1997-08-22

    申请人： Martin R{umlaut over (u)}benacker ,  Reinhard Schneider ,  J{umlaut over (u)}rgen Nieberle ,  Harald Meyer ,  Heinrich Hartmann

    发明人： Martin R{umlaut over (u)}benacker ,  Reinhard Schneider ,  J{umlaut over (u)}rgen Nieberle ,  Harald Meyer ,  Heinrich Hartmann

    IPC分类号： C08J312

    CPC分类号： C08J3/12 ,  C08F6/18 ,  C08F220/02 ,  C08F226/00 ,  C08J3/16 ,  C08J2300/14 ,  C08L71/02 ,  C09D7/43 ,  D06P1/5214 ,  D06P1/5242 ,  D06P1/5257 ,  D06P1/613

    摘要： Agglomerated particles of water-swellable addition polymers, the agglomerated particles having an average particle diameter of from 20 to 5000 &mgr;m and consisting of primary particles having an average particle diameter of from 0.1 to 15 &mgr;m, being preparable by polymerization of water-soluble monomers in the presence of from 1′ to 10% by weight of a regulator and at least 2000 ppm, each based on the monomers, of a crosslinking agent in the manner of a water-in-oil polymerization and subsequent azeotropic removal of water from the water-in-oil polymer emulsions, containing the primary particles, in the presence of agglomerating polyalkylene glycols which (a) are obtainable by an addition reaction of C2-C4-alkylene oxides with alcohols, phenols, amines or carboxylic acids, and (b) contain at least 2 polymerized alkylene oxide units, and disintegrating into the primary particles on introduction into an aqueous medium, processes for preparing the agglomerated polymer particles and use of the agglomerated particles as thickeners for print pastes.

    摘要翻译： 聚水凝胶颗粒的水溶胀性加成聚合物，凝聚颗粒的平均粒径为20-5000μm，由平均粒径为0.1至15μm的一次颗粒组成，可通过水溶性单体的聚合制备 以油包水聚合的方式存在1至10重量％的调节剂和至少2000ppm（基于单体）的交联剂，并且随后从水中共沸除去水 （a）可以通过C 2 -C 4 - 烯化氧与醇，酚，胺或羧酸的加成反应获得的聚亚烷基二醇存在下的含有一次颗粒的油中聚合物乳液，和（b） 含有至少2个聚合的烯化氧单元，并且在引入水性介质时分解成初级颗粒，制备聚集的聚合物颗粒的方法和使用 附聚颗粒作为印刷浆料的增稠剂。

    Water-in-oil polymer emulsions
    67.
    发明授权
    Water-in-oil polymer emulsions 失效
    油包水聚合物乳液

    公开(公告)号：US5292800A

    公开(公告)日：1994-03-08

    申请号：US929025

    申请日：1992-08-13

    申请人： Dietmar Moench ,  Heinrich Hartmann ,  Hans-Ulrich Wekel

    发明人： Dietmar Moench ,  Heinrich Hartmann ,  Hans-Ulrich Wekel

    IPC分类号： B01F17/42 ,  C08F2/32 ,  C08L101/00 ,  C09K8/36 ,  C08K5/11

    CPC分类号： C08F2/32 ,  C09K8/36

    摘要： Water-in-oil emulsions of water-soluble or water-swellable polymers, in which the oil phase of the emulsion consists of not less than 50% by weight of an oil of vegetable or animal origin, contain, as water-in-oil emulsifiers, compounds which are obtainable by(A) reacting a C.sub.10 -C.sub.22 -fatty alcohol with epichlorohydrin in a molar ratio of from 1:0.5 to 1:1.5 to give a glycidyl ether,(B) reacting the glycidyl ether with (1) a saturated C.sub.2 -C.sub.6 -alcohol containing from 2 to 6 OH groups or (2) the monoether thereof with a C.sub.10 -C.sub.22 -fatty alcohol, in a molar ratio of glycidyl ether to (1) or (2) of from 1:0.5 to 1:6, in the presence of an acid or base and(C) alkoxylating the reaction product from (B) with one or more C.sub.2 -C.sub.4 -alkylene oxides in a molar ratio of from 1:1 to 1:6,if necessary, from 5 to 95% by weight of the stated water-in-oil emulsifier being replaced with other water-in-oil emulsifiers.

    摘要翻译： 水溶性或水溶胀性聚合物的油包水乳液，其中乳液的油相由不少于50重量％的植物或动物来源的油包含作为油包水 乳化剂，可通过（A）使C 10 -C 22脂肪醇与摩尔比为1:0.5至1:1.5的表氯醇反应得到缩水甘油醚得到的化合物，（B）缩水甘油醚与（1） 含有2至6个OH基团的饱和C 2 -C 6醇或（2）其单醚与C 10 -C 22脂肪醇，缩水甘油醚与（1）或（2）的摩尔比为1:0.5 至1：6，在酸或碱的存在下，和（C）将（B）的反应产物与一种或多种摩尔比为1:1至1:6的C 2 -C 4 - 氧化烯烷氧基化，如 必要时，将所述油包水乳化剂的重量从5至95％重量替换为其它油包水乳化剂。

    Preparation of finely divided, water-soluble polymers containing vinylamine units
    68.
    发明授权
    Preparation of finely divided, water-soluble polymers containing vinylamine units 失效
    制备细分的含有乙烯胺单元的水溶性聚合物

    公开(公告)号：US5290880A

    公开(公告)日：1994-03-01

    申请号：US661180

    申请日：1991-02-27

    申请人： Dietmar Moench ,  Michael Kroener ,  Enrique Freudenberg ,  Heinrich Hartmann ,  Norbert Sendhoff

    发明人： Dietmar Moench ,  Michael Kroener ,  Enrique Freudenberg ,  Heinrich Hartmann ,  Norbert Sendhoff

    IPC分类号： C08F2/10 ,  C08F8/12 ,  C08F26/00 ,  C08F26/02

    CPC分类号： C08F26/02 ,  C08F8/44

    摘要： N-vinylformamide is polymerized with or without other water-soluble monoethylenically unsaturated monomers and with or without water-insoluble monoethylenically unsaturated monomers in not less than 30% strength by weight aqueous monomer solutions in the presence of a polymerization initiator at not more than 150.degree. C. in a kneader by a method in which the polymerization is carried out to such an extent that the initially formed water-containing polymer gel disintegrates into fine particles and the finely divided polymer obtainable in this manner is hydrolyzed, preferably in the kneader, so that not less than 0.1 mol % of the N-vinylformamide units present in the polymer are converted into vinylamine units. The polymers obtainable in this manner dissolve readily in water. The aqueous solutions are used, for example, in papermaking and tertiary oil production.

    摘要翻译： N-乙烯基甲酰胺与或不与其它水溶性单烯键式不饱和单体聚合，并且在不超过150度的聚合引发剂存在下，在不低于30重量％的重量比单体水溶液中含有或不含水不溶性单烯属不饱和单体 在捏合机中，通过聚合进行到最初形成的含水聚合物凝胶分解成细颗粒的程度，并且以这种方式获得的细碎聚合物优选在捏合机中水解， 存在于聚合物中的不少于0.1mol％的N-乙烯基甲酰胺单元转化为乙烯胺单元。 以这种方式获得的聚合物容易溶于水。 水溶液用于例如造纸和三次油生产。

    Use of nonhydrolyzed copolymers containing N-vinylformamide units as flocculants and drainage aids
    69.
    发明授权
    Use of nonhydrolyzed copolymers containing N-vinylformamide units as flocculants and drainage aids 失效
    含有N-乙烯酰胺单元的非脱乙酰基单体作为絮凝剂和排水艾滋病的使用

    公开(公告)号：US5225088A

    公开(公告)日：1993-07-06

    申请号：US762020

    申请日：1991-09-18

    申请人： Dietmar Moench ,  Heinrich Hartmann ,  Karl-Heinz Buechner

    发明人： Dietmar Moench ,  Heinrich Hartmann ,  Karl-Heinz Buechner

    IPC分类号： C02F1/54 ,  C08F226/02

    CPC分类号： C08F226/02 ,  C02F1/54

    摘要： Nonhydrolyzed copolymers of(a) from 99 to 1 mol % of N-vinylformamide and(b) from 1 to 99 mol % of one or more water-soluble dialkylaminoalkylacrylamides in the form of the salts or quaternized products or a dialkylammonium compoundare used as agents for the treatment of wastewaters and sludges.

    摘要翻译： PCT No.PCT / EP90 / 00410 Sec。 371 1991年9月18日 102（e）1991年9月18日PCT PCT 1990年3月14日PCT公布。 公开号WO90 / 11253 日期为1990年10月4日。（a）99至1摩尔％的N-乙烯基甲酰胺和（b）1至99摩尔％的一种或多种盐或季铵化产物形式的水溶性二烷基氨基烷基丙烯酰胺的非水解共聚物 或二烷基铵化合物用作废水和污泥的处理剂。

    Water-soluble copolymers, their preparation and their use
    70.
    发明授权
    Water-soluble copolymers, their preparation and their use 失效
    水溶性共聚物，其制备及其用途

    公开(公告)号：US4952655A

    公开(公告)日：1990-08-28

    申请号：US183611

    申请日：1988-04-19

    申请人： Hans-Peter Seelmann-Eggebert ,  Dieter Boeckh ,  Heinrich Hartmann ,  Wolfgang Trieselt ,  Alexander Kud

    发明人： Hans-Peter Seelmann-Eggebert ,  Dieter Boeckh ,  Heinrich Hartmann ,  Wolfgang Trieselt ,  Alexander Kud

    IPC分类号： A01N25/26 ,  C08F2/10 ,  C08F20/10 ,  C08F220/04 ,  C08F220/20 ,  C08F290/00 ,  C08F299/00 ,  C08L101/16

    CPC分类号： C08F220/04 ,  A01N25/26

    摘要： Water-soluble copolymers having a K value of from 15 to 120 (determined on the sodium salt according to H. Fikentscher in aqueous solution at 25.degree. C., a pH of 7 and a polymer concentration of the Na salt of 1% by weight) contain, in the polymerized form,(a) from 99.5 to 80 mol % of one or more monoethylenically unsaturated C.sub.3 -C.sub.6 -monocarboxylic acids and(b) from 0.5 to 20 mol % of one or more comonomers which possess two or more ethylenically unsaturated, non-conjugated double bonds, are derived from esters and are obtainable by esterification of(b1) monoethylenically unsaturated C.sub.3 -C.sub.6 -monocarboxylic acids with(b2) polyhydric alcohols of 2 to 6 carbon atoms, polyalkylene glycols, polyglycerols, polyvinyl alcohol and monohydric, monoethylenically unsaturated C.sub.3 -C.sub.6 -alcohols and(c) from 0 to 30 mol % of other water-soluble, monoethylenically unsaturated monomers which are copolymerizable with (a) and (b),the copolymers containing polymer segments which consist of units of the monomers (a) and (c), have a weight average molecular weight of not more than 15,000 and are bonded to one another via units of (b).

    摘要翻译： K值为15〜120的水溶性共聚物（根据H.Fikentscher的钠盐在25℃的水溶液中测定，pH为7，Na盐的聚合物浓度为1重量％ ）包含（a）99.5-80mol％的一种或多种单烯属不饱和C 3 -C 6 - 单羧酸和（b）0.5至20摩尔％的一种或多种具有两个或多个烯键式的共聚单体的共聚单体 不饱和的非共轭双键衍生自酯，可通过（b1）单烯属不饱和C3-C6-单羧酸与（b2）2至6个碳原子的多元醇酯，聚亚烷基二醇，聚甘油，聚乙烯醇和 一元，单烯属不饱和C 3 -C 6醇和（c）0至30摩尔％可与（a）和（b）共聚的其它水溶性单烯属不饱和单体，所述共聚物含有聚合物链段， monom （a）和（c）的重均分子量不大于15,000，通过（b）单元彼此结合。