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    Graft polymers containing N-vinyl units, their preparation and their use
    2.
    发明授权
    Graft polymers containing N-vinyl units, their preparation and their use 失效
    含有N-乙烯基单元的接枝聚合物，其制备及其用途

    公开(公告)号：US5753759A

    公开(公告)日：1998-05-19

    申请号：US704772

    申请日：1996-10-24

    申请人： Heinrich Hartmann ,  Walter Denzinger ,  Claudia Nilz

    发明人： Heinrich Hartmann ,  Walter Denzinger ,  Claudia Nilz

    IPC分类号： B01F17/00 ,  B01F17/52 ,  C05G3/00 ,  C08F263/00 ,  C08F265/00 ,  C08F271/00 ,  C09B67/46 ,  C09D17/00 ,  C09K17/20 ,  C11D3/37 ,  D21H17/34

    CPC分类号： C09D17/00 ,  B01F17/005 ,  C05G3/0029 ,  C08F271/00 ,  C09B67/0085 ,  C09K17/20 ,  C11D3/3788 ,  D21H17/34

    摘要： Graft polymers which contain N-vinyl units and in which the grafting base is a polymer which contains in each case at least 5% by weight of units of the formulae ##STR1## where R.sup.1 and R.sup.2 are each H or C.sub.1 -C.sub.6 -alkyl, monoethylenically unsaturated monomers are grafted onto the grafting base in a weight ratio of from 100:1 to 1:100, and which have K values of at least 7 (determined according to H. Fikentscher in 5% strength by weight aqueous solution at 25.degree. C. and pH 7), are prepared by polymerization of monoethylenically unsaturated monomers in the presence of polymers which in each case contain at least 5% by weight of units of the formulae I and/or II as the grafting base in a weight ratio of from 100:1 to 1:100, and are used as dispersants for pigments, as additives for detergents and cleaning agents, and strength agents for paper and as soil stabilizers and for fertilizer compaction.

    摘要翻译： PCT No.PCT / EP95 / 00912 Sec。 371日期1996年10月24日第 102（e）日期1996年10月24日PCT 1995年3月3日PCT PCT。 公开号WO95 / 25759 日期1995年9月28日含有N-乙烯基单元的接枝聚合物，其中接枝碱是一种聚合物，其在每种情况下含有至少5重量％的式（I）的单元（I） 其中R 1和R 2各自为H或C 1 -C 6烷基，单烯属不饱和单体以100:1至1:100的重量比接枝到接枝基上，并且其K值至少为7（根据 H. Fikentscher在25℃和pH7的5重量％水溶液中）通过在聚合物存在下聚合单烯属不饱和单体来制备，每种情况下聚合物含有至少5重量％的式 I和/或II作为接枝基质，重量比为100：1至1：100，并用作颜料分散剂，作为洗涤剂和清洁剂的添加剂，以及用于纸张和土壤稳定剂的强度剂， 肥料压实。

    Preparation of copolymers of monoethylenically unsaturated monocarboxylic acids and dicarboxylic acids
    5.
    发明授权
    Preparation of copolymers of monoethylenically unsaturated monocarboxylic acids and dicarboxylic acids 失效
    单烯属不饱和一元羧酸和二羧酸的共聚物的制备

    公开(公告)号：US5175361A

    公开(公告)日：1992-12-29

    申请号：US625621

    申请日：1990-11-30

    申请人： Walter Denzinger ,  Heinrich Hartmann ,  Wolfgang Trieselt ,  Albert Hettche ,  Rolf Schneider ,  Hans-Juergen Raubenheimer

    发明人： Walter Denzinger ,  Heinrich Hartmann ,  Wolfgang Trieselt ,  Albert Hettche ,  Rolf Schneider ,  Hans-Juergen Raubenheimer

    IPC分类号： C08F220/04 ,  C08F222/02

    CPC分类号： C08F222/02 ,  C08F220/04

    摘要： A process for the preparation of copolymers which contain monoethylenically unsaturated monocarboxylic acids and dicarboxylic acids as copolymerized monomer units, which comprises copolymerizinga) 10 to 60% by weight, based on the sum of the monomers, of a monoethylenically unsaturated dicarboxylic acid of 4 to 6 carbon atoms, -or an alkali metal salt thereof or, an anhydride thereof,b) 90 to 40% by weight of a monoethylenically unsaturated monocarboxylic acid of 3 to 10 carbon atoms or an alkali metal salt thereof andc) 0 to 20% by weight of another monoethylenically unsaturated monomer, not having carboxyl groups and which is copolymerizable with a) and b);in an aqueous medium in the presence of from 0.5 to 5% by weight, based on monomers, of a water-soluble initiator.

    摘要翻译： 一种制备包含单烯属不饱和一元羧酸和二羧酸作为共聚单体单元的共聚物的方法，其包括将基于单体总量的10-60重量％的单烯属不饱和二羧酸与4- 6个碳原子，或其碱金属盐或其酸酐，b）90〜40重量％的3〜10个碳原子的单烯属不饱和一元羧酸或其碱金属盐，c）0〜20重量％ 重量的不具有羧基且可与a）和b）共聚的另一单烯属不饱和单体; 在水介质中，以0.5至5重量％的单体为基础，存在水溶性引发剂。

    Use of partially esterified copolymers in liquid detergents
    8.
    发明授权
    Use of partially esterified copolymers in liquid detergents 失效
    在液体洗涤剂中使用部分酯化的共聚物

    公开(公告)号：US5008032A

    公开(公告)日：1991-04-16

    申请号：US417474

    申请日：1989-10-05

    申请人： Paul Diessel ,  Johannes Perner ,  Walter Denzinger ,  Heinrich Hartmann ,  Hans-Juergen Raubenheimer

    发明人： Paul Diessel ,  Johannes Perner ,  Walter Denzinger ,  Heinrich Hartmann ,  Hans-Juergen Raubenheimer

    IPC分类号： C08L67/00 ,  C11D3/37

    CPC分类号： C11D3/3765

    摘要： Liquid, alkaline detergent formulations which contain as essential constituents a surfactant, water and 0.1-20% by weight of partially esterified copolymers are obtainable by the copolymerization of(a) one or more C.sub.4 -C.sub.28 -olefins and(b) ethylenically unsaturated dicarboxylic anhydrides of from 4 to 8 carbon atomsin a molar ratio of 1:1 and subsequent partial esterification of the copolymers of the reaction products(A) C.sub.1 -C.sub.30 -alcohols, C.sub.8 -C.sub.22 fatty acids, C.sub.1 -C.sub.12 -alkylphenols or secondary C.sub.2 -C.sub.30 -amines with(B) one or more C.sub.2 -C.sub.4 -alkylene oxides or tetrahydrofuranin a molar ratio of (A):(B) of from 1:2 to 1:50 and hydrolysis of the anhydride groups of the copolymer to carboxyl groups, the partial esterification of the copolymers being carried on until more than 5 to 50% of the carboxyl groups of the copolymers have been esterified.

    摘要翻译： 通过（a）一种或多种C 4 -C 28 - 烯烃和（b）烯属不饱和二羧酸酐共聚获得含有作为表面活性剂，水和0.1-20重量％部分酯化共聚物的基本组分的液体，碱性洗涤剂制剂 4至8个碳原子，摩尔比为1:1，随后反应产物（A）C 1 -C 30醇，C 8 -C 22脂肪酸，C 1 -C 12烷基酚或仲C2-C30的共聚物的部分酯化 - 胺与（B）一种或多种C 2 -C 4 - 烯化氧或四氢呋喃的摩尔比为（A）：（B）为1:2至1:50，并将共聚物的酸酐基水解成羧基 ，承载共聚物的部分酯化直到共聚物的羧基的5至50％已被酯化。