公开(公告)号：US5225960A

公开(公告)日：1993-07-06

申请号：US851510

申请日：1992-03-16

申请人： Hiroshi Kishi ,  Hiroshi Saito ,  Hisamitsu Shizuno ,  Yuji Nishi ,  Katsuhiko Arai

发明人： Hiroshi Kishi ,  Hiroshi Saito ,  Hisamitsu Shizuno ,  Yuji Nishi ,  Katsuhiko Arai

IPC分类号： C04B35/46 ,  C04B35/468 ,  H01B3/12 ,  H01G4/12

CPC分类号： H01G4/1227 ,  C04B35/4684 ,  H01G4/1245 ,  Y10T29/435

摘要： Disclosed is a ceramic capacitor of a mono-layer structure or a multi-layer structure, which has characteristic X7R (characteristic B) and which is high in reliability in direct current breakdown voltage at 125.degree. C. and small in size. The ceramic capacitor has a dielectric layer and internal electrodes disposed so as to interpose the dielectric layer. The dielectric layer is composed of a sintered body of ceramic particles whose core sections are made mainly of BaTiO.sub.3 and whose shell sections are made from BaTiO.sub.3 in the form of a solid solution composed of an oxide of one or more than one element selected from Mg, Ca, Sr and Zn and an oxide of one or more than one element selected from Sc, Y, Gd, Dy, Ho, Er, Yb, Tb, Tm and Lu.

公开(公告)号：US5006954A

公开(公告)日：1991-04-09

申请号：US483076

申请日：1990-02-21

申请人： Hiroshi Kishi ,  Hirokazu Chazono ,  Minoru Oshio ,  Hiroshi Saito ,  Toshiya Nakamura ,  Hisamitsu Shizuno

发明人： Hiroshi Kishi ,  Hirokazu Chazono ,  Minoru Oshio ,  Hiroshi Saito ,  Toshiya Nakamura ,  Hisamitsu Shizuno

IPC分类号： C04B35/46 ,  C04B35/468 ,  C04B35/49 ,  H01G4/12

CPC分类号： C04B35/49 ,  C04B35/4682 ,  H01G4/1245

摘要： A monolithic capacitor having a dielectric ceramic body cosintered with at least two base metal electrodes. The ceramic body is composed of a major ingredient expressed by the formula,(1-.alpha.){(Ba.sub.k-x M.sub.x)O.sub.k TiO.sub.2 }+.alpha.CaZrO.sub.3where M is either or both of magnesium and zinc, and .alpha., k and y are numerals in specified ranges. To this major ingredient is added a minor proportion of a mixture of lithium oxide, silicon dioxide and at least one metal oxide selected from among barium oxide, strontium oxide, calcium oxide, magnesium oxide and zinc oxide. For the fabrication of capacitors the mixture of the above major ingredient and additives in finely divided form are formed into moldings of desired shape and size, each with at least two electrodes buried therein. The moldings and electrodes are cosintered in a reductive or neutral atmosphere at temperatures of less than 1200.degree. C. and then are reheated at a lower temperature in an oxidative atmosphere.

公开(公告)号：US4999738A

公开(公告)日：1991-03-12

申请号：US483079

申请日：1990-02-21

申请人： Hiroshi Kishi ,  Hirokazu Chazono ,  Minoru Oshio ,  Hiroshi Saito ,  Toshiya Nakamura ,  Hisamitsu Shizuno

发明人： Hiroshi Kishi ,  Hirokazu Chazono ,  Minoru Oshio ,  Hiroshi Saito ,  Toshiya Nakamura ,  Hisamitsu Shizuno

IPC分类号： C04B35/46 ,  C04B35/49 ,  H01G4/12

CPC分类号： C04B35/49 ,  H01G4/1245

摘要： A monolithic capacitor having a dielectric ceramic body cosintered with at least two base metal electrodes. The ceramic body is composed of a major ingredient expressed by the formula,(1-.alpha.){(Ba.sub.k-x M.sub.x)O.sub.k TiO.sub.2 }+.alpha.CaZrO.sub.3where M is either or both of calcium and strontium, and .alpha., k and y are numerals in specified ranges. To this major ingredient is added a minor proportion of a mixture of boric oxide, silicon dioxide and at least one metal oxide selected from among barium oxide, strontium oxide, calcium oxide, magnesium oxide and zinc oxide. For the fabrication of capacitors the mixture of the above major ingredient and additives in finely divided form are formed into moldings of desired shape and size, each with at least two electrodes buried therein. The moldings and electrodes are cosintered in a reductive or neutral atmosphere at temperatures of less than 1200.degree. C. and then are reheated at a lower temperature in an oxidative atmosphere.

公开(公告)号：US4700268A

公开(公告)日：1987-10-13

申请号：US945360

申请日：1986-12-22

申请人： Hirokazu Chazono ,  Hiroshi Kishi ,  Shunji Murai ,  Masami Fukui ,  Takeshi Wada

发明人： Hirokazu Chazono ,  Hiroshi Kishi ,  Shunji Murai ,  Masami Fukui ,  Takeshi Wada

IPC分类号： H01G4/30 ,  C04B35/47 ,  C04B35/49 ,  H01B3/12 ,  H01G4/12 ,  C04B35/46

CPC分类号： C04B35/49 ,  C04B35/47 ,  H01G4/1245

摘要： A temperature compensating capacitor of monolithic or multilayered configuration comprising a dielectric ceramic body and at least two electrodes buried therein. The ceramic body is composed of a major ingredent expressed by the formula, {(Sr.sub.1-x Ca.sub.x)O}.sub.k (Ti.sub.1-y Zr.sub.y)O.sub.2, where x, k and y are numerals in the ranges of 0.005 to 0.995 inclusive, 1.00 to 1.04 inclusive, and 0.005 to 0.100 inclusive, respectively. To this major ingredient is added a minor proportion of a mixture of boric oxide, silicon dioxide, and one or more metal oxides selected from among barium oxide, magnesium oxide, zinc oxide, strontium oxide and calcium oxide. For the fabrication of capacitors the mixture of the above major ingredient and additives in finely divided form are formed into moldings of desired shape and size, each with at least two electrodes buried therein. The moldings and electrodes are cosintered in a reductive or neutral atmosphere and then are reheated at a lower temperature in an oxidative atmosphere. The cosintering temperature can be so low that nickel or like base metal can be employed as the electrode material.

摘要翻译： 一种单片或多层结构的温度补偿电容器，包括介电陶瓷体和埋在其中的至少两个电极。 陶瓷体由以下公式表示的主要成分{（Sr1-xCax）O} k（Ti1-yZry）O2）组成，其中x，k和y为0.005-0.995（含）范围内的数字，1.00至1.04 分别为0.005〜0.100。 添加少量的氧化硼，二氧化硅和一种或多种选自氧化钡，氧化镁，氧化锌，氧化锶和氧化钙的金属氧化物的混合物。 为了制造电容器，将上述主要成分和细分散形式的添加剂的混合物形成为所需形状和尺寸的模制品，其中至少埋设有两个电极。 模制品和电极在还原或中性气氛中共烧结，然后在较低温度下在氧化气氛中再加热。 整个烧结温度可以低到可以使用镍或类似的贱金属作为电极材料。

公开(公告)号：US4607314A

公开(公告)日：1986-08-19

申请号：US805096

申请日：1985-12-04

申请人： Takeshi Wada ,  Hiroshi Kishi ,  Shunji Murai ,  Masami Fukui

发明人： Takeshi Wada ,  Hiroshi Kishi ,  Shunji Murai ,  Masami Fukui

IPC分类号： C04B35/49 ,  C04B35/46 ,  C04B35/468 ,  H01B3/12 ,  H01G4/12 ,  H01G4/30 ,  H01G1/005 ,  H01G4/06

CPC分类号： C04B35/4682 ,  H01G4/1245

摘要： A monolithic ceramic capacitor having a higher DC breakdown voltage per unit thickness of the dielectric ceramic body than heretofore. The major ingredient of the ceramic is expressed as {(Ba.sub.1-x-y Ca.sub.x Sr.sub.y)O}.sub.k (Ti.sub.1-z Zr.sub.z)O.sub.2, where x, y, z and k are numerals in the ranges specified herein. To this major ingredient is added a minor proportion of a mixture of boric oxide, silicon dioxide and at least one metal oxide selected from among BaO, SrO and CaO, in specified ranges of proportions. For the fabrication of capacitors having dielectric bodies of the above composition, the moldings of the mixture of the major ingredient and additives in the specified proportions are sintered to maturity in a reductive or neutral atmosphere and then reheated at a lower temperature in an oxidative atmosphere. The sintering temperature can be so low (1000.degree.-1200.degree. C.) that the moldings can be cosintered with base metal electrodes buried therein.

摘要翻译： 一种单片陶瓷电容器，其电介质陶瓷体的单位厚度的直流击穿电压高于迄今为止。 陶瓷的主要成分表示为{（Ba1-x-yCaxSry）O} k（Ti1-zZrz）O2，其中x，y，z和k是本文所指定范围内的数字。 在规定的比例范围内，向该主要成分添加少量比例的氧化硼，二氧化硅和至少一种选自BaO，SrO和CaO的金属氧化物的混合物。 为了制造具有上述组成的电介质体的电容器，将主要成分和特定比例的添加剂的混合物的模制品在还原性或中性气氛中烧结成熟，然后在较低温度下在氧化气氛中再加热。 烧结温度可以如此低（1000°-1200℃），模制品可以与埋在其中的贱金属电极共烧结。

公开(公告)号：US09797063B2

公开(公告)日：2017-10-24

申请号：US13307253

申请日：2011-11-30

申请人： Toshiaki Sudo ,  Hiroshi Kishi ,  Eriko Suzuki

发明人： Toshiaki Sudo ,  Hiroshi Kishi ,  Eriko Suzuki

IPC分类号： C30B15/10 ,  C03B19/09

CPC分类号： C30B15/10 ,  C03B19/095 ,  Y10T117/1032

摘要： The present invention provides a vitreous silica crucible which can suppress buckling and sidewall lowering of the crucible without fear of mixing of impurities into silicon melt. According to the present invention, provided is a vitreous silica crucible for pulling a silicon single crystal, wherein a ratio I2/I1 is 0.67 to 1.17, where I1 and I2 are area intensities of the peaks at 492 cm−1 and 606 cm−1, respectively, in Raman spectrum of vitreous silica of the region having a thickness of 2 mm from an outer surface to an inner surface of a wall of the crucible.

公开(公告)号：US09109300B2

公开(公告)日：2015-08-18

申请号：US13179280

申请日：2011-07-08

申请人： Toshiaki Sudo ,  Hiroshi Kishi

发明人： Toshiaki Sudo ,  Hiroshi Kishi

IPC分类号： C30B15/10

CPC分类号： C30B15/10 ,  Y10T117/1032

摘要： The present invention provides a vitreous silica crucible which can suppress buckling and sidewall lowering of the crucible in multi-pulling. According to the present invention, provided is a vitreous silica crucible for pulling a silicon single crystal, comprising a mineralizer on an inner surface of the crucible, wherein the mineralizer contains at least one atoms selected from the group consisting of Ca, Sr, Ba, Ra, Ti, Zr, Cr, Mo, Fe, Co, Ni, Cu, and Ag, and the concentration of the mineralizer on the inner surface is 1.0×105 to 1.0×1017 atoms/cm2.

摘要翻译： 本发明提供一种可以抑制多拉的坩埚的翘曲和侧壁降低的石英玻璃坩埚。 根据本发明，提供了一种用于拉动硅单晶的玻璃状石英坩埚，其包括在坩埚的内表面上的矿化剂，其中矿化剂含有选自Ca，Sr，Ba， Ra，Ti，Zr，Cr，Mo，Fe，Co，Ni，Cu和Ag，矿化剂在内表面的浓度为1.0×10 5〜1.0×10 17原子/ cm 2。

公开(公告)号：US08936684B2

公开(公告)日：2015-01-20

申请号：US13308344

申请日：2011-11-30

申请人： Toshiaki Sudo ,  Hiroshi Kishi ,  Ken Kitahara

发明人： Toshiaki Sudo ,  Hiroshi Kishi ,  Ken Kitahara

IPC分类号： C30B15/10 ,  C03B19/09

CPC分类号： C30B15/10 ,  C03B19/095 ,  Y10T117/10 ,  Y10T117/1024 ,  Y10T117/1032

摘要： The present invention provides a vitreous silica crucible which can suppress buckling and sidewall lowering of the crucible and the generation of cracks. According to the present invention, a vitreous silica crucible is provided for pulling a silicon single crystal having a wall, the wall including a non-doped inner surface layer made of natural vitreous silica or synthetic vitreous silica, a mineralizing element-maldistributed vitreous silica layer containing dispersed island regions each containing a mineralizing element, and wherein the vitreous silica of the island regions and the vitreous silica of a surrounding region of the island regions is a combination of mineralizing element-doped natural vitreous silica and non-doped synthetic vitreous silica, or a combination of mineralizing element-doped synthetic vitreous silica and non-doped natural vitreous silica, and the inner surface layer is made of vitreous silica of a different kind from that of the island region.

摘要翻译： 本发明提供一种可以抑制坩埚的翘曲和侧壁降低以及产生裂纹的石英玻璃坩埚。 根据本发明，提供一种玻璃状石英坩埚，用于拉拔具有壁的硅单晶，所述壁包括由天然氧化硅玻璃或合成玻璃态二氧化硅制成的非掺杂内表面层，矿化元素分布不均的玻璃状石英层 含有各自含有矿化元素的分散的岛状区域，岛状区域的石英二氧化硅和岛状区域的周围区域的玻璃态二氧化硅是矿化元素掺杂天然玻璃质石英和非掺杂合成玻璃态二氧化硅的组合， 或矿化元素掺杂的合成玻璃体二氧化硅和非掺杂天然玻璃体二氧化硅的组合，并且内表面层由与岛状区域不同种类的玻璃态二氧化硅制成。

公开(公告)号：US08852555B2

公开(公告)日：2014-10-07

申请号：US12670807

申请日：2008-07-25

申请人： Hiroshi Handa ,  Mamoru Hatakeyama ,  Masanori Abe ,  Satoshi Sakamoto ,  Yuka Masaike ,  Kosuke Nishio ,  Yoshinori Kita ,  Hiroshi Kishi

发明人： Hiroshi Handa ,  Mamoru Hatakeyama ,  Masanori Abe ,  Satoshi Sakamoto ,  Yuka Masaike ,  Kosuke Nishio ,  Yoshinori Kita ,  Hiroshi Kishi

IPC分类号： A61K49/00 ,  C09C3/08 ,  B22F1/00 ,  B82Y30/00 ,  A61K49/18 ,  C09C1/24 ,  C09C3/10 ,  G01N33/543 ,  B82Y25/00 ,  H01F1/00 ,  C09C3/12 ,  A61K41/00

CPC分类号： H01F1/0045 ,  A61K41/0052 ,  A61K49/183 ,  A61K49/1833 ,  A61K49/1836 ,  A61K49/1851 ,  A61K49/1854 ,  B22F1/0022 ,  B22F1/0062 ,  B82Y25/00 ,  B82Y30/00 ,  C01G49/00 ,  C01P2006/42 ,  C09C1/24 ,  C09C3/08 ,  C09C3/10 ,  C09C3/12 ,  G01N33/53 ,  G01N33/54393 ,  H01F1/0054

摘要： Nano-sized inorganic particles having uniform particle sizes and precisely controlled particle diameters have already been produced by synthesis in an organic solvent, but these nano-sized inorganic particles are hindered from dispersing in a polar solvent because of the adsorption of a long-chain fatty acid on the surfaces of the particles. Further, it was difficult to form nano-sized inorganic particles dispersible in a polar solvent by replacing the long-chain fatty acid coats. According to the invention, various surface-coated inorganic particles dispersible in polar solvents can be produced from fatty acid-coated inorganic particles by adding a temporary coating substance such as thiomalic acid to a nonpolar solvent containing fatty acid-coated inorganic particles dispersed therein to replace the fatty acid coats by the temporary coating substance, dispersing the inorganic particles coated with the temporary coating substance in a polar solvent, and then adding a coating substance dispersible in a polar solvent, e.g., citric acid to the obtained dispersion to replace the temporary coating substance coats covering the inorganic particles by the coating substance dispersible in a polar solvent.

摘要翻译： 通过在有机溶剂中合成已经制备了具有均匀粒度和精确控制的粒径的纳米尺寸的无机颗粒，但是这些纳米尺寸的无机颗粒由于吸附长链脂肪而被阻挡在极性溶剂中 酸在颗粒的表面上。 此外，通过代替长链脂肪酸涂层，难以形成分散在极性溶剂中的纳米级无机颗粒。 根据本发明，分散在极性溶剂中的各种表面涂覆的无机颗粒可以通过向包含分散在其中的含脂肪酸涂覆的无机颗粒的非极性溶剂中添加诸如硫代酸的临时涂层物质，由脂肪酸包覆的无机颗粒制备，以代替 通过临时涂布物质将脂肪酸涂布，将涂覆有临时涂层物质的无机颗粒分散在极性溶剂中，然后将分散在极性溶剂如柠檬酸中的涂覆物质加入到所得分散体中以替代临时涂层 通过可分散在极性溶剂中的涂层物质覆盖无机颗粒的物质外套。

公开(公告)号：US08749339B2

公开(公告)日：2014-06-10

申请号：US13642467

申请日：2011-04-26

申请人： Hideki Ogawa ,  Atsushi Tanada ,  Hitoshi Matsuura ,  Kiyoshi Tanaka ,  Hiroshi Kishi ,  Kenji Kawano

发明人： Hideki Ogawa ,  Atsushi Tanada ,  Hitoshi Matsuura ,  Kiyoshi Tanaka ,  Hiroshi Kishi ,  Kenji Kawano

IPC分类号： H01F27/28 ,  H01F27/02 ,  B05D5/12

CPC分类号： H01F1/22 ,  B22F2998/00 ,  C22C1/02 ,  C22C2202/02 ,  H01F1/12 ,  H01F1/14766 ,  H01F1/24 ,  H01F1/26 ,  H01F1/33 ,  H01F5/02 ,  H01F5/06 ,  H01F41/02 ,  H01F41/0246 ,  H01F41/098 ,  H01F41/10 ,  H01F41/125 ,  Y10T29/4902 ,  Y10T29/49069 ,  Y10T29/49071 ,  Y10T29/49073 ,  Y10T29/49144 ,  C22C33/0278

摘要： A coil-type electronic component has a coil inside or on the surface of its base material wherein the base material in the coil-type electronic component is constituted by a group of grains of a soft magnetic alloy containing iron, silicon and other element that oxidizes more easily than iron; the surface of each soft magnetic alloy grain has an oxide layer formed on its surface as a result of oxidization of the grain; this oxide layer contains the other element that oxidizes more easily than iron by a quantity larger than that in the soft magnetic alloy grain; and grains are bonded with one another via this oxide layer. The coil-type electronic component can be produced at low cost and combines high magnetic permeability with high saturation magnetic flux density.

摘要翻译： 线圈型电子部件在其基材的内部或表面上具有线圈，其中线圈型电子部件中的基材由包含铁，硅和其它元素的软磁合金的晶粒组成 比铁更容易 每个软磁合金颗粒的表面由于晶粒的氧化而在其表面上形成氧化层; 该氧化物层含有比铁更容易氧化的量比软磁性合金粒子大的量的另一种元素; 并且晶粒经由该氧化物层彼此结合。 线圈型电子部件可以低成本地生产，并且具有高磁导率和高饱和磁通密度。