公开(公告)号：US5241035A

公开(公告)日：1993-08-31

申请号：US762365

申请日：1991-09-19

申请人： Ichiro Ono ,  Hiroshi Yoshioka

发明人： Ichiro Ono ,  Hiroshi Yoshioka

IPC分类号： C08G18/62 ,  C08G18/80 ,  C08G77/42 ,  C08G77/442 ,  C08G81/02 ,  C09D183/00 ,  C09D183/04 ,  C09D183/10

CPC分类号： C08G18/6275 ,  C08G18/809 ,  C08G77/442 ,  C09D183/10

摘要： A graft copolymer, comprising a trunk polymer comprising a vinyl chloride/vinyl alcohol copolymer containing vinyl chloride and vinyl alcohol as the essential constituent monomer units, and a branch polymer comprising an organopolysiloxane grafted onto said trunk polymer, and a coating composition comprising said graft copolymer as the main component. The coating formed from the composition is excellent in slippage, water repellency and mold release properties in addition to good characteristics derived from the vinyl chloride/vinyl alcohol resin.

摘要翻译： 一种接枝共聚物，其包括含有氯乙烯和乙烯醇作为主要构成单体单元的氯乙烯/乙烯醇共聚物的树干聚合物，以及包含接枝到所述树脂聚合物上的有机聚硅氧烷的支链聚合物，以及包含所述接枝共聚物 作为主要组成部分。 除了由氯乙烯/乙烯醇树脂得到的良好特性之外，由该组合物形成的涂层具有优异的滑动性，防水性和脱模性。

公开(公告)号：US5225062A

公开(公告)日：1993-07-06

申请号：US826725

申请日：1992-01-28

申请人： Hiroshi Yoshioka ,  Yuichi Mori

发明人： Hiroshi Yoshioka ,  Yuichi Mori

IPC分类号： B01D57/02 ,  G01N27/447

CPC分类号： B01D57/02 ,  G01N27/44747

摘要： An electrophoretic gel comprising at least one crosslinked temperature-responsive polymeric compound having an LCST is disclosed. A method of separating and recovering substances involves conducting the electrophoresis of a sample containing substances to be separated using the electrophoretic gel at a temperature below the LCST, excising each portion of the gel containing the substance to be separated and raising the temperature of the excised portion to a temperature above the LCST to shrink the excised portion to recover the substances.

公开(公告)号：US5179142A

公开(公告)日：1993-01-12

申请号：US532719

申请日：1990-06-04

申请人： Ichiro Ono ,  Hiroshi Yoshioka

发明人： Ichiro Ono ,  Hiroshi Yoshioka

IPC分类号： C08G18/61 ,  C08G63/68 ,  C08G63/695 ,  C08G77/14 ,  C08G77/22 ,  C08G77/38 ,  C08G77/445 ,  C08G81/00 ,  C08L63/00 ,  C08L101/00 ,  C09D183/04 ,  C09D183/10

CPC分类号： C08L63/00 ,  C08G18/61 ,  C08G77/445 ,  C08L101/00

摘要： A polylactone-modified organopolysiloxane compound, wherein a polylactone-containing group represented by the formula (I) is bound to a silicon atom located at at least either of the terminal positions and/or intermediate positions to impart excellent properties as a synthetic resin modifier (when Y in (I) is an acetyl group or a hydrogen atom) or as a film former (when Y in (I) is a hydrogen atom): ##STR1## wherein Z represents a trivalent hydrocarbon residue which may contain oxygen, sulfur or/and nitrogen atom(s); X represents a lactone group of the formula, ##STR2## (wherein R represents a hydrogen atom or an alkyl group containing from 1 to 12 carbon atoms; a represents an integer from 4 to 6), k and L each represents an integer of 1 or more; and Y represents a hydrogen atom or an acetyl group.

摘要翻译： 聚内酯改性的有机聚硅氧烷化合物，其中由式（I）表示的含聚内酯的基团与位于末端位置和/或中间位置的至少任一个的硅原子结合，以赋予作为合成树脂改性剂优异的性能 当（I）中的Y为乙酰基或氢原子时）或成膜剂（当（I）中的Y为氢原子时）：其中Z表示可含有氧的三价烃残基 ，硫或/和氮原子; X表示下式的内酯（其中R表示氢原子或含有1至12个碳原子的烷基; a表示4-6的整数），k和L各自表示1的整数 或者更多; Y表示氢原子或乙酰基。

公开(公告)号：US5174713A

公开(公告)日：1992-12-29

申请号：US724102

申请日：1991-07-01

申请人： Shingo Iwai ,  Hiroshi Yoshioka

发明人： Shingo Iwai ,  Hiroshi Yoshioka

IPC分类号： F02M37/04 ,  F04B11/00 ,  F04D5/00 ,  F04D29/18 ,  F04D29/20 ,  F04D29/66

CPC分类号： F02M37/048 ,  F04D29/188 ,  F04D29/20 ,  F04D29/669 ,  F04D5/002

摘要： A circumferential flow type fuel pump has an impeller rotated by engagement between a hole in the impeller and a rotating shaft having a diameter smaller than that of the hole. The center ofthe hole is eccentric with respect to the center of the impeller in accordance with the difference between the diameter of the hole and the diameter in section of the rotating shaft, so that the center of the impeller coincides with the center of the rotating shaft during rotation of the impeller.

公开(公告)号：US5086145A

公开(公告)日：1992-02-04

申请号：US539486

申请日：1990-06-18

申请人： Takashi Morimoto ,  Hiroshi Yoshioka

发明人： Takashi Morimoto ,  Hiroshi Yoshioka

IPC分类号： C08G77/06 ,  C08G77/08 ,  C08G77/16

CPC分类号： C08G77/08 ,  C08G77/16

摘要： Disclosed is a method of manufacturing solvent-soluble polyorganosilsesquioxanes of the formula; ##STR1## wherein each R is a substituted or unsubstituted alkyl, alkenyl or halogen-substituted alkyl group of 1-5 carbon atoms, or substituted or unsubstituted phenyl of 6-10 carbon atoms, and n is 2-10,000; which comprises reacting an organotriacetoxysilane with a stoichiometric quantity of alcohol and/or water in an organic solvent to obtain a diacetoxymonoalkoxysilane, which is condensation polymerized in the presence of sodium hydrogencarbonate to obtain a prepolymer, which prepolymer is then condensation polymerized by heat in the presence of a catalyst selected from alkali metal hydroxides, alkaline earth metal hydroxides, alkali metal fluorides, alkaline earth metal fluorides and triethylamine.

摘要翻译： 公开了制备下式的溶剂可溶性聚有机倍半硅氧烷的方法： 其中每个R是1-5个碳原子的取代或未取代的烷基，烯基或卤素取代的烷基，或6-10个碳原子的取代或未取代的苯基，n是2-10,000; 其包括在有机溶剂中使有机三乙酰氧基硅烷与化学计量的醇和/或水反应，得到在碳酸氢钠存在下缩聚获得预聚物的二乙酰氧基单烷氧基硅烷，然后将该预聚物在存在下通过加热进行缩聚 选自碱金属氢氧化物，碱土金属氢氧化物，碱金属氟化物，碱土金属氟化物和三乙胺的催化剂。

公开(公告)号：US5039771A

公开(公告)日：1991-08-13

申请号：US422173

申请日：1989-01-16

申请人： Takashi Morimoto ,  Hiroshi Yoshioka

发明人： Takashi Morimoto ,  Hiroshi Yoshioka

IPC分类号： C08G77/06 ,  C08G77/04 ,  C08G77/08 ,  C08G77/16

CPC分类号： C08G77/08 ,  C08G77/04 ,  C08G77/16

摘要： An oligomeric cage-like poly(silsesquioxane) of the general formula ##STR1## in which R is a monovalent hydrocarbon group and m is 4 to 12, can be polymerized by being admixed with a catalyst, e.g. alkali hydroxide or fluoride, and irradiated with microwaves. Different from conventional method of thermal polymerization, the polymerization reaction proceeds very uniformly at a high velocity to give a polymer of a high average molecular weight and narrow molecular weight distribution.

摘要翻译： 其中R为一价烃基且m为4至12的通式为“IMAGE”的低聚笼状聚（倍半硅氧烷）可以通过与催化剂， 碱性氢氧化物或氟化物，并用微波照射。 与常规热聚合方法不同，聚合反应以高速非常均匀地进行，得到高分子量和窄分子量分布的聚合物。

公开(公告)号：US4748225A

公开(公告)日：1988-05-31

申请号：US52402

申请日：1987-05-21

申请人： Hiroshi Yoshioka ,  Ichiro Ono

发明人： Hiroshi Yoshioka ,  Ichiro Ono

IPC分类号： C08G77/24 ,  B29C33/64 ,  C08G77/22 ,  C08G77/385 ,  C08G77/46 ,  C08K5/5419 ,  C08L101/00 ,  C08G77/04

CPC分类号： C08G77/46 ,  B29C33/64 ,  C08G77/385 ,  C08L101/00

摘要： A synthetic resin modifier comprising an organopolysiloxane represented by General Formula (I): ##STR1## wherein the group represented by X consists of 2 to 40% by weight of a group represented by R.sup.1 CO--, wherein R.sup.1 represents a saturated or unsaturated monovalent hydrocarbon group having 7 to 21 carbon atoms, and 60 to 98% by weight of a group represented by R.sup.2 --O-C.sub.q H.sub.2q), wherein R.sup.2 represents a saturated or unsaturated monovalent hydrocarbon group having 7 to 21 carbon atoms.This modifier can be effective for any type of synthetic resins, imparting good lubricity and release properties to the surface of forms or molding products, including films, and improving the workability in the molding of synthetic resins.

摘要翻译： 一种合成树脂改性剂，其包含由通式（I）表示的有机聚硅氧烷：其中由X表示的基团由2〜40重量％的由R 1 CO-表示的基团组成，其中R 1表示饱和或不饱和的 具有7〜21个碳原子的一价烃基和由R 2 -O-C q H 2q表示的基团的60〜98重量％），其中，R 2表示碳原子数为7〜21的饱和或不饱和一价烃基。 该改性剂对于任何类型的合成树脂都是有效的，赋予形式或成型产品（包括膜）表面良好的润滑性和释放性能，并提高合成树脂的模塑中的可加工性。

公开(公告)号：US4678688A

公开(公告)日：1987-07-07

申请号：US834906

申请日：1986-02-28

申请人： Kunio Itoh ,  Shohei Kozakai ,  Yoshinori Hida ,  Hiroshige Okinoshima ,  Fumio Okada ,  Toshio Oba ,  Hisashi Shimizu ,  Yuji Hinoto ,  Hiroshi Yoshioka

发明人： Kunio Itoh ,  Shohei Kozakai ,  Yoshinori Hida ,  Hiroshige Okinoshima ,  Fumio Okada ,  Toshio Oba ,  Hisashi Shimizu ,  Yuji Hinoto ,  Hiroshi Yoshioka

IPC分类号： C08G77/54 ,  C09D183/14 ,  B05D3/02

CPC分类号： C08J7/047 ,  C08G77/54 ,  C09D183/14 ,  C08J2483/00

摘要： The inventive method for forming a cured film on a substrate surface comprises coating the surface with a room temperature curable organosiloxazane polymer comprising, in a molecule, (a) at least one organosiloxane unit represented by the unit formula (a) at least one organosiloxane unit represented by the unit formulaR.sup.1.sub.a SiO.sub.(4-a)/2,and (b) at least one organosilazane unit represented by the unit formulaR.sup.2.sub.b Si(NR.sup.3).sub.(4-b)/2,in which R.sup.1, R.sup.2 and R.sup.3 are each a hydrogen atom or a substituted or unsubstituted monovalent hydrocarbon group, not all of them being simultaneously hydrogen atoms, and the subscripts a and b are each a positive integer of 1, 2 or 3 with the proviso that a and b cannot be simultaneously equal to 3, in a molecule and subjecting the coating film to exposure to a moisture-containing atmosphere. The method is useful for forming a surface-protecting film or for imparting surface releasability.

摘要翻译： 用于在基材表面上形成固化膜的本发明方法包括用室温可固化的有机硅氮烷聚合物涂覆表面，所述室温可固化的有机硅氮烷聚合物在分子中包含（a）至少一个由式（a）表示的有机硅氧烷单元，至少一个有机硅氧烷单元 由式R1aSiO（4-a）/ 2表示的至少一种有机硅氮烷单元，（b）由单元式R2bSi（NR3）（4-b）/ 2表示的至少一种有机硅氮烷单元，其中R1，R2和R3各自为 氢原子或取代或未取代的一价烃基，并不全部同时为氢原子，下标a和b各自为正整数1,2或3，条件是a和b不能同时为3 在分子中并使涂膜暴露于含水气氛。 该方法可用于形成表面保护膜或赋予表面剥离性。

公开(公告)号：US4633792A

公开(公告)日：1987-01-06

申请号：US837591

申请日：1986-03-07

申请人： Hiroshi Yoshioka

发明人： Hiroshi Yoshioka

IPC分类号： D05B3/12 ,  A41H37/06 ,  A44B19/40 ,  A44B19/42 ,  D05B35/06

CPC分类号： D05B35/064 ,  A41H37/06 ,  A44B19/42

摘要： A slide fastener is sewn to a pair of fabric pieces in a sewing station defined by a double-needle sewing machine. A pair of fastener stringers is twisted around in mirror symmetry with respect to the longitudinal centerline of the slide fastener. A slider, which is slidable on and along the fastener stringers, is temporarily held by a slider holder disposed upstream of and adjacent to the sewing station. As the sewing operation progresses and until after the engagement of the slider with the bottom end portion of the slide fastener, the pair of fastener stringers are automatically progressively uncoupled. The further movement of the slide fastener causes the slider to be forced by the bottom end portion of the slide fastener past the slider holder.

摘要翻译： 将拉链缝在由双针缝纫机定义的缝纫站中的一对织物上。 一对紧固件桁条相对于拉链的纵向中心线以镜像对称的方式被扭转。 沿着拉链条可以滑动的滑块由设置在缝纫台上方并与其相邻的滑块保持器临时保持。 当缝纫操作进行到拉链与拉链的底端部分接合之后，一对拉链条自动逐渐脱开。 拉链的进一步运动导致滑块被拉链的底端部分压过滑块架。

公开(公告)号：US4632045A

公开(公告)日：1986-12-30

申请号：US837602

申请日：1986-03-07

申请人： Hiroshi Yoshioka

发明人： Hiroshi Yoshioka

IPC分类号： A44B19/42 ,  D05B35/06 ,  D05B3/12 ,  D05B23/00

CPC分类号： D05B35/064

摘要： An apparatus for sewing a slide fastener to a pair of fabric pieces is provided with a slider-moving unit for coupling a pair of opposed stringers of the slide fastener immediately after the opposed stringers have been sewn to the respective fabric pieces. The slider-moving unit includes a slider-holding mechanism disposed downstream of a sewing station and reciprocable for pulling a slider on the slide fastener away from the sewing station, and a brake disposed adjacent to an upstream end of the reciprocating movement of the slider-holding mechanism for retaining a bottom end of the slide fastener while the slider is being pulled by the slider-holding mechanism.

摘要翻译： 一种用于将拉链缝合到一对织物上的装置设置有滑块移动单元，用于在相对的桁条被缝合到各个织物片之后立即将拉链的一对相对的桁条紧固在一起。 滑块移动单元包括：滑动器保持机构，其设置在缝合站的下游，并且可往复运动，用于将拉链上的滑块从缝合站拉出;以及制动器，其布置成与滑动件的往复运动的上游端相邻， 保持机构，用于在滑块被滑块保持机构拉动的同时保持拉链的底端。