公开(公告)号：US07935771B2

公开(公告)日：2011-05-03

申请号：US11815844

申请日：2006-11-10

申请人： Tatsuki Fukui ,  Akiko Tominaga ,  Takashi Kenmoku ,  Masato Minami ,  Tetsuya Yano ,  Takeshi Ikeda ,  Atsushi Tani ,  Norikazu Fujimoto

发明人： Tatsuki Fukui ,  Akiko Tominaga ,  Takashi Kenmoku ,  Masato Minami ,  Tetsuya Yano ,  Takeshi Ikeda ,  Atsushi Tani ,  Norikazu Fujimoto

IPC分类号： C08F128/02

CPC分类号： G03G9/08724 ,  C07C309/51 ,  C07C309/76 ,  C07C309/88 ,  C08F8/02 ,  C08F8/34 ,  C08F12/14 ,  C08F12/30 ,  C08F12/32 ,  C08F212/08 ,  C08F212/14 ,  G03G9/08726 ,  G03G9/08728 ,  G03G9/08791

摘要： There is provided a polymer including a unit represented by Chemical Formula (1): wherein R represents -A1-SO2R1; R1w and R1x are each independently a halogen atom or a hydrogen atom; R1y is a CH3 group, a halogen atom or a hydrogen atom; A01 is a substituted or unsubstituted aromatic ring structure or a substituted or unsubstituted heterocyclic structure; A1 is a substituted or unsubstituted aliphatic hydrocarbon structure, a substituted or unsubstituted aromatic ring structure or a substituted or unsubstituted heterocyclic structure; R1 is OH, a halogen atom, ONa, OK or OR1a; R1a is a substituted or unsubstituted aliphatic hydrocarbon structure, a substituted or unsubstituted aromatic ring structure or a substituted or unsubstituted heterocyclic structure.

摘要翻译： 提供包含由化学式（1）表示的单元的聚合物：其中R表示-A1-SO2R1; R1w和R1x各自独立地为卤素原子或氢原子; R1y是CH3基，卤素原子或氢原子; A01是取代或未取代的芳环结构或取代或未取代的杂环结构; A1是取代或未取代的脂族烃结构，取代或未取代的芳环结构或取代或未取代的杂环结构; R1是OH，卤素原子，ONa，OK或OR1a; R 1a是取代或未取代的脂族烃结构，取代或未取代的芳环结构或取代或未取代的杂环结构。

公开(公告)号：US20080064828A1

公开(公告)日：2008-03-13

申请号：US10574001

申请日：2005-06-09

申请人： Takashi Kenmoku ,  Tatsuki Fukui ,  Chieko Mihara ,  Ako Kusakari ,  Tetsuya Yano

发明人： Takashi Kenmoku ,  Tatsuki Fukui ,  Chieko Mihara ,  Ako Kusakari ,  Tetsuya Yano

IPC分类号： C08G63/02 ,  C07D319/12 ,  C07D321/00 ,  C08G69/44 ,  C08F24/00

CPC分类号： C08G63/912 ,  C08G63/6852 ,  C08G63/6882

摘要： The invention is to provide a novel polyhydroxyalkanoate having a reactive function group within the molecule and a producing method therefor In a polyhydroxyalkanoate containing a unit having a vinyl group in a side chain, such vinyl group is utilized for deriving a polyhydroxyalkanoate comprising a carboxyl group or a unit having an amide group and a sulfonic acid group.

摘要翻译： 本发明提供一种在分子内具有反应性官能团的新型聚羟基链烷酸酯及其制备方法在含有侧链中具有乙烯基的单元的聚羟基链烷酸酯中，使用这种乙烯基来得到包含羧基的聚羟基链烷酸酯或 具有酰胺基和磺酸基的单元。

公开(公告)号：US20070117945A1

公开(公告)日：2007-05-24

申请号：US11558222

申请日：2006-11-09

申请人： Masato Minami ,  Tatsuki Fukui ,  Takashi Kenmoku ,  Tetsuya Yano ,  Takeshi Ikeda ,  Norikazu Fujimoto ,  Atsushi Tani

发明人： Masato Minami ,  Tatsuki Fukui ,  Takashi Kenmoku ,  Tetsuya Yano ,  Takeshi Ikeda ,  Norikazu Fujimoto ,  Atsushi Tani

IPC分类号： G03G9/00

CPC分类号： G03G9/08706 ,  G03G9/09733

摘要： Provided are a novel polymer having a sulfonic group, a sulfonic acid ester group, or a derivative thereof incorporated therein, a method of producing the polymer, and a novel compound suitable for producing the polymer. A polymer is characterized by containing a unit represented by the following formula (1): wherein R1w and R1x are each independently a halogen atom or a hydrogen atom, R1y is a CH3 group or a hydrogen atom, and any one of R1a, R1b, and R1c is a sulfonate group represented by SO3R1f.

摘要翻译： 提供一种具有磺酸基，磺酸酯基或其衍生物的新型聚合物，其制备方法，以及适用于生产该聚合物的新型化合物。 聚合物的特征在于含有由下式（1）表示的单元：其中R 1w和R 1X 1各自独立地为卤素原子或氢原子， R 1，R 3，R 3，R 1b，R 1b，R 1b，R 1b，R 1b， 1c是由SO 3 R 1f 1表示的磺酸盐基团。

公开(公告)号：US20070117937A1

公开(公告)日：2007-05-24

申请号：US10580830

申请日：2005-06-09

申请人： Takashi Kenmoku ,  Chieko Mihara ,  Tatsuki Fukui ,  Ako Kusakari ,  Tetsuya Yano

发明人： Takashi Kenmoku ,  Chieko Mihara ,  Tatsuki Fukui ,  Ako Kusakari ,  Tetsuya Yano

IPC分类号： C08F20/00

CPC分类号： C08G63/6852 ,  C08G63/6882 ,  C08G63/912

摘要： The invention is to provide a novel polyhydroxyalkanoate having a reactive functional group within a molecule, a novel polyhydroxyalkanoate having a novel function by a chemical modification of the polyhydroxyalkanoate having the reactive functional group, and a producing method therefor. A polyhydroxyalkanoate containing a unit having a carboxyl group in a side chain is utilized for deriving a polyhydroxyalkanoate containing a unit having an amide group and a sulfonic acid group in the molecule.

摘要翻译： 本发明提供一种在分子内具有反应性官能团的新型聚羟基链烷酸酯，其具有通过化学修饰具有反应性官能团的聚羟基链烷酸酯具有新功能的新型聚羟基链烷酸酯及其制备方法。 在侧链中含有具有羧基的单元的聚羟基链烷酸酯用于衍生含有分子中具有酰胺基和磺酸基的单元的聚羟基链烷酸酯。

公开(公告)号：US07169598B2

公开(公告)日：2007-01-30

申请号：US10649646

申请日：2003-08-28

申请人： Tsutomu Honma ,  Toyoko Kobayashi ,  Tetsuya Yano ,  Shin Kobayashi ,  Takeshi Imamura ,  Sakae Suda ,  Takashi Kenmoku

发明人： Tsutomu Honma ,  Toyoko Kobayashi ,  Tetsuya Yano ,  Shin Kobayashi ,  Takeshi Imamura ,  Sakae Suda ,  Takashi Kenmoku

IPC分类号： C12N1/20

CPC分类号： C12P7/62 ,  C08G63/06 ,  C08G63/6822 ,  C08G63/6852 ,  Y10S435/874

摘要： A polyhydroxyalkanoate having a monomer unit composition represented by General Formula (1): AmB(1-m)  (1) wherein A is represented by General Formula (2), B is at least one selected from the group consisting of monomer units represented by General Formula (3) or (4), and m has a value of 0.01 or larger and smaller than 1: wherein n has a value of 0 to 10, k has a value of 3 or 5, and R is at least one group selected from the group consisting of groups represented by General Formulae (5) to (7): in Formula (5) R1 is a group selected from the group consisting of a hydrogen atom (H), halogen atoms, —CN, —NO2, —CF3, —C2F5. and —C3F7; and q is an integer selected from 1 to 8; in Formula (6) R2 is a group selected from the group consisting of a hydrogen atom (H), halogen atoms, —CN, —NO2, —CF3, —C2F5 and —C3F7; and r is an integer selected from 1 to 8; in Formula (7) R3 is a group selected from the group consisting of a hydrogen atom (H), halogen atoms, —CN, —NO2, —CF3, —C2F5 and —C3F7; and s is an integer selected from 1 to 8. The efficient production methods are also provided.

摘要翻译： 具有由通式（1）表示的单体单元组成的聚羟基链烷酸酯：<？in-line-formula description =“In-line Formulas”end =“lead”？> A （1-m）（1）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中A由通式（2）表示，B为至少一个 选自由通式（3）或（4）表示的单体单元组，并且m具有0.01以上且小于1的值：其中n具有0至10的值，k的值为3 或5，并且R是选自由通式（5）至（7）表示的基团中的至少一个基团：在式（5）中，R 1是选自氢原子（H） ，卤素原子，-CN，-NO 2，-CF 3，-C 2 H 5。 和-C 3 N 3 R 7; q为选自1至8的整数; 在式（6）中，R 2是选自氢原子（H），卤素原子，-CN，-NO 2，-CF 3， C 2 F 5和-C 3 F 7; 并且r是选自1至8的整数; 在式（7）中，R 3是选自氢原子（H），卤素原子，-CN，-NO 2，-CF 3 N， C 2 F 5和-C 3 F 7; s是选自1至8的整数。还提供了有效的制备方法。

公开(公告)号：US07135540B2

公开(公告)日：2006-11-14

申请号：US10359600

申请日：2003-02-07

申请人： Tsutomu Honma ,  Shinya Kozaki ,  Takeshi Imamura ,  Takashi Kenmoku ,  Tatsuki Fukui ,  Etsuko Sugawa ,  Tetsuya Yano

发明人： Tsutomu Honma ,  Shinya Kozaki ,  Takeshi Imamura ,  Takashi Kenmoku ,  Tatsuki Fukui ,  Etsuko Sugawa ,  Tetsuya Yano

IPC分类号： C08G63/02

CPC分类号： C12P7/625 ,  C08G63/6822 ,  C08G63/6882 ,  C12P11/00

摘要： The invention provides a polyhydroxyalkanoate having a bromo group in a unit and being thermally stable and capable of arbitrarily controlling physical properties, and a producing method thereof. According to the invention, there are provided a polyhydroxyalkanoate copolymer including a 3-hydroxy-ω-bromoalkanoic acid unit represented by a formula—[OCH((CH2)nBr)CH2C(O)]— (n=1 to 8) (1) and a unit represented by a formula —[OCH((CH2)mR)CH2C(O)]— (2) within a same molecule, and a method for producing a polyhydroxyalkanoate copolymer by microorganisms, utilizing a ω-bromoalkanoic acid represented by a formula Br(CH2)pCH2CH2COOH (p=1 to 8) (20) and a compound represented by a formula R(CH2)qCH2CH2COOH (21) as raw materials.

摘要翻译： 本发明提供一种具有溴基团并且是热稳定的并能够任意控制物理性能的聚羟基链烷酸酯及其制备方法。 根据本发明，提供了一种包含由式 - [OCH（（CH 2）n）n Br表示的3-羟基-ω-溴代链烷酸单元的聚羟基链烷酸酯共聚物 ）CH 2 C（O）] - （n = 1-8）（1）和由式 - [OCH（（CH 2）2） （O）] - （2），以及通过微生物制备聚羟基链烷酸酯共聚物的方法，使用由以下化合物表示的ω-溴烷酸： 式（Br 2 CH 2 CH 2 CH 2 CH 2 CH 2 CH 2 CH 2 COOH（p = 1〜8）（20 ）和由式R（CH 2 CH 2）q CH 2 CH 2 COOH（21）表示的化合物 作为原料。

公开(公告)号：US07045321B2

公开(公告)日：2006-05-16

申请号：US10084172

申请日：2002-02-28

申请人： Takeshi Imamura ,  Etsuko Sugawa ,  Tetsuya Yano ,  Tsuyoshi Nomoto ,  Tomohiro Suzuki ,  Tsutomu Honma ,  Takashi Kenmoku ,  Tatsuki Fukui

发明人： Takeshi Imamura ,  Etsuko Sugawa ,  Tetsuya Yano ,  Tsuyoshi Nomoto ,  Tomohiro Suzuki ,  Tsutomu Honma ,  Takashi Kenmoku ,  Tatsuki Fukui

IPC分类号： C12P11/00 ,  C12P13/00 ,  C08G63/02

CPC分类号： G03G9/08755 ,  C08G63/6882 ,  C12P7/625 ,  C12P11/00 ,  G03G9/08791 ,  G03G9/09733 ,  G03G9/09775

摘要： A polyhydroxyalkanoate characterized by having in the molecule a unit represented by Chemical Formula (1): wherein n may assume any one integral value within the range of from 1 to 8. Also disclosed are a process for producing the polyhydroxyalkanoate by the use of a microorganism having the ability to produce the polyhydroxyalkanoate and accumulate it in the bacterial body; a charge control agent, a toner binder and a toner which contain this polyhydroxyalkanoate; and an image-forming method and an image-forming apparatus which make use of the toner.

摘要翻译： 公开了在分子中具有由化学式（1）表示的单元的聚羟基链烷酸酯。 其中R选自氢原子，卤原子，CN，NO 2，COOR'，SO 2 R“，CH 3，C 2 H 5，C 3 H 7，C（CH 3）2 H和C（CH 3）3; 其中R'是H，Na，K，CH3或C2H5，R“是OH，ONa，OK，卤素原子，OCH3或OC2H5; x是任意选自1至8的整数; 条件是排除了具有氢原子作为R的聚羟基链烷酸酯，并且所有单元中的x均为2或4.还公开了通过使用具有生产聚羟基链烷酸酯的能力的微生物来生产聚羟基链烷酸酯并累积 它在细菌体内

公开(公告)号：US20060040366A1

公开(公告)日：2006-02-23

申请号：US10531572

申请日：2003-10-23

申请人： Takashi Kenmoku ,  Tetsuya Yano ,  Shinya Kozaki ,  Tsutomu Honma

发明人： Takashi Kenmoku ,  Tetsuya Yano ,  Shinya Kozaki ,  Tsutomu Honma

IPC分类号： C12P7/62 ,  C08G69/44

CPC分类号： C12P7/625 ,  C08G63/06 ,  C08G63/664 ,  C08G63/6882

摘要： Provided are a PHA having an active group, which is produced by microorganisms with high productivity, and in which the ratio of units on its side chain having an active group can be controlled and the physical properties can be arbitrarily controlled so that its application as a polymer is not limited, and a method for producing the same. A 3-hydroxy-ω-[(phenylmethyl)oxy]alkanoic acid unit expressed by the following chemical formula (1): wherein x can be one or more integers within the range shown in the chemical formula.

摘要翻译： 提供具有活性基团的PHA，其由高生产率的微生物产生，并且其中可以控制具有活性基团的侧链上的单元比例，并且物理性质可以任意控制，使得其作为 聚合物不受限制，也可以是其制造方法。 由以下化学式（1）表示的3-羟基-ω（ - （（苯甲基）氧基）链烷酸单元：其中x可以是化学式所示范围内的一个或多个整数。

公开(公告)号：US06911521B2

公开(公告)日：2005-06-28

申请号：US10157142

申请日：2002-05-30

申请人： Takashi Kenmoku ,  Etsuko Sugawa ,  Tetsuya Yano ,  Tsuyoshi Nomoto ,  Takeshi Imamura ,  Tomohiro Suzuki ,  Tsutomu Honma

发明人： Takashi Kenmoku ,  Etsuko Sugawa ,  Tetsuya Yano ,  Tsuyoshi Nomoto ,  Takeshi Imamura ,  Tomohiro Suzuki ,  Tsutomu Honma

IPC分类号： C08G63/06 ,  C08G63/02 ,  C08G63/688 ,  C08G63/78 ,  C12P7/62 ,  C12P11/00

CPC分类号： C12P11/00 ,  C08G63/6882 ,  C12P7/625

摘要： A polyhydroxyalkanoate that comprises a unit represented by the following chemical formula (1): wherein R1 is a substituent of an aromatic ring selected from the group consisting of H, CH3, C2H5, CH3CH2CH2, (CH3)2CH, (CH3)3C, a halogen atom, CN, NO2, COOR′, and SO2R″, wherein R′ is selected from the group consisting of H, Na, K, CH3, and C2H5, and R″ is selected from the group consisting of OH, a halogen atom, ONa, OK, OCH3, and OC2H5; and x represents an integer of 1 to 8 being the same or different each other in the polyhydroxyalkanoate. A method for producing the polyhydroxyalkanoate is also provided.

摘要翻译： 一种聚羟基链烷酸酯，其包含由以下化学式（1）表示的单元：其中R1是选自H，CH 3，C 2， CH 3，CH 3，CH 2，CH 2，CH 3，CH 3，CH 3，CH 3， ）CH 2（CH 3）3 C，卤素原子，CN，NO 2，COOR' ，和SO 2 R“，其中R'选自H，Na，K，CH 3，和C 2 H 5，并且R“选自OH，卤素原子，ONa，OK，OCH 3和OC 2， 5 H 5; x表示在聚羟基链烷酸酯中相同或不同的1〜8的整数。 还提供了生产聚羟基链烷酸酯的方法。

公开(公告)号：US06911520B2

公开(公告)日：2005-06-28

申请号：US10373851

申请日：2003-02-27

申请人： Tatsuki Fukui ,  Etsuko Sugawa ,  Tetsuya Yano ,  Chieko Mihara ,  Takeshi Imamura ,  Takashi Kenmoku

发明人： Tatsuki Fukui ,  Etsuko Sugawa ,  Tetsuya Yano ,  Chieko Mihara ,  Takeshi Imamura ,  Takashi Kenmoku

IPC分类号： C08G63/06 ,  C08G63/688 ,  C08G63/91 ,  C08L101/16 ,  G03G9/087 ,  G03G9/097 ,  C08G63/02

CPC分类号： C08G63/912 ,  C08G63/06 ,  C08G63/6882 ,  G03G9/08791 ,  G03G9/097 ,  G03G9/09733

摘要： Provided is a polyhydroxyalkanoate containing in a molecule thereof one or more units each selected from the following formulae (1) (2), (3) and (4): wherein R1 and R6 are each OH, halogen, ONa, OK, OCH3 or OC2H5; A1 and J6 are each a substituted or unsubstituted aliphatic hydrocarbon; m and n are each 0 to 7; r is 1 to 500; and R1′ to R5′ are each hydrogen or halogen.

摘要翻译： 提供一种分子中含有一个或多个选自下式（1）（3）和（4）中的单元的聚羟基链烷酸酯：其中R 1和R 6 每个OH，卤素，ONa，OK，OCH 3或OC 2 H 5; A 1和J 6各自为取代或未取代的脂族烃; m和n各自为0至7; r为1〜500; R 1至R 5'各自为氢或卤素。