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    Dicarboximides and their use as herbicides
    61.
    发明授权
    Dicarboximides and their use as herbicides 失效
    DICARBOXIMIDES及其作为除草剂的用途

    公开(公告)号：US5176739A

    公开(公告)日：1993-01-05

    申请号：US718639

    申请日：1991-06-21

    申请人： Volker Maywald ,  Klaus Ditrich ,  Thomas Kuekenhoehner ,  Gerhard Hamprecht ,  Wolfgang Freund ,  Karl-Otto Westphalen ,  Matthias Gerber ,  Helmut Walter

    发明人： Volker Maywald ,  Klaus Ditrich ,  Thomas Kuekenhoehner ,  Gerhard Hamprecht ,  Wolfgang Freund ,  Karl-Otto Westphalen ,  Matthias Gerber ,  Helmut Walter

    IPC分类号： A01N43/76 ,  A01N43/78 ,  A01N43/80 ,  A01N43/90 ,  C07D498/04 ,  C07D499/04 ,  C07D513/04

    CPC分类号： C07D513/04 ,  A01N43/90

    摘要： Dicarboximides of the formulae Ia, Ib and Ic ##STR1## where X is oxygen or sulfur, R.sup.1 is hydrogen, halogen, cyano, alkyl, cycloalkyl, alkenyl, alkynyl, alkoxy, alkenyloxy, alkynyloxy, alkylthio, haloalkoxy, haloalkylthio, alkylsulfonyl, haloalkylsulfonyl, phenyl, phenylalkyl, phenoxy or phenylthio, a 5-membered or 6-membered saturated or aromatic heterocyclic radical containing one or two hetero atoms selected from the group consisting of oxygen, sulfur and nitrogen, where the stated organic radicals may be further substituted, andR.sup.2 is hydrogen, hydroxyl, alkoxy, alkyl, cycloalkyl, alkenyl, alkynyl, di-C.sub.1 -C.sub.4 -alkylamino, a 5-membered or 6-membered heterocyclic saturated or aromatic radical having one or two hetero atoms selected from the group consisting of oxygen, sulfur and nitrogen, phenyl or naphthyl, where the stated organic radicals may be further substituted,and plant-tolerated salts of the dicarboximides I, except for 3-methylisoxazole-4,5-dicarboximide and thiazole-4,5-dicarboximides in which R.sup.2 is phenyl when R.sup.1 is methyl or 2-thiazolyl,and herbicides containing these compounds.

    摘要翻译： 其中X是氧或硫，R 1是氢，卤素，氰基，烷基，环烷基，烯基，炔基，烷氧基，烯氧基，炔氧基，烷氧基， 烷硫基，卤代烷氧基，卤代烷硫基，烷基磺酰基，卤代烷基磺酰基，苯基，苯基烷基，苯氧基或苯硫基，含有一个或两个选自氧，硫和氮的杂原子的5元或6元饱和或芳族杂环基团， 所述有机基团可以被进一步取代，并且R 2是氢，羟基，烷氧基，烷基，环烷基，烯基，炔基，二-C 1 -C 4 - 烷基氨基，具有一个或多个的五元或六元杂环饱和或芳族基团 选自氧，硫和氮的两个杂原子，苯基或萘基，其中所述有机基团可以被进一步取代，以及二甲酰亚胺I的植物耐受盐，除了3-甲基异恶唑-4,5-二甲酰亚胺 e和噻唑-4,5-二羧酰亚胺，当R 1为甲基或2-噻唑基时，R 2为苯基，以及含有这些化合物的除草剂。

    Substituted (4-brompyrazole-3-yl) benzazoles
    63.
    发明授权
    Substituted (4-brompyrazole-3-yl) benzazoles 失效

    公开(公告)号：US06482774B1

    公开(公告)日：2002-11-19

    申请号：US09673996

    申请日：2000-10-25

    申请人： Cyrill Zagar ,  Gerhard Hamprecht ,  Markus Menges ,  Olaf Menke ,  Robert Reinhard ,  Peter Schäfer ,  Karl-Otto Westphalen ,  Martina Otten ,  Helmut Walter

    发明人： Cyrill Zagar ,  Gerhard Hamprecht ,  Markus Menges ,  Olaf Menke ,  Robert Reinhard ,  Peter Schäfer ,  Karl-Otto Westphalen ,  Martina Otten ,  Helmut Walter

    IPC分类号： C07D41704

    CPC分类号： C07D413/04 ,  A01N43/74 ,  C07D231/16 ,  C07D417/04 ,  C07D417/14 ,  C07F9/6541 ,  C07F9/65583

    摘要： Substituted (4-bromopyrazol-3-yl)benzazoles I and their salts where R1=H, C1-C4-alkyl, C1-C4-haloalkyl; R2=CN, Cl-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-haloalkoxy, C1-C4-alkylthio, C1-C4-haloalkylthio, C1-C4-alkylsulfinyl, C1-C4-haloalkylsulfinyl, C1-C4-alkylsulfonyl, C1-C4-haloalkylsulfonyl; R4=H, halogen; R5=H, CN, halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy or C1-C4-haloalkoxy; Z=—N═C(XR6)—O— or —N═C(XR6)—S—, attached to &agr; via the nitrogen, oxygen or sulfur; X=a chemical bond, oxygen, sulfur, —S(O)—, —SO2—, —NH— or —N(R7)—; R6, R7=Cl-C6-alkyl, Cl-C6-haloalkyl, cyano-Cl-C4-alkyl, hydroxy-C1-C4-alkyl, C3-C6-alkenyl, cyano-C3-C6-alkenyl, C3-C6-haloalkenyl, C3-C6-alkynyl, cyano-C3-C6-alkynyl, C3-C6-haloalkynyl, C1-C4-alkoxy-C1-C4-alkyl, C1-C4-haloalkoxy-C1-C4-alkyl, C3-C4-alkenyloxy-C1-C4-alkyl, C3-C4-alkynyloxy-C1-C4-alkyl, C3-C8-cycloalkyloxy-C1-C4-alkyl, amino-Cl-C4-alkyl, C1-C4-alkylamino-C1-C4-alkyl, di(C1-C4-alkyl)amino-C1-C4-alkyl, Cl-C4-alkylthio-C1-C4-alkyl, C1-C4-haloalkylthio-C1-C4-alkyl, C3-C4-alkenylthio-C1-C4-alkyl, C3-C4-alkynylthio-C1-C4-alkyl, C1-C4-alkylsulfinyl-Cl-C4-alkyl, C1-C4-haloalkylsulfinyl-C1-C4-alkyl, C3-C4-alkenylsulfinyl-C1-C4-alkyl, C3-C4-alkynylsulfinyl-C1-C4-alkyl, C1-C4-alkylsulfonyl-C1-C4-alkyl, C1-C4-haloalkylsulfonyl-C1-C4-alkyl, C3-C4-alkenylsulfonyl-C1-C4-alkyl, C3-C4-alkynylsulfonyl-C1-C4-alkyl, hydroxycarbonyl-C1-C4-alkyl, C1-C4-alkoxycarbonyl-C1-C4-alkyl, which may carry a CN or C1-C4-alkoxycarbonyl group, C1-C4-alkylthiocarbonyl-C1-C4-alkyl, aminocarbonyl-C1-C4-alkyl, C1-C4-alkylaminocarbonyl-C1-C4-alkyl, di(C1-C4-alkyl)aminocarbonyl-C1-C4-alkyl, di(C1-C4-alkyl)-phosphonyl-C1-C4-alkyl, C1-C4-alkoxyimino-C1-C4-alkyl, C3-C4-alkenyloxyimino-C1-C4-alkyl, unsubstituted or substituted C3-C8-cycloalkyl, C3-C8-cycloalkyl-C1-C4-alkyl, phenyl, phenyl-C1-C4-alkyl, 3- to 7-membered heterocyclyl or heterocyclyl-C1-C4-alkyl, where each cycloalkyl and each heterocyclyl ring may contain a CO or CS ring member; if X=a chemical bond, —O—, —S—, —NH— or —N(R7)—, R6 may also be C1-C4-alkylcarbonyl, C1-C4-haloalkylcarbonyl, C1-C4-alkoxycarbonyl, C1-C4-alkylsulfonyl or C1-C4-haloalkylsulfonyl; if X=a chemical bond, R6 may furthermore be CN, SH, NH2, halogen, —CH2—CH(halogen)-R8, —CH═CH—R8 or —CH═C(halogen)-R8, where R8=COOH, C1-C4-alkoxycarbonyl, C1-C4-alkylthiocarbonyl, CONH2, C1-C4-alkylaminocarbonyl, di(C1-C4-alkyl)aminocarbonyl or di(C1-C4-alkyl)phosphonyl; or R6+R7=an unsubstituted or substituted 1,3-propylene, tetramethylene, pentamethylene or ethyleneoxyethylene chain. Use: As herbicides; for the desiccation/defoliation of plants.

    Substituted 2-phenyl-3(2H)-pyridazinones
    69.
    发明授权
    Substituted 2-phenyl-3(2H)-pyridazinones 失效
    取代的2-苯基-3（2H） - 哒嗪酮

    公开(公告)号：US06225313B1

    公开(公告)日：2001-05-01

    申请号：US09508781

    申请日：2000-03-16

    申请人： Peter Schäfer ,  Gerhard Hamprecht ,  Markus Menges ,  Olaf Menke ,  Michael Rack ,  Robert Reinhard ,  Cyrill Zagar ,  Peter Münster ,  Karl-Otto Westphalen ,  Martina Otten ,  Helmut Walter

    发明人： Peter Schäfer ,  Gerhard Hamprecht ,  Markus Menges ,  Olaf Menke ,  Michael Rack ,  Robert Reinhard ,  Cyrill Zagar ,  Peter Münster ,  Karl-Otto Westphalen ,  Martina Otten ,  Helmut Walter

    IPC分类号： C07D23718

    CPC分类号： C07D405/10 ,  A01N43/58 ,  C07D237/22

    摘要： Substituted 2-phenyl-3(2H)-pyridazinones I and salts thereof, where n=0, 1, 2; R1=C1-C4-alkyl, C1-C4-haloalkyl; R2=H, halogen; R3=halogen, CN; R4=H, NO2, CN, CHO, NH—OH, C1-C4-alkyl, C1-C4-halogenalkyl, —OR5, —CH═N—OR6, —CH═C(R7)—CO—OR8, —CO—OR9, C1-C6-alkyl-SO2—NH, di(C1-C6-alkylsulfonyl)amino or R5=C1-C6-alkyl, C3-C6-alkenyl, C3-C6-alkynyl, (C1-C6-alkoxy)carbonyl-C1-C4-alkyl, (C3-C6-alkenyloxy)carbonyl-C1-C4-alkyl, (C3-C6-alkynyloxy)carbonyl-C1-C4-alkyl, C1-C4-alkoxy(C1-C4-alkoxy)carbonyl-C1-C4-alkyl; R6=H, C1-C4-alkyl, hydroxycarbonyl-C1-C4-alkyl, (C1-C4-alkoxy)carbonyl-C1-C4-alkyl; R7=H, halogen, C1-C4-alkyl; R8=H, C1-C6-alkyl; R9=H, C1-C6-alkyl, C3-C6-alkenyl, C3-C6-alkynyl, C1-C4-alkoxy-C1-C4-alkoxy, hydroxycarbonyl-C1-C4-alkyl, (C1-C6-alkoxy)carbonyl-C1-C4-alkyl, (C3-C6-alkenyloxy)carbonyl-C1-C4-alkyl, (C3-C6-alkynyloxy)carbonyl-C1-C4-alkyl, C1-C4-alkoxy-(C1-C4-alkoxy)carbonyl-C1-C4-alkyl; R10=H, C1-C6-alkyl, COOH, (C1-C6-alkoxy)carbonyl; and their use as herbicides and for the desiccation/defoliation of plants are described.

    摘要翻译： 取代的2-苯基-3（2H） - 哒嗪酮I和其盐，其中n = 0,1,2; R1 = C1-C4-烷基，C1-C4卤代烷基; R2 = H，卤素; R3 =卤素，CN; R4 = H，NO2，CN，CHO，NH-OH，C1-C4-烷基，C1-C4-卤代烷基，-OR5，-CH = N-OR6，-CH = C（R7） CO-OR 8，-CO-OR 9，C 1 -C 6烷基-SO 2 -NH，二（C 1 -C 6烷基磺酰基）氨基或R 5 = C 1 -C 6烷基，C 3 -C 6 - 烯基，C 3 -C 6炔基，（C 1 C 3-6 - 烷氧基）羰基-C 1 -C 4烷基，（C 3 -C 6 - 烯氧基）羰基-C 1 -C 4 - 烷基，（C 3 -C 6 - 炔氧基）羰基-C 1 -C 4烷基，C 1 -C 4 - C 1 -C 4 - 烷氧基）羰基-C 1 -C 4 - 烷基; R 6 = H，C 1 -C 4 - 烷基，羟基羰基-C 1 -C 4 - 烷基，（C 1 -C 4 - 卤素，C 1 -C 4 - 烷基; R8 = H，C1-C6-烷基; R9 = H，C1-C6-烷基，C3-C6-烯基，C3-C6-炔基，C1-C4-烷氧基-C1-C4-烷氧基，羟基羰基C1-C4- 烷基，（C 1 -C 6 - 烷氧基）羰基-C 1 -C 4 - 烷基，（C 3 -C 6 - 烯氧基）羰基-C 1 -C 4烷基，（C 3 -C 6 - 炔氧基）羰基-C 1 -C 4烷基，C 1 -C 4 - 烷氧基 - （C 1 -C 4 - 烷氧基）羰基-C 1 -C 4烷基; R 10 = H，C 1 -C 6烷基，COOH，（C 1 -C 6 - 烷氧基）羰基;及其作为除草剂和干燥/ 的植物被描述。

    Benzylhydroxylamines and intermediates used to prepare them
    70.
    发明授权
    Benzylhydroxylamines and intermediates used to prepare them 失效

    公开(公告)号：US6057269A

    公开(公告)日：2000-05-02

    申请号：US973780

    申请日：1998-01-05

    申请人： Ralf Klintz ,  Gerhard Hamprecht ,  Elisabeth Heistracher ,  Peter Schafer ,  Cyrill Zagar ,  Karl-Otto Westphalen ,  Helmut Walter ,  Ulf Misslitz ,  Olaf Menke ,  Markus Menges

    发明人： Ralf Klintz ,  Gerhard Hamprecht ,  Elisabeth Heistracher ,  Peter Schafer ,  Cyrill Zagar ,  Karl-Otto Westphalen ,  Helmut Walter ,  Ulf Misslitz ,  Olaf Menke ,  Markus Menges

    IPC分类号： A01N43/54 ,  A01N47/12 ,  A01N47/24 ,  A01N47/30 ,  A01N53/00 ,  C07C239/08 ,  C07C239/10 ,  C07C239/16 ,  C07C239/20 ,  C07C265/12 ,  C07C271/22 ,  C07C271/28 ,  C07C271/54 ,  C07C271/58 ,  C07C275/32 ,  C07C275/40 ,  C07D239/54 ,  C07D405/12

    CPC分类号： C07D239/54 ,  A01N43/54 ,  A01N47/12 ,  A01N47/24 ,  A01N47/30 ,  A01N53/00 ,  C07C239/08 ,  C07C239/10 ,  C07C265/12 ,  C07C271/22 ,  C07C271/28 ,  C07C271/54 ,  C07C271/58 ,  C07C275/40

    摘要： Benzylhydroxylamines I ##STR1## (X=--N(R.sup.7)--O--; Y=O, S; R.sup.1 =halogen, CN, NO.sub.2, CF.sub.3 ; R.sup.2 =H, halogen; R.sup.3 =H, NH.sub.2, CH.sub.3 ;R.sup.4 =H, halogen, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -haloalkyl, C.sub.1 -C.sub.6 -alkylthio, C.sub.1 -C.sub.6 -alkylsulfinyl or C.sub.1 -C.sub.6 -alkylsulfonyl;R.sup.5 =H, halogen, C.sub.1 -C.sub.6 -alkyl;R.sup.6 =H, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -haloalkyl, C.sub.3 -C.sub.6 -cycloalkyl, C.sub.2 -C.sub.6 -alkenyl;R.sup.7 =H, C.sub.1 -C.sub.6 -alkyl, C.sub.3 -C.sub.8 -cycloalkyl, C.sub.1 -C.sub.6 -haloalkyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkynyl, C.sub.1 -C.sub.6 -alkylcarbonyl, C.sub.3 -C.sub.6 -alkenylcarbonyl, C.sub.3 -C.sub.6 -alkynylcarbonyl, C.sub.1 -C.sub.6 -alkoxycarbonyl, C.sub.2 -C.sub.8 -alkenyloxycarbonyl, C.sub.2 -C.sub.6 -alkynyloxycarbonyl, C.sub.1 -C.sub.6 -alkylthiocarbonyl, C.sub.1 -C.sub.6 -alkylsulfonyl, C.sub.1 -C.sub.6 -alkylcarbamoyl, it being possible for the 14 last-mentioned radicals to have attached to them 1-3 substituents:NO.sub.2, CN, halogen, C.sub.3 -C.sub.8 -cycloalkyl, OH, C.sub.1 -C.sub.6 -alkoxy, C.sub.3 -C.sub.8 -cycloalkoxy, C.sub.3 -C.sub.6 -alkenyloxy, C.sub.3 -C.sub.6 -alkynyloxy, C.sub.1 -C.sub.6 -alkoxy-C.sub.1 -C.sub.6 -alkoxy, C.sub.1 -C.sub.6 -alkylthio, C.sub.1 -C.sub.6 -alkylcarbonyl, C.sub.1 -C.sub.6 -alkylcarbonyloxy, C.sub.1 -C.sub.6 -alkylsulfinyl, C.sub.1 -C.sub.6 -alkylsulfonyl, C.sub.1 -C.sub.6 -alkylideneaminoxy, C.sub.1 -C.sub.6 -alkylcarbamoyl,unsubstituted or substituted phenyl, phenoxy or phenylsulfonyl,a 3- to 7-membered heterocyclyl or heterocyclyloxy group having 1-3 hetero atoms, it being possible for this group to be saturated, unsaturated or aromatic and to have attached to it 1-3 substituents,--CO--Z.sup.1 R.sup.9, --OCO--Z.sup.1 R.sup.9, --N(R.sup.9)R.sup.10 orR.sup.7 =unsubstituted or substituted cycloalkylcarbonyl, phenylcarbonyl, phenylsulfonyl, phenylcarbamoyl;R.sup.8 =H, C.sub.1 -C.sub.6 -alkyl, C.sub.3 -C.sub.8 -cycloalkyl, C.sub.1 -C.sub.6 -haloalkyl, C.sub.3 -C.sub.6 -alkenyl or C.sub.3 -C.sub.6 -alkynyl, it being possible for each of the 5 last-mentioned radicals to have attached to it 1-3 substituents:NO.sub.2, CN, halogen, C.sub.3 -C.sub.8 -cycloalkyl, OH, C.sub.1 -C.sub.6 -alkoxy, C.sub.3 -C.sub.8 -cycloalkoxy, C.sub.3 -C.sub.6 -alkenyloxy, C.sub.3 -C.sub.6 -alkynyloxy, C.sub.1 -C.sub.6 -alkoxy-C.sub.1 -C.sub.6 -alkoxy, C.sub.1 -C.sub.6 -alkylthio, C.sub.1 -C.sub.6 -alkylsulfinyl, C.sub.1 -C.sub.6 -alkylsulfonyl, C.sub.1 -C.sub.6 -alkylideneaminoxy,unsubstituted or substituted phenyl- [sic], phenoxy-[sic] or phenylsulfonyl,a 3- to 7-membered heterocyclyl or heterocyclyloxy group having 1-3 hetero atoms, it being possible for this group to be saturated, unsaturated or aromatic and to have attached to it 1-3 substituents,--CO--Z.sup.2 R.sup.11, --OCO--Z.sup.2 R.sup.11, --N(R.sup.11)R.sup.12 ;Z.sup.1 a chemical bond, oxygen, sulfur or --N(R.sup.10)--;Z.sup.2 =a chemical bond, oxygen, sulfur or --N(R.sup.12)--;R.sup.9, R.sup.11 =H, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -haloalkyl, C.sub.3 -C.sub.8 -cycloalkyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkynyl, C.sub.1 -C.sub.6 -alkoxy-C.sub.1 -C.sub.6 -alkyl, (C.sub.1 -C.sub.6 -alkoxy)carbonyl-C.sub.1 -C.sub.6 -alkyl, unsubstituted or substituted phenyl or phenyl-C.sub.1 -C.sub.6 -alkyl,orZ.sup.1 and R.sup.9 and/or Z.sup.2 and R.sup.11 together=a 3- to 7-membered heterocycle having 1-3 hetero atoms and bonded via nitrogen, it being possible for this heterocycle to be saturated, unsaturated or aromatic and, if desired, to have attached to it one to three substituents,R.sup.10, R.sup.12 =H, OH, C.sub.1 -C.sub.6 -alkyl, C.sub.3 -C.sub.8 -cycloalkyl, C.sub.1 -C.sub.6 -alkoxy)and the salts of I where R.sup.3, R.sup.7 and/or R.sup.8 =hydrogenare used as herbicides and for the desiccation/defoliation of plants.