N-Substituted Carbamic Acid Ester Production Method, Isocyanate Production Method Using Such N-Substituted Carbamic Acid Ester, And Composition For Transfer And Storage Of N-Substituted Carbamic Acid Ester Comprising N-Substituted Carbamic Acid Ester and Aromatic Hydroxy Compound
    5.
    发明申请
    N-Substituted Carbamic Acid Ester Production Method, Isocyanate Production Method Using Such N-Substituted Carbamic Acid Ester, And Composition For Transfer And Storage Of N-Substituted Carbamic Acid Ester Comprising N-Substituted Carbamic Acid Ester and Aromatic Hydroxy Compound 有权
    N-取代氨基甲酸酯制造方法,使用这种N-取代氨基甲酸酯的异氰酸酯制造方法以及包含N-取代的氨基甲酸酯和芳香族羟基化合物的N-取代的氨基甲酸酯的转移和储存的组合物

    公开(公告)号:US20110133121A1

    公开(公告)日:2011-06-09

    申请号:US12810668

    申请日:2009-09-29

    IPC分类号: C07C269/04 C07C263/04

    摘要: The present invention is a method for producing an N-substituted carbamic acid ester derived from an organic amine from an organic amine, a carbonic acid derivative and a hydroxy composition containing one or more types of hydroxy compounds, wherein the organic amine, the carbonic acid derivative and the hydroxy composition are reacted using a urethane production reaction vessel provided with a condenser, a gas containing the hydroxy composition, the compound having the carbonyl group derived from the carbonic acid derivative, and an ammonia formed as a by-product in the reaction, is introduced into the condenser provided in the urethane production reaction vessel, and the hydroxy composition and the compound having the carbonyl group derived from the carbonic acid derivative are condensed, and wherein a stoichiometric ratio of a hydroxy compound contained in the condensed hydroxy composition to the condensed compound having the carbonyl group derived from the carbonic acid derivative is 1 or more, and a ratio of number of carbonyl groups (—C(═O)—) contained in the compound having the carbonyl group derived from the carbonic acid derivative and number of ammonia molecules contained in the ammonia recovered as a gas from the condenser is 1 or less.

    摘要翻译: 本发明是由有机胺,碳酸衍生物和含有一种或多种羟基化合物的羟基组合物生产由有机胺衍生的N-取代氨基甲酸酯的方法,其中有机胺,碳酸 衍生物和羟基组合物使用设置有冷凝器,含有羟基组合物的气体,具有衍生自碳酸衍生物的羰基的化合物和在反应中作为副产物形成的氨的氨基甲酸酯制备反应容器进行反应 被引入聚氨酯生产反应容器中的冷凝器中,羟基组合物和衍生自碳酸衍生物的具有羰基的化合物被缩合,其中在缩合羟基组合物中包含的羟基化合物的化学计量比与 具有衍生自碳酸衍生物的羰基的缩合化合物 为1以上,由碳酸衍生物衍生的具有羰基的化合物中所含的羰基数(-C(= O) - ))与作为气体回收的氨中氨分子数的比例 冷凝器为1或更小。