公开(公告)号：US5406015A

公开(公告)日：1995-04-11

申请号：US69260

申请日：1993-05-28

申请人： Jeffrey S. Beck ,  Sharon B. McCullen ,  David H. Olson ,  Chaya R. Venkat

发明人： Jeffrey S. Beck ,  Sharon B. McCullen ,  David H. Olson ,  Chaya R. Venkat

IPC分类号： B01J29/40 ,  B01J37/08 ,  C07C6/12 ,  C07C5/52

CPC分类号： C07C6/123 ,  B01J29/40 ,  B01J37/086 ,  B01J2229/12 ,  B01J2229/32 ,  B01J2229/36 ,  B01J2229/42 ,  C07C2529/40

摘要： A process for shape selective hydrocarbon conversion that involves contacting a hydrocarbon feedsteam, including ethylbenzene, under conversion conditions with a catalytic molecular sieve which has been modified by being ex situ selectivated with a silicon compound. The ex situ selectivation involves exposing the molecular sieve to at least two silicon impregnation sequences, each sequence comprising an impregnation with a silicon compound followed by calcination. The modified catalyst used in the process may also be steamed. Optionally, the modified catalyst may be trim-selectivated.

摘要翻译： 一种用于形状选择性烃转化的方法，其包括在转化条件下将烃类原料（包括乙苯）与通过用硅化合物进行非原位选择性修饰的催化分子筛接触。 异位选择包括将分子筛暴露于至少两个硅浸渍序列，每个序列包含用硅化合物浸渍，随后煅烧。 在该方法中使用的改性催化剂也可以蒸。 任选地，修饰的催化剂可以是修剪选择的。

公开(公告)号：US5348687A

公开(公告)日：1994-09-20

申请号：US157549

申请日：1993-11-26

申请人： Jeffrey S. Beck ,  Guenter H. Kuehl ,  David H. Olson ,  John L. Schlenker ,  Galen D. Stucky ,  James C. Vartuli

发明人： Jeffrey S. Beck ,  Guenter H. Kuehl ,  David H. Olson ,  John L. Schlenker ,  Galen D. Stucky ,  James C. Vartuli

IPC分类号： G02F1/355 ,  G02B1/02 ,  H01L31/0264 ,  H01L31/0344

CPC分类号： B82Y20/00 ,  G02F1/3556

摘要： A material exhibiting third order nonlinear optic properties includes quantum size clusters of semiconducting guest material incorporated into the pores of M41S material in an arrangement to provide nonlinear optic properties.A material exhibiting second order nonlinear optic properties includes an organic guest material incorporated into the pores of M41S material so that a non-centrosymmetric structure is formed which will provide second harmonic generation when subjected to electromagnetic radiation of a selected frequency.

摘要翻译： 显示三阶非线性光学特性的材料包括结合到M41S材料的孔中的半导体客体材料的量子尺寸簇，以提供非线性光学性质。 显示二阶非线性光学性质的材料包括并入M41S材料的孔中的有机载体材料，使得形成非对称中心对称结构，当经受选定频率的电磁辐射时，其将提供二次谐波产生。

公开(公告)号：US5264203A

公开(公告)日：1993-11-23

申请号：US735224

申请日：1991-07-24

申请人： Jeffrey S. Beck ,  Charles T. Kresge ,  Michael E. Leonowicz ,  Wieslaw J. Roth ,  James C. Vartuli

发明人： Jeffrey S. Beck ,  Charles T. Kresge ,  Michael E. Leonowicz ,  Wieslaw J. Roth ,  James C. Vartuli

IPC分类号： B01D53/86 ,  B01J20/02 ,  B01J29/03 ,  B01J29/04 ,  B01J29/40 ,  B01J29/70 ,  B01J29/82 ,  B01J29/83 ,  B01J29/85 ,  C01B37/00 ,  C01B37/02 ,  C01B37/08 ,  C01B39/00 ,  C10G11/05 ,  C10G47/16 ,  C01B33/34

CPC分类号： B01J29/04 ,  B01D53/8628 ,  B01J20/041 ,  B01J20/06 ,  B01J20/08 ,  B01J20/103 ,  B01J20/12 ,  B01J20/18 ,  B01J29/0308 ,  B01J29/041 ,  B01J29/40 ,  B01J29/70 ,  B01J29/82 ,  B01J29/83 ,  B01J29/85 ,  C01B37/00 ,  C01B37/02 ,  C01B37/08 ,  C01B39/00 ,  C10G11/05 ,  C10G47/16 ,  B01J2229/26 ,  B01J2229/32 ,  B01J2229/34 ,  B01J2229/36 ,  B01J2229/40 ,  B01J2229/42

摘要： This invention relates to a new synthetic composition of ultra-large pore crystalline material, e.g., [metallo]silicoaluminophosphate, having a composition, expressed on an anhydrous basis as follows:M.sub.n/q (W.sub.a X.sub.b Y.sub.c Z.sub.d O.sub.h)wherein M is one or more ions; n is the charge of the composition excluding M expressed as oxides; q is the weighted molar average valence of M; n/q is the number of moles or mole fraction of M; W is one or more divalent elements; X is one or more trivalent elements; Y is one or more tetravalent elements; Z is one or more pentavalent elements; a, b, c, and d are mole fractions of W, X, Y, and Z, respectively; (a+b+c+d)=1; a .gtoreq. 0; b, c, and d are each>0; and h is a number of from 1 to 2.5. The crystalline material is prepared by i) crystallizing a reaction mixture comprising sources of W, X, Z and an organic directing agent; ii) contacting the product of i) with a reaction mixture comprising sources of Y and organic directing agent; and iii) maintaining the mixture of ii) under conditions sufficient to form said composition of matter. The composition is suited to use for catalytic conversion of organic compounds.

摘要翻译： 本发明涉及具有如下无水基础的组成的[金属]硅铝磷酸盐的超大孔结晶材料的新合成组合物：Mn / q（WaXbYcZdOh）其中M是一个或多个离子; n是不含M表示为氧化物的组成的电荷; q是M的加权摩尔平均化合价; n / q是M的摩尔数或摩尔分数; W是一个或多个二价元素; X是一个或多个三价元素; Y是一种或多种四价元素; Z是一种或多种五价元素; a，b，c和d分别为W，X，Y和Z的摩尔分数; （a + b + c + d）= 1; a> / = 0; b，c和d各自> 0; h为1〜2.5的数。 晶体材料通过i）使含有W，X，Z和有机导向剂的反应混合物结晶来制备; ii）使i）的产物与包含Y和有机导向剂的反应混合物接触; 和iii）保持ii）的混合物在足以形成所述组合物的条件下。 该组合物适用于有机化合物的催化转化。

公开(公告)号：US5246689A

公开(公告)日：1993-09-21

申请号：US735240

申请日：1991-07-24

申请人： Jeffrey S. Beck ,  William S. Borghard ,  Charles T. Kresge ,  Michael E. Leonowicz ,  Wieslaw J. Roth ,  James C. Vartuli

发明人： Jeffrey S. Beck ,  William S. Borghard ,  Charles T. Kresge ,  Michael E. Leonowicz ,  Wieslaw J. Roth ,  James C. Vartuli

IPC分类号： B01D53/86 ,  B01J20/02 ,  B01J29/03 ,  B01J29/04 ,  B01J29/40 ,  B01J29/70 ,  B01J29/82 ,  B01J29/83 ,  B01J29/85 ,  C01B37/00 ,  C01B37/02 ,  C01B37/08 ,  C01B39/00 ,  C10G11/05 ,  C10G47/16

CPC分类号： C10G11/05 ,  B01D53/8628 ,  B01J20/041 ,  B01J20/06 ,  B01J20/08 ,  B01J20/103 ,  B01J29/0308 ,  B01J29/04 ,  B01J29/041 ,  B01J29/40 ,  B01J29/70 ,  B01J29/82 ,  B01J29/83 ,  B01J29/85 ,  C01B37/00 ,  C01B37/02 ,  C01B37/08 ,  C01B39/00 ,  C10G47/16 ,  B01J2229/26 ,  B01J2229/32 ,  B01J2229/34 ,  B01J2229/36 ,  B01J2229/40 ,  B01J2229/42

摘要： This invention relates to a composition of matter, e.g., silicoaluminate or metalloaluminosilicate, comprising an inorganic, porous crystalline phase material exhibiting, after calcination, an X-ray diffraction pattern with at least one peak at a d-spacing greater than 1.8 nm and having a benzene adsorption capacity of greater than 15 grams benzene per 100 grams of said material at 6.7 kPa (50 torr) and 25.degree. C. wherein said crystalline phase has a composition expressed as follows:M.sub.n/q (W.sub.a X.sub.b Y.sub.c O.sub.h)wherein M is one or more ions; n is the charge of the composition excluding M expressed as oxides; q is the weighted molar average valence of M; n/q is the number of moles or mole fraction of M; W is one or more divalent elements; X is one or more trivalent elements; Y is one or more tetravalent elements; a, b, and c are mole fractions of W, X, and Y, respectively; h is a number of from 1 to 2.5; (a+b+c)=1; and a, b, and c, are each >0.

摘要翻译： 本发明涉及一种物质的组合物，例如硅铝酸盐或金属铝硅酸盐，其包含无机多孔结晶相材料，其在煅烧后表现出具有至少一个d值大于1.8nm的峰的X射线衍射图，并且具有 在6.7kPa（50托）和25℃下每100克所述材料苯吸附量大于15克苯。其中所述结晶相的组成如下表示：Mn / q（WaXbYcOh）其中M是一个或 更多离子 n是不含M表示为氧化物的组成的电荷; q是M的加权摩尔平均化合价; n / q是M的摩尔数或摩尔分数; W是一个或多个二价元素; X是一个或多个三价元素; Y是一种或多种四价元素; a，b和c分别是W，X和Y的摩尔分数; h是从1到2.5的数字; （a + b + c）= 1; 和a，b和c分别为> 0。

公开(公告)号：US5145816A

公开(公告)日：1992-09-08

申请号：US718056

申请日：1991-06-20

申请人： Jeffrey S. Beck ,  David C. Calabro ,  Sharon B. McCullen ,  Bruce P. Pelrine ,  Kirk D. Schmitt ,  James C. Vartuli

发明人： Jeffrey S. Beck ,  David C. Calabro ,  Sharon B. McCullen ,  Bruce P. Pelrine ,  Kirk D. Schmitt ,  James C. Vartuli

IPC分类号： B01J20/10 ,  B01D53/86 ,  B01J20/02 ,  B01J29/03 ,  B01J29/04 ,  B01J29/06 ,  B01J29/40 ,  B01J29/70 ,  B01J29/82 ,  B01J29/83 ,  B01J29/85 ,  C01B37/00 ,  C01B37/02 ,  C01B37/08 ,  C01B39/00 ,  C01B39/04 ,  C01B39/06 ,  C01B39/48 ,  C10G11/05 ,  C10G47/16

CPC分类号： B01D53/8628 ,  B01J20/041 ,  B01J20/06 ,  B01J20/08 ,  B01J20/103 ,  B01J20/12 ,  B01J20/18 ,  B01J20/3078 ,  B01J29/0308 ,  B01J29/04 ,  B01J29/041 ,  B01J29/045 ,  B01J29/40 ,  B01J29/82 ,  B01J29/83 ,  B01J29/85 ,  C01B37/00 ,  C01B37/02 ,  C01B37/08 ,  C01B39/00 ,  C10G11/05 ,  C10G47/16 ,  B01J2229/12 ,  B01J2229/14 ,  B01J2229/26 ,  B01J2229/32 ,  B01J2229/34 ,  B01J2229/40 ,  B01J2229/42

摘要： A method is described for modifying an ultra-large pore crystalline material by contacting with a treatment composition M'X'Y'.sub.n wherein M' is an element of Groups IIA, IVA, VA, VIA, VIIA, IB, IIB, IVB, VB or VIB; X' is halide, hydride, alkoxide of C.sub.1-6', or acetate; Y' is X or phosphine, sulfide, carbonyl or cyano; and N=1-5. The contacted crystalline material becomes functionalized. The functionalized material is also described and can be used as a sorbent or catalyst component.

摘要翻译： 描述了通过与处理组合物M'X'Y'n接触来改性超大孔结晶材料的方法，其中M'是IIA，IVA，VA，VIA，VIIA，IB，IIB，IVB，IVB族的元素， VB或VIB; X'是卤化物，氢化物，C1-6'的醇盐或乙酸盐; Y'是X或膦，硫化物，羰基或氰基; N = 1-5。 接触的结晶材料变得官能化。 还描述了官能化材料并且可以用作吸附剂或催化剂组分。