Abstract:
An object is to suppress electrochemical decomposition of an electrolyte solution and the like at a negative electrode in a lithium ion battery or a lithium ion capacitor; thus, irreversible capacity is reduced, cycle performance is improved, or operating temperature range is extended. A negative electrode for a power storage device including a negative electrode current collector, a negative electrode active material layer which is over the negative electrode current collector and includes a plurality of particles of a negative electrode active material, and a film covering part of the negative electrode active material. The film has an insulating property and lithium ion conductivity.
Abstract:
An object is to suppress electrochemical decomposition of an electrolyte solution and the like at a negative electrode in a lithium ion battery or a lithium ion capacitor; thus, irreversible capacity is reduced, cycle performance is improved, or operating temperature range is extended. A negative electrode for a power storage device including a negative electrode current collector, a negative electrode active material layer which is over the negative electrode current collector and includes a plurality of particles of a negative electrode active material, and a film covering part of the negative electrode active material. The film has an insulating property and lithium ion conductivity.
Abstract:
A power storage device which can have an improved performance such as higher discharge capacity and in which deterioration due to peeling of an active material layer or the like is difficult to occur, and a method for manufacturing the power storage device are provided. The power storage device includes a current collector, a mixed layer formed over the current collector, and a crystalline silicon layer which is formed over the mixed layer and functions as an active material layer. The crystalline silicon layer includes a crystalline silicon region and a whisker-like crystalline silicon region including a plurality of protrusions projecting over the crystalline silicon region. The whisker-like crystalline silicon region includes a protrusion having a bending or branching portion.
Abstract:
A power storage device is reduced in weight. A metal sheet serving as a negative electrode current collector is separated and another negative electrode current collector is formed. For example, through the step of forming silicon serving as a negative electrode active material layer over a titanium sheet and then performing heating, the titanium sheet can be separated. Then, another negative electrode current collector with a thickness of more than or equal to 10 nm and less than or equal to 1 μm is formed. Thus, light weight of the power storage device can be achieved.
Abstract:
A power storage device with high capacity or high energy density is provided. A highly reliable power storage device is provided. A long-life power storage device is provided. An electrode includes an active material, a first binder, and a second binder. The specific surface area of the active material is S [m2/g]. The weight of the active material, the weight of the first binder, and the weight of the second binder are a, b, and c, respectively. The solution of {(b+c)/(a+b+c)}×100÷S is 0.3 or more. The electrode includes a first film in contact with the active material. The first film preferably includes a region in contact with the active material. The first film preferably includes a region with a thickness of 2 nm or more and 20 nm or less. The first film contains a water-soluble polymer.
Abstract:
To provide a highly reliable power storage device. To provide a long-life power storage device. To provide a power storage device electrode having high adhesion with a current collector. To reduce or inhibit electrochemical decomposition of an electrolytic solution or the like on a surface of an electrode. The power storage device electrode includes a current collector and a second electrode layer provided over the current collector and including a second binder and an active material. A first electrode layer including a first binder and conductive particles is provided between the current collector and the second electrode layer. At least part of a surface of the active material is provided with a coating film, and the coating film is porous.
Abstract:
A secondary battery that can inhibit deterioration of an electrode is provided. A flexible secondary battery is provided. The secondary battery includes a positive electrode, a negative electrode, a separator, a first spacer, a second spacer, a positive electrode lead, a negative electrode lead, and an exterior body. The positive electrode includes a first portion coated with a positive electrode active material and a second portion where a positive electrode current collector is exposed. The negative electrode includes a third portion coated with a negative electrode active material and a fourth portion where a negative electrode current collector is exposed. The first portion, the third portion, and the separator overlap with each other in a stacked portion. The positive electrode lead is connected to the second portion in a position overlapping with the stacked portion. The negative electrode lead is connected to the fourth portion in a position overlapping with the stacked portion. The first spacer is in contact with the exterior body in a region surrounded by one end portion of the stacked portion, the positive electrode lead, and the negative electrode lead. The second spacer includes a region interposed between the stacked portion and the second portion, a region interposed between the stacked portion and the fourth portion, and a region connected to the first spacer.
Abstract:
To provide a battery having excellent charge-discharge characteristics even in a low-temperature environment. The battery includes a positive electrode, a negative electrode, an electrolyte solution, and a separator. The electrolyte solution and the separator are included between the positive electrode and the negative electrode; the negative electrode includes a carbon material; and the electrolyte solution includes a lithium salt, a potassium salt, a fluorinated cyclic carbonate, a fluorinated linear carbonate, and at least one kind of anion. The carbon material includes graphite; the lithium salt includes LiPF6; the potassium salt includes KFSI; the fluorinated cyclic carbonate includes fluoroethylene carbonate; and the fluorinated linear carbonate includes methyl trifluoropropionate.
Abstract:
An all-solid-state secondary battery having a higher level of safety than a conventional lithium-ion secondary battery using an electrolyte solution, specifically, a thin-film-type solid-state secondary battery, and a manufacturing method thereof are provided. As a solid electrolyte, a mixed material obtained by co-evaporation of SiO and an organic complex of lithium is used. That is, a solid electrolyte layer formed using a mixed material of an inorganic material and an organic material is used in a solid-state secondary battery. The ratio of oxygen to silicon in the solid electrolyte layer is higher than 1 and lower than 2.
Abstract:
Novel graphene is provided. A novel graphene compound is provided. An electrode having a high output is provided. A novel electrode is provided. A secondary battery with little deterioration is provided. A secondary battery with a high degree of safety is provided. Graphene has a vacancy formed with a many-membered ring that is a nine- or more-membered ring composed of carbon atoms. One or more of the carbon atoms included in the many-membered ring are terminated with fluorine.