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    Process for displacing the double bond in olefins using a catalytic composition based on transition metal complexes
    63.
    发明授权
    Process for displacing the double bond in olefins using a catalytic composition based on transition metal complexes 失效
    使用基于过渡金属络合物的催化组合物来置换烯烃中的双键的方法

    公开(公告)号：US5780702A

    公开(公告)日：1998-07-14

    申请号：US664561

    申请日：1996-06-17

    申请人： Yves Chauvin ,  Lothar Mussmann ,  Helene Olivier

    发明人： Yves Chauvin ,  Lothar Mussmann ,  Helene Olivier

    IPC分类号： B01J31/24 ,  C07B61/00 ,  C07C5/25 ,  C07C11/02 ,  C07C11/10 ,  C07C5/23

    CPC分类号： C07C5/2562

    摘要： A catalytic composition comprises at least one quaternary ammonium and/or phosphonium salt in which the anion is preferably selected from the group formed by tetrafluoroborate, tetrachloroborate, hexafluorophosphate, hexafluoroantimonate, hexafluoroarsenate, trifluorosulphonate, fluorosulphonate, tetrachloroaluminate, dichlorocuprate, and trichlorozincate, and at least one complex of a transition metal from groups 8, 9 and 10, i.e., iron, ruthenium, cobalt, rhodium, iridium, nickel, palladium and platinum, is for the displacement of the double bond in olefins.

    摘要翻译： 催化剂组合物包含至少一种季铵盐和/或鏻盐，其中阴离子优选选自四氟硼酸盐，四氯硼酸盐，六氟磷酸盐，六氟锑酸盐，六氟砷酸盐，三氟磺酸盐，氟磺酸盐，四氯铝酸盐，二氯磷酸盐和三氯酸锌形成的基团， 来自组8,9和10的过渡金属的一个复合物，即铁，钌，钴，铑，铱，镍，钯和铂，用于在烯烃中置换双键。

    Process for codimerization of dienes and olefins
    67.
    发明授权
    Process for codimerization of dienes and olefins 失效
    二烯和烯烃的同分异构化方法

    公开(公告)号：US5476956A

    公开(公告)日：1995-12-19

    申请号：US232984

    申请日：1994-04-25

    申请人： Gerard Hillion ,  Robert Stern ,  Abakar Kotoko ,  Yves Chauvin

    发明人： Gerard Hillion ,  Robert Stern ,  Abakar Kotoko ,  Yves Chauvin

    IPC分类号： B01J27/13 ,  B01J31/16 ,  C07B37/02 ,  C07B61/00 ,  C07C2/04 ,  C07C2/38 ,  C07C11/12 ,  C07C67/347 ,  C07C69/65 ,  C09F7/06

    CPC分类号： C07C2/04 ,  C07B37/02 ,  C07C67/347 ,  C07C2531/22

    摘要： Co dimerization is conducted of at least one monoolefin, for example a monoolefinic hydrocarbon such as ethylene, propylene or 1-butene, a halogenated monoolefin such as vinyl chloride, or an olefinic functional compound such as methyl acrylate, acrylonitrile, allyl acetate or vinyl acetate, with at least one polyolefin containing at least two conjugated or unconjugated ethylene bonds, for example a diene hydrocarbon such as 1,3-butadiene, piperylene, or isoprene or a polyolefin containing a carboxylic function, such as a fatty acid or a fatty acid ester having 14 to 24 carbon atoms in the fatty chain derived, for example, from a natural oil. The reaction is carried out in the presence of a catalytic system having general formula [RhX.sub.4 ][YR.sub.4 ] where X represents a halogen ion or a SO.sub.4.sup.--, SO.sub.3.sup.-, OH.sup.-, OR.sup.- or R.sup.- group, at least one X being a halogen ion, Y represents a nitrogen atom or a phosphorous atom, and R represents an alkyl, cycloalkyl, alkenyl, aryl, alkylaryl, polystyryl, alkyl polystyryl or acyl radical.

    摘要翻译： Co二聚化由至少一种单烯烃，例如单烯烃如乙烯，丙烯或1-丁烯，卤代单烯烃如氯乙烯或烯属官能化合物如丙烯酸甲酯，丙烯腈，乙酸烯丙酯或乙酸乙烯酯 与至少一种含有至少两个共轭或非共轭的乙烯键的聚烯烃，例如二烯烃如1,3-丁二烯，戊间二烯或异戊二烯或含有羧酸官能团的聚烯烃如脂肪酸或脂肪酸 在脂肪链中具有14至24个碳原子的酯衍生自例如天然油。 该反应在具有通式[RhX4] [YR4]的催化体系存在下进行，其中X表示卤素离子或SO 4 - ，SO 3 - ，OH-，OR-或R-基团，至少一个X 作为卤素离子，Y表示氮原子或磷原子，R表示烷基，环烷基，烯基，芳基，烷基芳基，聚苯乙烯基，烷基聚苯乙烯基或酰基。