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1.发明授权Catalytic composition based on transition metal complexes, and a process for the hydrogenation of unsaturated compounds 失效基于过渡金属络合物的催化组合物，以及不饱和化合物氢化的方法
公开(公告)号：US5852130A
公开(公告)日：1998-12-22
申请号：US664539
申请日：1996-06-17
Applicant: Lothar Mussmann , Yves Chauvin , Helene Olivier
Inventor： Lothar Mussmann , Yves Chauvin , Helene Olivier
IPC: B01J31/22 , B01J23/46 , B01J31/02 , B01J31/16 , B01J31/24 , C07B61/00 , C07C5/03 , C07C5/11 , C07C9/00 , C07C13/20 , C07C13/58 , C08F8/04
CPC classification number: B01J31/16 , B01J31/0278 , B01J31/0284 , B01J31/0288 , B01J31/20 , B01J31/2291 , B01J31/2404 , B01J31/2409 , B01J2231/645 , B01J23/462 , B01J23/464 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/827 , B01J2531/828 , B01J2531/845
Abstract: A novel catalytic composition comprises at least one quaternary ammonium and/or phosphonium salt in which the anion is selected from the group formed by tetrafluoroborate, tetrachloroborate, hexafluorophosphate, hexafluoroantimonate, hexafluoroarsenate, trifluorosulphonate, fluorosulphonate, tetrachloroaluminate, dichlorocuprate, and trichlorozincate, and at least one complex of a transition metal from groups 8, 9 and 10, i.e., iron, ruthenium, cobalt, rhodium iridium, nickel, palladium and platinum. Application to total or selective hydrogenation of unsaturated compounds such as monoolefins, diolefins, acetylenic compounds, aromatic compounds, polynuclear aromatic compounds. Hydrogenation may be accompanied by isomerisation.
Abstract translation: 一种新型催化剂组合物包含至少一种季铵盐和/或鏻盐，其中阴离子选自四氟硼酸盐，四氯硼酸盐，六氟磷酸盐，六氟锑酸盐，六氟砷酸盐，三氟磺酸盐，氟磺酸盐，四氯铝酸盐，二氯磷酸盐和三氯酸锌形成的基团， 来自组8,9和10的过渡金属的一个复合物，即铁，钌，钴，铑铱，镍，钯和铂。 适用于单烯烃，二烯烃，炔属化合物，芳香族化合物，多核芳香族化合物等不饱和化合物的全部或选择性氢化。 氢化可伴随异构化。
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公开(公告)号：US5874638A
公开(公告)日：1999-02-23
申请号：US755853
申请日：1996-12-02
Applicant: Yves Chauvin , Helene Olivier , Lothar Mussmann
Inventor： Yves Chauvin , Helene Olivier , Lothar Mussmann
CPC classification number: C07C45/50
Abstract: A hydroformylation process for unsaturated compounds such as monoolefins and diolefins is carried out in an ionic medium in which the catalytic species is dissolved, but in which the reaction products (aldehydes) formed are only slightly soluble or are insoluble. The ionic medium is liquid at a temperature below 90.degree. C. and comprises at least one quaternary ammonium and/or phosphonium cation and at least one anion which is preferably selected from the group formed by tetrafluoroborate when the cation is ammonium, hexafluorophosphate, hexafluoroantimonate, hexafluoroarsenate, perfluoroalkylsulphonates, fluorosulphonate, bis-perfluoroalkylsulphonyl amides or dichlorocuprate, tetrachlorocuprate, tetrachloroaluminate, or trichlorozincate. At the end of the reaction, the organic phase is separated out and the polar phase containing the catalyst is used again.
Abstract translation: 用于不饱和化合物如单烯烃和二烯烃的加氢甲酰化方法在其中溶解催化物质的离子介质中进行，但其中形成的反应产物（醛）仅仅是微溶或不溶解的。 离子介质在低于90℃的温度下是液体，并且包含至少一种季铵和/或鏻阳离子和至少一种阴离子，当阳离子是铵，六氟磷酸盐，六氟锑酸盐时，优选选自四氟硼酸盐形成的基团， 六氟砷酸盐，全氟烷基磺酸盐，氟磺酸盐，双全氟烷基磺酰胺或二氯磷酸盐，四氯磷酸盐，四氯铝酸盐或三氯酸锌。 在反应结束时，分离有机相，再次使用含有催化剂的极性相。
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3.发明授权Catalytic composition based on transition metal complexes, and a process for the hydrogenation of unsaturated compounds 有权基于过渡金属络合物的催化组合物，以及不饱和化合物氢化的方法
公开(公告)号：US6040263A
公开(公告)日：2000-03-21
申请号：US154402
申请日：1998-09-15
Applicant: Lothar Mussmann , Yves Chauvin , Helene Olivier
Inventor： Lothar Mussmann , Yves Chauvin , Helene Olivier
IPC: B01J31/22 , B01J23/46 , B01J31/02 , B01J31/16 , B01J31/24 , C07B61/00 , C07C5/03 , C07C5/11 , C07C9/00 , C07C13/20 , C07C13/58 , B01J31/00 , C07C5/02 , C07C5/05 , C07C5/10
CPC classification number: B01J31/16 , B01J31/0278 , B01J31/0284 , B01J31/0288 , B01J31/20 , B01J31/2291 , B01J31/2404 , B01J31/2409 , B01J2231/645 , B01J23/462 , B01J23/464 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/827 , B01J2531/828 , B01J2531/845
Abstract: A novel non-aqueous catalytic composition comprises at least one quaternary ammonium and/or phosphonium salt in which the anion is selected from the group consisting of tetrafluoroborate, tetrachloroborate, hexafluorophosphate, hexafluoroantimonate, hexafluoroarsenate, trifluorosulphonate, fluorosulphonate, trifluoromethylsulphonate, trifluoroarsenate, dichlorocuprate, trichlorocuprate, tetrachlorocuprate, and trichlorozincate, and at least one complex of a transition metal from groups 8, 9 or 10, i.e., iron, ruthenium, colbalt, rhodium iridium, nickel, palladium and platinum. The catalyst can be used in a process of total or selective hydrogenation of unsaturated compounds such as monoolefins, diolefins, acetylene compounds, aromatic compounds, or polynuclear aromatic compounds. Hydrogenation may be accompanied by isomerisation.
Abstract translation: 一种新型非水催化剂组合物包含至少一种季铵盐和/或鏻盐，其中阴离子选自四氟硼酸盐，四氯硼酸盐，六氟磷酸盐，六氟锑酸盐，六氟砷酸盐，三氟磺酸盐，氟磺酸盐，三氟甲基磺酸盐，三氟砷酸盐，二氯磷酸盐，三氯代磷酸盐 四氯蔗糖和三氯酸锌，以及至少一种来自组8,9或10的过渡金属络合物，即铁，钌，钴，铑，铱，镍，钯和铂。 催化剂可用于不饱和化合物如单烯烃，二烯烃，乙炔化合物，芳香族化合物或多核芳族化合物的全部或选择性氢化的方法。 氢化可伴随异构化。
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4.发明授权Process for displacing the double bond in olefins using a catalytic composition based on transition metal complexes 失效使用基于过渡金属络合物的催化组合物来置换烯烃中的双键的方法
公开(公告)号：US5780702A
公开(公告)日：1998-07-14
申请号：US664561
申请日：1996-06-17
Applicant: Yves Chauvin , Lothar Mussmann , Helene Olivier
Inventor： Yves Chauvin , Lothar Mussmann , Helene Olivier
CPC classification number: C07C5/2562
Abstract: A catalytic composition comprises at least one quaternary ammonium and/or phosphonium salt in which the anion is preferably selected from the group formed by tetrafluoroborate, tetrachloroborate, hexafluorophosphate, hexafluoroantimonate, hexafluoroarsenate, trifluorosulphonate, fluorosulphonate, tetrachloroaluminate, dichlorocuprate, and trichlorozincate, and at least one complex of a transition metal from groups 8, 9 and 10, i.e., iron, ruthenium, cobalt, rhodium, iridium, nickel, palladium and platinum, is for the displacement of the double bond in olefins.
Abstract translation: 催化剂组合物包含至少一种季铵盐和/或鏻盐，其中阴离子优选选自四氟硼酸盐，四氯硼酸盐，六氟磷酸盐，六氟锑酸盐，六氟砷酸盐，三氟磺酸盐，氟磺酸盐，四氯铝酸盐，二氯磷酸盐和三氯酸锌形成的基团， 来自组8,9和10的过渡金属的一个复合物，即铁，钌，钴，铑，铱，镍，钯和铂，用于在烯烃中置换双键。
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5.发明授权Complexes and method for synthesis of group 4 organometallics grafted on anions olefin oligomerization and polymerization method 失效用于合成第4族有机金属化合物的络合物和方法接枝在阴离子烯烃低聚和聚合方法上公开(公告)号：US08470940B2
公开(公告)日：2013-06-25
申请号：US12667557
申请日：2008-07-03
Applicant: Christine Bibal , Catherine Santini , Yves Chauvin , Helene Olivier-Bourbigou , Christophe Vallee
Inventor： Christine Bibal , Catherine Santini , Yves Chauvin , Helene Olivier-Bourbigou , Christophe Vallee
CPC classification number: C07F17/00 , C07F7/00 , C08F4/65912 , C08F10/00 , C08F10/02 , C08F2410/03 , C08F4/659 , C08F4/65908 , C08F4/643 , C08F4/65925
Abstract: Novel group 4 organometallic compounds, supported on anions by means of at least one covalent metal-oxygen bond, are obtained by reaction of at least one borate or aluminum comprising at least one hydroxy group with at least one group 4 transition metal compound. These compounds are used in a catalytic composition implemented in an olefin oligomerization or polymerization method.
Abstract translation: 通过至少一种包含至少一个羟基的硼酸盐或铝与至少一种4族过渡金属化合物的反应获得通过至少一种共价金属 - 氧键负载在阴离子上的新型4族有机金属化合物。 这些化合物用于以烯烃低聚或聚合方法实施的催化组合物。
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Patent Agency Ranking
6.发明申请公开(公告)号：US20100286349A1
公开(公告)日：2010-11-11
申请号：US12667557
申请日：2008-07-03
Applicant: Christine Bibal , Catherine Santini , Yves Chauvin , Helene Olivier-Bourbigou , Christophe Vallee
Inventor： Christine Bibal , Catherine Santini , Yves Chauvin , Helene Olivier-Bourbigou , Christophe Vallee
IPC: C08F4/52 , C07D233/58 , C07F9/54 , C07D207/06 , B01J31/14
CPC classification number: C07F17/00 , C07F7/00 , C08F4/65912 , C08F10/00 , C08F10/02 , C08F2410/03 , C08F4/659 , C08F4/65908 , C08F4/643 , C08F4/65925
Abstract: Novel group 4 organometallic compounds, supported on anions by means of at least one covalent metal-oxygen bond, are obtained by reaction of at least one borate or aluminium comprising at least one hydroxy group with at least one group 4 transition metal compound. These compounds are used in a catalytic composition implemented in an olefin oligomerization or polymerization method.
Abstract translation: 通过至少一种包含至少一个羟基的硼酸盐或铝与至少一种4族过渡金属化合物的反应获得通过至少一种共价金属 - 氧键负载在阴离子上的新型4族有机金属化合物。 这些化合物用于以烯烃低聚或聚合方法实施的催化组合物。
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7.发明授权Aliphatic alkylation catalyst comprising an active phase containing a cuprous compound on a support 失效脂肪族烷基化催化剂包含在载体上含有亚铜化合物的活性相
公开(公告)号：US5693585A
公开(公告)日：1997-12-02
申请号：US664538
申请日：1996-06-17
Applicant: Eric Benazzi , Yves Chauvin , Andre Hirschauer , Nathalie Ferrer , Helene Olivier , Jean-Yves Bernhard
Inventor： Eric Benazzi , Yves Chauvin , Andre Hirschauer , Nathalie Ferrer , Helene Olivier , Jean-Yves Bernhard
IPC: B01J21/08 , B01J27/125 , B01J31/02 , B01J31/26 , B01J31/28 , B01J32/00 , B01J35/02 , B01J35/10 , C07B61/00 , C07C2/58 , C07C2/60 , C07C9/16 , B01J27/122 , B01J27/25 , B01J31/00
CPC classification number: C07C2/60 , B01J31/0294 , B01J31/26 , B01J31/28 , B01J31/30 , B01J21/08 , B01J2231/323 , B01J35/023 , B01J35/1019 , B01J35/1047 , C07C2521/08 , C07C2527/053 , C07C2527/122 , C07C2527/125 , C07C2527/126 , C07C2527/24 , C07C2531/02 , C07C2531/04 , Y02P20/584
Abstract: A catalyst containing a porous organic or mineral support and at least one active phase having at least one aluminum halide, at least one compound selected for quaternary ammonium halides and amine hydrohalides, and at least one cuprous compound, the support having been impregnated with the active phase, the catalyst essentially constituted by particles with an average diameter in the range 0.1 .mu.m to 150 .mu.m, and the support, before impregnation with the active phase, has a total pore volume in the range 0.1 cm.sup.3 /g and 6 cm.sup.3 /g.
Abstract translation: 含有多孔有机或矿物载体和至少一种具有至少一种卤化铝，至少一种选自季铵卤化物和胺氢卤化物的化合物和至少一种亚铜化合物的活性相的催化剂，该载体已经浸渍有活性 相，催化剂基本上由平均直径在0.1μm至150μm的颗粒构成，并且在用活性相浸渍之前，载体的总孔体积在0.1cm 3 / g和6cm 3 / G。
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8.发明授权Process for producing organolanthanides, the resultant compounds and their use 失效生产有机镧系元素的方法，所得化合物及其用途
公开(公告)号：US4845201A
公开(公告)日：1989-07-04
申请号：US146752
申请日：1988-01-22
Applicant: Yves Chauvin , Dominique Commereuc , Francois Hugues , Helene Olivier , Lucien Saussine
Inventor： Yves Chauvin , Dominique Commereuc , Francois Hugues , Helene Olivier , Lucien Saussine
CPC classification number: C22B59/00 , C07C29/143 , C07C45/61 , C07C45/62 , C07C45/65 , C07C5/03 , C07F5/00 , C08F4/42 , C07C2103/24 , C07C2531/12 , Y02P20/52
Abstract: A process for producing organolanthanides by reaction of a rare-earth metal with an unsaturated compound in an ether medium, the resultant compounds and the use of these compounds in organic synthesis and for catalysis is disclosed. The process is conducted at -80.degree. to +100.degree. C., in the absence of oxygen and any compound having active protons. The resultant compounds are useful as catalysts, e.g., in the hydrogenation of olefins and diolefins and in the polymerization thereof, and are useful as chemical intermediates.
Abstract translation: 公开了一种通过稀土金属与不饱和化合物在醚介质中反应制备有机镧系元素的方法，所得化合物以及这些化合物在有机合成和催化中的用途。 该方法在-80℃至+ 100℃下进行，在不存在氧气和任何具有活性质子的化合物的情况下进行。 所得化合物可用作催化剂，例如在烯烃和二烯烃的氢化中和在其聚合反应中，并且可用作化学中间体。
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9.发明授权
公开(公告)号：US5502018A
公开(公告)日：1996-03-26
申请号：US309703
申请日：1994-09-21
Applicant: Yves Chauvin , Sandra Einloft , Helene Olivier
Inventor： Yves Chauvin , Sandra Einloft , Helene Olivier
IPC: B01J31/02 , B01J31/14 , B01J31/18 , B01J31/22 , B01J31/24 , C07B61/00 , C07C2/32 , C07C2/36 , C07C11/02 , C10G50/00 , B01J27/185
CPC classification number: C07C2/36 , B01J31/143 , B01J31/181 , B01J31/24 , B01J31/2404 , B01J2231/20 , B01J2531/847 , B01J2531/90 , B01J31/0234 , B01J31/2208 , C07C2527/128 , C07C2531/14 , C07C2531/22 , C07C2531/24
Abstract: The invention concerns a catalytic composition and a process for the dimerization, codimerization or oligomerization of olefins, said composition comprising a mixture of at least one bivalent nickel complex which contains two tertiary phosphine molecules, at least one nickel compound or complex compound which contains neither water nor phosphine, and at least one alkylaluminum halide. The mixture is particularly for use in ionic type non aqueous liquid compositions, such as those formed by quaternary ammonium halides and/or quaternary phosphonium halides with aluminum halides and/or alkylaluminum halides.
Abstract translation: 本发明涉及一种催化组合物和烯烃二聚，共二聚或低聚的方法，所述组合物包含至少一种含有两个叔膦分子的二价镍络合物的混合物，至少一种不含水的镍化合物或络合物 也不是膦，以及至少一种烷基铝卤化物。 该混合物特别用于离子型非水性液体组合物，例如由具有卤化铝和/或烷基卤化铝的季铵卤化物和/或季卤化鏻形成的那些。
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公开(公告)号：US5550306A
公开(公告)日：1996-08-27
申请号：US456820
申请日：1995-06-01
Applicant: Yves Chauvin , Sandra Einloft , Helene Olivier
Inventor： Yves Chauvin , Sandra Einloft , Helene Olivier
CPC classification number: B01J27/125 , B01J31/0284 , B01J31/0288 , B01J31/143 , B01J31/24 , C07C2/36 , B01J2231/20 , B01J2531/847 , C07C2531/22 , C07C2531/24
Abstract: The invention is concerned with a process for the dimerization, co-dimerization and oligomerization of olefins with a catalytic composition resulting from mixing at least one quaternary ammonium halide and/or at least one quaternary phosphonium halide, at least one aluminum halide, at least one aromatic hydrocarbon and optionally an aluminium organometallic compound.
Abstract translation: 本发明涉及一种通过将至少一种季铵卤化物和/或至少一种季鏻卤化物，至少一种卤化铝和至少一种卤化铝混合而得到的催化组合物进行烯烃二聚，共二聚和低聚的方法 芳族烃和任选的铝有机金属化合物。
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