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    Disazo dyes containing an acetoacetabukube coupling component and a quaternized aminoalkylene aminocarbonyl group bound to it
    61.
    发明授权
    Disazo dyes containing an acetoacetabukube coupling component and a quaternized aminoalkylene aminocarbonyl group bound to it 失效
    含有乙酰乙酰尿素偶联组分的双偶氮染料和与其结合的季铵化氨基亚烷基氨基羰基

    公开(公告)号：US4921945A

    公开(公告)日：1990-05-01

    申请号：US198266

    申请日：1988-05-25

    申请人： Willy Stingelin

    发明人： Willy Stingelin

    IPC分类号： C09B44/06 ,  C09B44/02 ,  D06P1/08 ,  D21H11/06 ,  D21H19/10 ,  D21H21/28

    CPC分类号： D21H21/28 ,  C09B44/02 ,  D21H11/06

    摘要： Disazo dyes which are useful for dyeing and printing, of the formula ##STR1## in which: D is the radical of a substituted or unsubstituted, homocyclic or heterocyclic diazo component, V.sup.1 and V.sup.2 independently of one another are hydrogen, substituted or unsubstituted C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy, halogen or cyano, X is hydrogen, substituted or unsubstituted C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy, halogen, cyano or a group of the formula --NH--CHO, --NH--CO--NH.sub.2, --NH--CO--NH--Q or --NH--CO--(0).sub.m --Q in which m is zero or 1 and Q is substituted or unsubstituted C.sub.1 -C.sub.4 alkyl or phenyl, Z is C.sub.1 -C.sub.4 alkyl--CO--, --CN, --COO--C.sub.1 -C.sub.4 alkyl, --CONH.sub.2 or --CO--C.sub.6 H.sub.5, R.sup.1, R.sup.2 and R.sup.3 independently of one another are in each case a substituted or unsubstituted alkyl radical or R.sup.1 and R.sup.2, together with the nitrogen atom linking them, or R.sup.1, R.sup.2 and R.sup.3, together with the nitrogen atom linking them, are a heterocyclic radical, A is an alkylene radical having 2 to 6 C atoms, n is 1 or 2 and An.sup..crclbar. is an anion.

    摘要翻译： 可用于染色和印花的双偶氮染料，其分子式为：其中：D为取代或未取代的双环或双环重氮组分，V1和V2彼此独立的基团为氢 取代或未取代的C 1 -C 4烷基或C 1 -C 4烷氧基，卤素或氰基，X为氢，取代或未取代的C 1 -C 4烷基或C 1 -C 4烷氧基，卤素，氰基或式-NH-CHO，-NH-CO- NH 2，-NH-CO-NH-Q或-NH-CO-（O）mQ，其中m为0或1，Q为取代或未取代的C 1 -C 4烷基或苯基，Z为C 1 -C 4烷基-CO-，-CN 在各种情况下，-COO-C 1 -C 4烷基，-CONH 2或-CO-C 6 H 5，R 1，R 2和R 3彼此独立地为取代或未取代的烷基或R 1和R 2与连接它们的氮原子或R 1 ，R2和R3与连接它们的氮原子一起是杂环基，A是具有2至6个C原子的亚烷基，n是1或2，An（ - ）是阴离子。

    Sulfo group-containing basic azo compounds having a central 1,3,5-triazine ring and two terminal 1-hydroxynaphthyl-2 groups and 1:1 and 1:2 metal complexes therof
    62.
    发明授权
    Sulfo group-containing basic azo compounds having a central 1,3,5-triazine ring and two terminal 1-hydroxynaphthyl-2 groups and 1:1 and 1:2 metal complexes therof 失效
    含有磺基的碱性偶氮化合物，具有中心的1,3,5-三嗪环和两个末端的1-羟基萘基-2和1：1和1：2的金属络合物

    公开(公告)号：US4742160A

    公开(公告)日：1988-05-03

    申请号：US834976

    申请日：1986-02-28

    申请人： Jacky Dore ,  Reinhard Pedrazzi

    发明人： Jacky Dore ,  Reinhard Pedrazzi

    IPC分类号： C09B35/039 ,  C09B43/16 ,  C09B44/02 ,  C09B44/06 ,  C09B45/24 ,  C09B62/095 ,  D06P1/02 ,  D06P1/41 ,  D06P3/32 ,  D21H19/10 ,  D21H21/28 ,  C09B35/18 ,  C09B44/08 ,  C09B45/26

    CPC分类号： D06P3/3226 ,  C09B43/16 ,  C09B44/02 ,  C09B62/095 ,  D06P1/02 ,  D21H21/28

    摘要： Metal-free compounds of the formula ##STR1## and 1:1 and 1:2 metal complexes thereof, and salts of the metal-free compounds and 1:1 and 1:2 metal complexes, whereR is hydrogen, --SO.sub.3 H or --NR.sub.5 R.sub.6 ;R.sub.a is hydrogen or --NR.sub.5 R.sub.6 ;R.sub.1 is hydrogen, halogen, --OH, C.sub.1-4 alkyl, C.sub.1-4 alkoxy or --SO.sub.3 H;R.sub.3 is hydrogen or C.sub.1-4 alkyl;R.sub.4 is halogen, --OH, C.sub.1-4 alkyl, C.sub.1-4 alkoxy, phenyl, --NH.sub.2, an aliphatic, cycloaliphatic or aromatic amino group, a heterocyclic amino group containing 1 to 3 hereto atoms or a hydrazino group,R.sub.5 is hydrogen or C.sub.1-4 alkyl; andR.sub.6 is an organic radical, are useful as cationic dyes for dyeing and printing fibers, threads and textile materials comprising, for example, a natural or regenerated cellulosic material such as cotton, a modified synthetic polyamide or polyester, and a homo- or co-polymer of acrylonitrile or 1,1-dicyanoethylene, bast fibers such as hemp and particularly paper and leather.

    摘要翻译： 具有式 + TR＆lt; IMAGE＆gt;和1：1和1：2金属络合物的金属化合物和无金属化合物和1：1和1：2金属络合物的盐，其中 R为氢，-SO 3 H或-NR 5 R 6; Ra是氢或-NR5R6; R 1是氢，卤素，-OH，C 1-4烷基，C 1-4烷氧基或-SO 3 H; R3是氢或C1-4烷基; R 4是卤素，-OH，C 1-4烷基，C 1-4烷氧基，苯基，-NH 2，脂族，脂环族或芳族氨基，含有1至3个原子的杂环氨基或肼基，R5是氢或C1- 4个烷基; 并且R6是有机基团，可用作染色和印刷纤维，丝线和纺织材料的阳离子染料，其包括例如天然或再生纤维素材料如棉，改性合成聚酰胺或聚酯，以及均聚物或共聚物 丙烯腈或1,1-二氰基乙烯的聚合物，诸如大麻，特别是纸和皮革的韧皮纤维。

    Basic azo and non-azo compounds having one or two disubstituted 1,3,5-triazine rings each of which is linked through a bridging radical to the 1-position of a pyrazole ring
    63.
    发明授权
    Basic azo and non-azo compounds having one or two disubstituted 1,3,5-triazine rings each of which is linked through a bridging radical to the 1-position of a pyrazole ring 失效
    具有一个或两个二取代的1,3,5-三嗪环的碱性偶氮和非偶氮化合物，其各自通过桥连基团连接到吡唑环的1-位上

    公开(公告)号：US4686285A

    公开(公告)日：1987-08-11

    申请号：US699916

    申请日：1985-02-08

    申请人： Reinhard Pedrazzi

    发明人： Reinhard Pedrazzi

    IPC分类号： C09B31/143 ,  C07D403/12 ,  C09B29/36 ,  C09B29/50 ,  C09B31/28 ,  C09B33/12 ,  C09B35/03 ,  C09B35/34 ,  C09B35/48 ,  C09B44/02 ,  C09B44/08 ,  C09B35/08 ,  C09B45/26

    CPC分类号： C07D403/12 ,  C09B44/02

    摘要： (i) Metal-free compounds of the formula ##STR1## (ii) tautomers thereof, (iii) 1:1 and 1:2 metal complexes of (i) and (ii),(iv) salts of (i), (ii), and (iii), and(v) mixtures of (i), (ii), (iii), and (iv),wherein the symbols are as defined in the Specification, are useful as dyes for, for example, polymers and copolymers of acrylonitrile, polyesters modified to contain acid groups, polyamides such as wool, leather, cotton, bast fibers such as hemp, flax, sisal jute, coir and straw, regenerated cellulose, glass fibers and paper (those wherein R.sub.o is other than hydrogen) or as intermediates for the synthesis of dyes.

    摘要翻译： （i）下式的金属化合物（ⅱ）其互变异构体，（iii）（i）和（ii）的1:1和1:2金属络合物，（iv）（i），（ⅰ） ii）和（iii）和（v）（i），（ii），（iii）和（iv）的混合物，其中符号如本说明书中所定义，可用作例如染料， 丙烯腈的聚合物和共聚物，被改性成含有酸基团的聚酯，羊毛，皮革，棉花，韧皮纤维如大麻，亚麻，剑麻黄麻，椰子和稻草，再生纤维素，玻璃纤维和纸 或者作为合成染料的中间体。

    Azo moiety containing metal complexes in toners
    64.
    发明授权
    Azo moiety containing metal complexes in toners 失效
    在调色剂中含有金属络合物的偶氮部分

    公开(公告)号：US4563409A

    公开(公告)日：1986-01-07

    申请号：US668323

    申请日：1984-11-05

    申请人： Nobuo Suzuki ,  Takeo Kurahashi ,  Katsuichi Motohashi ,  Genpei Sugiyama ,  Takayuki Sakai

    发明人： Nobuo Suzuki ,  Takeo Kurahashi ,  Katsuichi Motohashi ,  Genpei Sugiyama ,  Takayuki Sakai

    IPC分类号： C09B44/02 ,  C09B45/14 ,  G03G9/09 ,  G03G9/08

    CPC分类号： G03G9/091 ,  C09B44/02 ,  C09B45/14

    摘要： A symmetric 2:1 metal complex represented by the general formula: ##STR1## where R is a hydrogen atom, an alkyl group having from 1 to 10 carbon atoms, an alkoxy group having from 1 to 4 carbon atoms, an alkoxycarbonyl group having from 2 to 5 carbon atoms, an acyl group having from 2 to 5 carbon atoms, an aminocarbonyl group, an alklyaminocarbonyl group having from 2 to 5 carbon atoms, an alkylsulfonyl group having from 1 to 3 carbon atoms, an aminosulfonyl group, an acylamino group having from 2 to 5 carbon atoms, a nitro group, a cyano group or a halogen atom, m is an integer of from 1 to 4, when m is 2 or more, the plurality of R may be the same or different substituents, Q is --NHCO--Y--Z or --CONH--Y--Z (where Y is an alkylene group having from 1 to 4 carbon atoms, and Z is a quaternary ammonium group), M is a chromium atom or a cobalt atom, and X.sup..crclbar. is an anion.

    摘要翻译： 由下式通式表示的对称2:1金属络合物：其中R是氢原子，具有1至10个碳原子的烷基，具有1至4个碳原子的烷氧基，具有1至4个碳原子的烷氧基 2至5个碳原子，具有2至5个碳原子的酰基，氨基羰基，2至5个碳原子的烷基氨基羰基，1至3个碳原子的烷基磺酰基，氨基磺酰基，酰氨基 具有2至5个碳原子，硝基，氰基或卤素原子，m为1至4的整数，当m为2以上时，多个R可以相同或不同，取代基Q 是-NHCO-YZ或-CONH-YZ（其中Y是具有1至4个碳原子的亚烷基，Z是季铵基团），M是铬原子或钴原子，X（ - ）是 一种阴离子。

    N,N-Dialkyl-N-aminoalkyl-N-(amino or nitro)phenylalkyl- and N-methyl-N-[3-(amino or nitro)phenoxy-2-hydroxy-1-propyl]-N,N-bis(3-aminopropyl)quaternary ammonium salts
    66.
    发明授权
    N,N-Dialkyl-N-aminoalkyl-N-(amino or nitro)phenylalkyl- and N-methyl-N-[3-(amino or nitro)phenoxy-2-hydroxy-1-propyl]-N,N-bis(3-aminopropyl)quaternary ammonium salts 失效
    N，N-二烷基-N-氨基烷基-N-（氨基或硝基）苯基烷基和N-甲基-N- [3-（氨基或硝基）苯氧基-2-羟基-1-丙基] -N， （3-氨基丙基）季铵盐

    公开(公告)号：US4206144A

    公开(公告)日：1980-06-03

    申请号：US963031

    申请日：1978-11-22

    申请人： Patrick J. Jefferies ,  Nathan N. Crounse

    发明人： Patrick J. Jefferies ,  Nathan N. Crounse

    IPC分类号： C09B44/02 ,  C07C87/30

    CPC分类号： C09B44/02

    摘要： N,N-Dialkyl-N-aminoalkyl-N-aminophenylalkyl quaternary ammonium salts and N-methyl-N-(3-aminophenoxy-2-hydroxy-1-propyl)-N,N-bis(3-aminopropyl) quaternary ammonium salts and their N-nitrophenylalkyl and N-(3-nitrophenoxy) precussor quaternary ammonium salts, respectively are intermediates to water-soluble azo-dyestuffs useful for coloring natural fibers, synthetic fiber-forming materials and cellulosic materials. These dyes dye cotton and paper various shades of yellows, reds, and oranges with less prone to bleed and with a high degree of discharge when bleached with hypochlorite or chlorine bleaches.

    摘要翻译： N，N-二烷基-N-氨基烷基-N-氨基苯基烷基季铵盐和N-甲基-N-（3-氨基苯氧基-2-羟基-1-丙基）-N，N-双（3-氨基丙基）季铵盐 和它们的N-硝基苯基烷基和N-（3-硝基苯氧基）预混合季铵盐分别是可用于着色天然纤维，合成纤维形成材料和纤维素材料的水溶性偶氮染料的中间体。 这些染料染色棉花和纸张，黄色，红色和橙色的各种色调，不太容易出血，并且在用次氯酸盐或氯漂白剂漂白时会出现高度的放电。

    Water-soluble quaternary ammonium azo dyestuffs
    68.
    发明授权
    Water-soluble quaternary ammonium azo dyestuffs 失效
    水溶性季铵偶氮染料

    公开(公告)号：US4065500A

    公开(公告)日：1977-12-27

    申请号：US672428

    申请日：1976-03-31

    申请人： Patrick J. Jefferies ,  Nathan N. Crounse

    发明人： Patrick J. Jefferies ,  Nathan N. Crounse

    IPC分类号： C09B44/02 ,  C09B47/32 ,  C07C87/30

    CPC分类号： C09B44/02 ,  C09B47/32

    摘要： Water-soluble cationic dyestuffs of the formulae ##STR1## WHEREIN R.degree. is hydrogen, lower-alkyl or hydroxy-lower-alkyl;R.sup.1 is lower-alkyl, lower-alkenyl or hydroxy-lower-alkyl;R.sup.2 is lower-alkyl, lower-alkenyl, hydroxy-lower-alkyl or -(lower-alkylene)-NR.degree.Y or R.sup.1 and R.sup.2 together with the nitrogen atom, are pyrrolidino, piperidino or 4-lower-alkanoyl piperazino;Y is hydrogen or ##STR2## wherein R is hydrogen, lower-alkyl, lower-alkenyl, phenyl or phenyl-lower-alkyl;A is a member selected from the group consisting of an aromatic azo dyestuff residue attached to the quaternary ammonium nitrogen atom through a lower-alkylene bridge.k is a small integer whose value is dependent on the nature of A such that it has a range from one to two;R.sup.8 is lower-alkyl, lower-alkenyl or hydroxy-lower-alkyl;R.sup.9 is lower-alkyl, hydroxy-lower-alkyl or NH.sub.2 ;R.sup.10 is lower-alkyl or lower-alkenyl;A.sup.1 is an aromatic azo dyestuff residue attached to the quaternary ammonium nitrogen atom through a lower-alkylene bridge;g is a small integer whose value is dependent on the nature of A.sup.1 such that it has a range from one to two;R.sup.8' is lower alkyl;R.sup.9' is lower-alkyl, lower-alkenyl or hydroxy-lower-alkyl;R.sup.10' is lower-alkyl, lower-alkenyl or hydroxy-lower-alkyl or R.sup.9' and R.sup.10' together with the nitrogen atom are morpholino;A.sup.2 is an aromatic azo dyestuff residue attached to the quaternary ammonium nitrogen atom through a lower-alkylene bridge;h is a small integer whose value is dependent on the nature of A.sup.2 such that it has a range from one to two; andAn is an anionAre particularly useful for coloring natural fibers, synthetic fiber-forming materials and cellulosic materials. These dyes dye cotton and paper various shades of stable yellows, reds and oranges. The dyeing from these dyes on paper are less prone to bleed and have a high degree of color discharge when bleached with hypochlorite or chlorine bleaches.

    摘要翻译： 下式的水溶性阳离子染料，其中R为氢，低级烷基或羟基 - 低级 - 烷基; R1是低级烷基，低级烯基或羟基 - 低级 - 烷基; R2是低级烷基，低级烯基，羟基 - 低级 - 烷基或 - （低级亚烷基）-NRYY或R1和R2与氮原子一起是吡咯烷子基，哌啶子基或4-低级烷酰基哌嗪子基; Y是氢或者其中R是氢，低级烷基，低级烯基，苯基或苯基 - 低级 - 烷基; A是选自通过低级亚烷基桥连接到季铵氮原子的芳族偶氮染料残基的成员。

    Substituted 4-(2-benzothiazolyl)phenylazo dyes having a quaternary ammonium, hydrazinium or optionally substituted amino substituent
    70.
    发明授权
    Substituted 4-(2-benzothiazolyl)phenylazo dyes having a quaternary ammonium, hydrazinium or optionally substituted amino substituent 失效
    具有季铵，腙或任选取代的氨基取代基的取代的4-（2-苯并噻唑基）苯偶氮染料

    公开(公告)号：US3933787A

    公开(公告)日：1976-01-20

    申请号：US323300

    申请日：1973-01-12

    申请人： Helmut Moser

    发明人： Helmut Moser

    IPC分类号： C09B44/02 ,  D21H21/28 ,  C09B29/10 ,  C09B29/32 ,  C09B29/38 ,  D21H1/46

    CPC分类号： D21H21/28 ,  C09B44/02 ,  Y10S8/919

    摘要： Azo dyes of the formula ##SPC1##WhereX stands for the radical of a coupling component of the aminobenzene, hydroxybenzene, aminonaphthalene, hydroxynaphthalene or heterocyclic series or one with a coupling methylene group,A.sub.n .sup.- for an anion equivalent to K.sub.n .sup.+,n for 1 to 6,K.sup.+ for the group ##EQU1## and where the aromatic rings B and/or D may be further substituted. The dyes are useful for dyeing and printing paper (e.g., dyeing in the stock). The dyed paper is fast to light and wet treatments and has good fastness to bleaching, water, alcohol and light.

    摘要翻译： 式WHERE X的偶氮染料代表氨基苯，羟基苯，氨基萘，羟基萘或杂环系列的偶联组分或具有偶合亚甲基的偶联组分，An +相当于Kn +，N FOR 1至6，组+（CH 2 -K）n N ANGLE ANGLE CN = NX A n - （I），S和其中芳环B和/或D可进一步被取代的K +。 染料可用于染色和印刷纸（例如，在原料中染色）。 染色纸易于光亮和湿润处理，具有良好的漂白，水，酒精和光线牢度。