Abstract:
There are provided a surface modified material comprising a base material, and one or more kinds of sulfonimide compound groups bonded onto the surface of the base material via one or more linking groups -A-Y′— (A is a direct bond or an organic group. Y′ is a bonding site with the base material.); the sulfonimide compound group comprising, in its molecular structure, one or more linking groups -A—Y′— and two or more sulfonimide groups; as well as a fuel cell using the surface modified material for a catalyst layer. There is also provided a sulfonimide compound for surface modification comprising one or more reactive end groups -A-Y (A is a direct bond or an organic group. Y is a reactive functional group.) and two or more sulfonimide groups.
Abstract:
A curable composition comprising: (i) 2.5 to 50 wt % crosslinker comprising at least two acrylamide groups; (ii) 12 to 65 wt % curable ionic compound comprising an ethylenically unsaturated group and a cationic group; (iii) 15 to 70 wt % solvent; and (iv) 0 to 10 wt % of free radical initiator; and (v) 2 to 50 wt % of non-curable salt; wherein the composition has a pH of 1 to 12. The compositions are useful for preparing ion exchange membranes.
Abstract:
An electrolytic membrane for a fuel cell including a crystalline organic and inorganic porous composite, an electrode for a fuel cell including a crystalline organic and inorganic porous composite, and a fuel cell including the electrolytic membrane and/or the electrode.
Abstract:
The present invention provides a polymer electrolyte membrane for a fuel cell, including a porous membrane including ceramic fibers crisscrossed in a network and pores formed by the ceramic fibers coalesced at intersection points, and a proton conductive polymer inside the pores.
Abstract:
A method for preparing an anion exchange membrane suitable for use in an alkaline fuel cell and particularly in a direct borohydride fuel cell, involves radiation grafting a hydrocarbon polymer film with a monomer and adding a quaternising agent. The degree of grafting is improved by mixing the monomer with a diluent comprising alcohol and a hydrocarbon solvent.
Abstract:
A naphthoxazine benzoxazine-based monomer is represented by Formula 1 below: In Formula 1, R2 and R3 or R3 and R4 are linked to each other to form a group represented by Formula 2 below, and R5 and R6 or R6 and R7 are linked to each other to form a group represented by Formula 2 below, In Formula 2, * represents the bonding position of R2 and R3, R3 and R4, R5 and R6, or R6 and R7 of Formula 1. A polymer is formed by polymerizing the naphthoxazine benzoxazine-based monomer, an electrode for a fuel cell includes the polymer, an electrolyte membrane for a fuel cell includes the polymer, and a fuel cell uses the electrode.
Abstract:
A phosphorus containing monomer, a polymer thereof, an electrode for a fuel cell including the polymer, an electrolyte membrane for a fuel cell including the polymer, and a fuel cell including the electrode. The phosphorus containing monomer is represented by Formula 1: Group A is represented by:
Abstract:
A solid polymer fuel cell stack has a layered product comprised of a plurality of cells stacked, and is so structured that the layered product is fastened by end plates on both sides thereof via a current collector and an insulating plate on each side. Each cell is structured such that an MEA is sandwiched between an anode-side plate, which is provided with a fuel path disposed counter to an anode of the MEA, and a cathode-side plate, which is provided with an oxidizing agent path disposed counter to a cathode of the MEA. An MEA is comprised of a solid polymer electrolyte membrane, an anode and a cathode. The solid polymer electrolyte membrane is composed of powder of basic polymer such as polybenzimidazole, strong acid such as phosphoric acid impregnated with the basic polymer, and binder such as fluorocarbon resin.
Abstract:
A conductive composition, a polymer obtained from the conductive composition, a method of preparing the composition, an electrode and electrolyte membrane of a fuel cell, each including at least one of the composition and the polymer, and a fuel cell including at least one of the composition and the polymer. The conductive composition includes at least one benzoxazine-based compound with a conductive functional group and a cross-linkable compound. A composition including a conductive functional group and a polymer that is a polymerization product of the composition demonstrates good resistance to chemicals, heat, and acid. An electrode for fuel cells that includes the same demonstrates improved electrical conductivity.
Abstract:
Embodiments are disclosed herein that relate to PEM fuel cells comprising membrane-electrode assemblies having plural membrane layers. For example, one disclosed embodiment provides a fuel cell including an anode, a cathode, and a multi-layer membrane disposed between the anode and the cathode, the multi-layer membrane comprising two or more polymer membranes layers. The fuel cell further comprises an electrolyte within the multi-layer membrane.