Electrical grade extruded filled thermoplastic sheet material and
process for the manufacture thereof
    61.
    发明授权
    Electrical grade extruded filled thermoplastic sheet material and process for the manufacture thereof 失效
    电级挤出填充的热塑性片材及其制造方法

    公开(公告)号:US4500603A

    公开(公告)日:1985-02-19

    申请号:US230918

    申请日:1981-02-02

    Abstract: Disclosed is a novel filled continuous thermoplastic sheet material highly suitable for use in electrical applications, such as in the production of printed circuit boards. This material comprises an extruded sheet of a thermoplastic polymer, preferably poly(1,4-butylene terephthalate), containing from about 5 to 60% by weight of reinforcing filler material such as glass fibers, and having a polymer-rich surface, a gloss value of at least 15, and a maximum roughness of about 150 microinches. Also disclosed is a process and apparatus for the production of this material by extruding a filled thermoplastic polymer into a continuous laminar melt stream, conveying the laminar melt stream to a hot, highly polished surface, and then contacting the resulting melt stream with the hot, highly polished surface under temperature and pressure conditions sufficient to cause the filler material to retreat from the surface of the melt stream and to produce a sheet material having a smooth, glossy, polymer-rich surface thereon.

    Abstract translation: 公开了一种高度适用于电气应用的新型填充的连续热塑性片材,例如在印刷电路板的制造中。 该材料包括热塑性聚合物的挤出片材,优选聚对苯二甲酸1,4-丁二醇酯,其含有约5至60重量%的增强填料如玻璃纤维,并且具有富聚合物表面,光泽度 值至少为15,最大粗糙度为约150微英寸。 还公开了一种通过将填充的热塑性聚合物挤出成连续的层状熔体流来生产该材料的方法和装置,将层状熔体流输送到热的高度抛光的表面,然后使所得的熔体流与热的, 在足以使填料从熔体流表面退回并在其上产生具有光滑,有光泽,富聚合物的表面的片材的温度和压力条件下的高度抛光的表面。

    Acetylene-terminated polyimide derivatives
    65.
    发明授权
    Acetylene-terminated polyimide derivatives 失效
    乙炔封端的聚酰亚胺衍生物

    公开(公告)号:US4168367A

    公开(公告)日:1979-09-18

    申请号:US927814

    申请日:1978-07-25

    CPC classification number: C08G73/16 Y10T428/31623 Y10T428/31652

    Abstract: Novel, unsaturated, polyimide-polyesters and processes for their preparation are disclosed herein. These new polyimides are derivatives of anhydride-terminated aromatic polyimides, from which they are prepared by esterification to provide unsaturated ester groups having a terminal --C.tbd.CH group. These new compositions are more tractable than the original anhydride-terminated polyimides and can be converted at appropriate lower temperatures to crosslinked, insoluble, infusible polymers without by-product formation, thereby extending greatly the applications for which the aromatic polyimides can be employed.

    Abstract translation: 新颖的,不饱和的聚酰亚胺 - 聚酯及其制备方法在本文中公开。 这些新的聚酰亚胺是酸酐封端的芳族聚酰亚胺的衍生物,通过酯化制备它们以提供具有末端-C3ONDCH基团的不饱和酯基。 这些新组合物比原始的酸酐封端的聚酰亚胺更易于处理,并且可以在合适的较低温度下转化成交联的,不溶的,不会产生副产物的聚合物,从而大大延长了可以使用芳族聚酰亚胺的应用。

    Transparent laminate and adhesive film
    66.
    发明授权
    Transparent laminate and adhesive film 失效
    透明层压板和粘合膜

    公开(公告)号:US4137364A

    公开(公告)日:1979-01-30

    申请号:US739367

    申请日:1976-11-05

    Abstract: The invention relates to transparent or optically clear laminates and adhesive films used to make these laminates having a temperature utility range far greater than those previously developed and which are especially useful for windshields of high speed aircraft which need such a broad temperature range. These transparent adhesive films have a temperature utility in the range of -65.degree. F to at least 350.degree. F in laminates and comprise an ethylene/vinyl acetate copolymer having a vinyl acetate content in the range of 40% to 60%, the copolymer being partially hydrolyzed to form a terpolymer having a hydroxyl content in the range of 1% to 6%, the terpolymer in film form and/or laminate being heat treated and cross-linked to give the adhesive film. The laminates are made from transparent layers of glass and/or plastic bound together with the transparent adhesive film.

    Abstract translation: 本发明涉及用于制造这些层压板的透明或光学透明层压板和粘合膜,其温度效用范围远远大于先前开发的温度效用范围,并且其对于需要这样宽的温度范围的高速飞行器的挡风玻璃特别有用。 这些透明粘合剂膜在层压体中具有在-65°F至至少350°F范围内的温度效用,并且包含乙酸乙烯酯含量在40%至60%范围内的乙烯/乙酸乙烯酯共聚物,共聚物为 部分水解以形成羟基含量在1%至6%范围内的三元共聚物,膜形式和/或层压体的三元共聚物经过热处理和交联,得到粘合剂膜。 层压板由与透明粘合剂膜结合在一起的透明玻璃和/或塑料层制成。

    Polyamide-imide precondensates
    68.
    发明授权
    Polyamide-imide precondensates 失效
    聚酰胺酰亚胺预缩合物

    公开(公告)号:US4121266A

    公开(公告)日:1978-10-17

    申请号:US693351

    申请日:1976-06-07

    CPC classification number: H01B3/306 C08G73/14 H01B3/305 Y10T428/31623

    Abstract: A polyamide-imide precondensate which is solid at room temperature, but is fusible and soluble in polar solvents. It is manufactured by first condensing 1 mole of diamine with 2 moles of tricarboxylic acid anhydride in a diol as the solvent, to give a diimide-dicarboxylic acid, then esterifying the diimide-dicarboxylic acid with the diol and finally effecting the polycondensation by adding 1 mole of diamine per mole of diester. The precondensate may be used, as a melt, as a solution in organic solvents or as an aqueous dispersion, for coating electrical conductors.

    Abstract translation: 聚酰胺 - 酰亚胺预缩合物,在室温下为固体,但易熔,易溶于极性溶剂。 通过在二醇中首先将1摩尔二胺与2摩尔三羧酸缩合作为溶剂,得到二酰亚胺 - 二羧酸,然后将二酰亚胺二羧酸与二醇酯化,最后通过加入1进行缩聚来进行缩聚 摩尔二胺/摩尔二酯。 预缩合物可以作为熔体用作有机溶剂或作为水分散体的溶液用于涂覆电导体。

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