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    Reduced calorie fats which comprise reduced calorie triglycerides containing medium and long chain fatty acids and which exhibit rapid crystallization to beta phase
    61.
    发明授权
    Reduced calorie fats which comprise reduced calorie triglycerides containing medium and long chain fatty acids and which exhibit rapid crystallization to beta phase 失效
    含有含有中等长链脂肪酸的低热量甘油三酸酯并且显示快速结晶至β相的减少热量的脂肪

    公开(公告)号：US5492714A

    公开(公告)日：1996-02-20

    申请号：US336360

    申请日：1994-11-08

    申请人： Gerald J. Guskey ,  James A. Hellyer ,  Bernard W. Kluesener ,  Gordon K. Stipp

    发明人： Gerald J. Guskey ,  James A. Hellyer ,  Bernard W. Kluesener ,  Gordon K. Stipp

    IPC分类号： A23D9/00 ,  C07C69/30 ,  C11C3/08

    CPC分类号： C11C3/08 ,  A23D9/00 ,  C07C69/30 ,  Y10S426/804

    摘要： The present invention relates to reduced calorie fats comprising mixtures of reduced calorie triglycerides which are enriched in long chain fatty acid 2-position isomers (MLM triglycerides). In particular, the reduced calorie fats comprise at least about 40% of the long chain fatty acid 2-position isomer. The reduced calorie fats according to the present invention further comprise at least about 85% combined MML and MLM triglycerides, no more than about 5% combined LLM and LML triglycerides, no more than about 2% LLL triglycerides, no more than about 4% MMM triglycerides and no more than about 6% other triglycerides; wherein M=fatty acids selected from the group consisting of C.sub.6 to C.sub.10 saturated fatty acids, and mixtures thereof, and L=fatty acids selected from the group consisting of C.sub.17 to C.sub.26 saturated fatty acids, and mixtures thereof. The reduced calorie fats of the present invention have the following fatty acid composition by weight percent:(a) from about 15% to about 70% C.sub.6 to C.sub.10 saturated fatty acids;(b) from about 10% to about 70% C.sub.17 to C.sub.26 saturated fatty acids;(c) not more than about 10% fatty acids selected from the group consistingof C.sub.12:0 and C.sub.14:0, and mixtures thereof;(d) not more than about 20% fatty acids selected from the group consisting of C.sub.18:1, C.sub.18:2, C.sub.18:3 and mixtures thereof, and(e) not more than 4% C.sub.18:2 fatty acids.The reduced calorie fats of the present invention exhibit rapid crystallization into the stable beta phase.

    摘要翻译： 本发明涉及含有富含长链脂肪酸2-位异构体（MLM甘油三酸酯）的低热量甘油三酯的混合物的低热量脂肪。 特别地，低热量脂肪占至少约40％的长链脂肪酸2-位异构体。 根据本发明的低热量脂肪还包含至少约85％的组合的MML和MLM甘油三酸酯，不超过约5％的组合的LLM和LML甘油三酸酯，不超过约2％的LLL甘油三酸酯，不超过约4％的MMM 甘油三酯和不超过约6％的其他甘油三酸酯; 其中M =选自C6至C10饱和脂肪酸的脂肪酸及其混合物，L =选自C 17至C 26饱和脂肪酸的脂肪酸及其混合物。 本发明的低卡路里脂肪具有以下重量百分比的脂肪酸组成：（a）约15％至约70％的C6至C10饱和脂肪酸; （b）约10％至约70％C17至C26饱和脂肪酸; （c）不超过约10％选自C 12：0和C 14：0的脂肪酸及其混合物; （d）不超过约20％的选自C18：1，C18：2，C18：3及其混合物的脂肪酸，和（e）不超过4％的C18：2脂肪酸。 本发明的低热量脂肪显示快速结晶进入稳定的β相。

    Process for preparing a C.sub.12 -C.sub.24 saturated fatty acid esterified alkoxylated polyol
    62.
    发明授权
    Process for preparing a C.sub.12 -C.sub.24 saturated fatty acid esterified alkoxylated polyol 失效
    制备C12-C24饱和脂肪酸酯化烷氧基化多元醇的方法

    公开(公告)号：US5466843A

    公开(公告)日：1995-11-14

    申请号：US235751

    申请日：1994-04-29

    申请人： Charles F. Cooper

    发明人： Charles F. Cooper

    IPC分类号： C07C69/30 ,  C07C51/367

    CPC分类号： C07C69/30

    摘要： Esterified alkoxylated polyols containing long chain saturated linear acyl groups are obtained by esterification of an alkoxylated polyol such as propoxylated glycerin with a C.sub.12 -C.sub.24 fatty acid such as behenic acid and recovery of excess fatty acid by treatment with an aliphatic hydrocarbon. Esterified alkoxylated polyols prepared in this manner are useful fat substitutes for the formulation of reduced calorie food products.

    摘要翻译： 含有长链饱和直链酰基的酯化烷氧基化多元醇是通过烷氧基化多元醇如丙氧基化甘油与C 12 -C 24脂肪酸如山萮酸酯化，并通过用脂族烃处理回收过量脂肪酸得到的。 以这种方式制备的酯化的烷氧基化多元醇是制备低热量食品的有用的脂肪代用品。

    Process for the production of fatty acid lower alkyl esters
    63.
    发明授权
    Process for the production of fatty acid lower alkyl esters 失效
    生产脂肪酸低级烷基酯的方法

    公开(公告)号：US5455370A

    公开(公告)日：1995-10-03

    申请号：US178281

    申请日：1994-01-10

    申请人： Guenther Demmering ,  Christian Pelzer ,  Lothar Friesenhagen

    发明人： Guenther Demmering ,  Christian Pelzer ,  Lothar Friesenhagen

    IPC分类号： C07C69/30 ,  C07C67/03 ,  C11C3/04 ,  C11C3/10 ,  C11C3/00

    CPC分类号： C11C3/04 ,  C07C67/03

    摘要： Fatty acid glycerides can be transesterified with lower aliphatic alcohols if the reaction is carried out in the presence of fatty acids corresponding to formula (II):R.sup.2 --COOH (II),in which R.sup.2 is an aliphatic hydrocarbon moiety containing 11 to 17 carbon atoms and 0, 1 or 2 double bonds. The products are distinguished by a low content of bound glycerol and a low acid value. Removal or neutralization of the catalyst is unnecessary because, after the transesterification, the fatty acids are also present in the form of their esters.

    摘要翻译： PCT No.PCT / EP92 / 01463 Sec。 371日期1994年1月10日 102（e）日期1994年1月10日PCT提交1992年6月29日PCT公布。 出版物WO93 / 01263 如果反应在对应于式（II）的脂肪酸存在下进行，则其中R2是脂族烃（II），R2-COOH（Ⅱ） 部分含有11至17个碳原子和0,1或2个双键。 产品的特征在于低含量的结合甘油和低酸值。 催化剂的去除或中和是不必要的，因为在酯交换之后，脂肪酸也以它们的酯的形式存在。

    Synthetic oil and cosmetics and external preparations containing the same
    64.
    发明授权
    Synthetic oil and cosmetics and external preparations containing the same 失效
    合成油和化妆品及含有相同的外用制剂

    公开(公告)号：US5436006A

    公开(公告)日：1995-07-25

    申请号：US95199

    申请日：1993-07-23

    申请人： Tadashiro Hirose ,  Yoshihiro Ueda ,  Takashi Murata

    发明人： Tadashiro Hirose ,  Yoshihiro Ueda ,  Takashi Murata

    IPC分类号： A61K8/30 ,  A61K8/00 ,  A61K8/37 ,  A61K9/06 ,  A61Q1/00 ,  A61Q1/04 ,  A61Q19/00 ,  C07C69/30 ,  C11B11/00 ,  C11C3/02 ,  A61K7/48 ,  A61K7/027

    CPC分类号： A61Q19/00 ,  A61K8/375 ,  C11C3/025 ,  A61Q1/06 ,  Y10S514/844 ,  Y10S514/846 ,  Y10S514/873 ,  Y10S514/937

    摘要： Diclosed is a lanolin-like synthetic oil produced by esterification of glycerol with a branched fatty acid having 6 to 14 carbon atoms, a linear fatty acid having 15 to 28 carbon atoms and a dibasic acid having 4 to 10 carbon atoms while all the following conditions (a) to (c) are satisfied:(a) molar ratio of the branched fatty acid to the linear fatty acid ranges from 1.7 to 2.3,(b) 0.7 to 0.8 mol of the dibasic acid is used per mol of glycerol, and(c) the number of remaining hydroxyl group ranges from 0.4 to 0.6 for three hydroxyl groups of glycerol.The synthetic ester oil has a color, smell and stability superior to those of lanolin and an adherability, spreadability, gloss and touch very similar to those of lanolin. Such an oil can be suitably incorporated into cosmetics, toiletries and external preparations to overcome the defects of lanolin and also to exhibit the characteristic features of the oil.

    摘要翻译： 密闭型是通过甘油与碳原子数为6〜14的支链脂肪酸，碳原子数为15〜28的直链脂肪酸和碳原子数为4〜10的二元酸酯化而成的羊毛脂状合成油， （a）〜（c）：（a）支链脂肪酸与线性脂肪酸的摩尔比为1.7〜2.3，（b）每摩尔甘油使用0.7〜0.8摩尔的二元酸， （c）甘油三个羟基的剩余羟基数为0.4-0.6。 合成酯油具有优于羊毛脂的颜色，气味和稳定性，并且与羊毛脂的粘合性，可铺展性，光泽和触感非常相似。 这样的油可以适当地并入化妆品，化妆品和外用制剂中以克服羊毛脂的缺点，并且还具有油的特征。

    Process for producing esterified alkoxylated polyols
    70.
    发明授权
    Process for producing esterified alkoxylated polyols 失效
    生产酯化烷氧基化多元醇的方法

    公开(公告)号：US5118448A

    公开(公告)日：1992-06-02

    申请号：US600462

    申请日：1990-10-19

    申请人： Charles F. Cooper

    发明人： Charles F. Cooper

    IPC分类号： A23D9/013 ,  C07C43/11 ,  C07C43/178 ,  C07C69/30 ,  C11C3/00 ,  C11C3/02

    CPC分类号： C11C3/003 ,  A23D9/013 ,  C07C43/11 ,  C07C43/1785 ,  C07C69/30 ,  C11C3/02

    摘要： Esterified alkoxylated polyols useful as fat mimetics may be prepared by alkoxylating a benzylated polyol with an epoxide under basic conditions, reacting the benzyl ether group with hydrogen to convert it to a hydroxy group, and then esterifying with a fatty acid compound. The resulting product has at least one fatty acid ester group attached directly to the polyol residue.

    摘要翻译： 可用作脂肪模拟物的酯化烷氧基化多元醇可以通过在碱性条件下用环氧化物烷氧基化苄基化多元醇来制备，使苄基醚基团与氢气反应以将其转化成羟基，然后用脂肪酸化合物酯化。 所得产物具有至少一个直接与多元醇残基连接的脂肪酸酯基。