1-4-Dihydropyridine-containing ir-sensitive composition and use thereof for the production of imageable elements

    公开(公告)号:US20060154172A1

    公开(公告)日:2006-07-13

    申请号:US10559230

    申请日:2004-06-08

    Abstract: Initiator system comprising: (a) at least one substance capable of absorbing IR radiation, (b) at least one compound capable of forming free radicals, and (c) at least one 1,4-dihydropyridine derivative of the formula (I) wherein R1 is selected from a hydrogen atom, —C(O)OR7, an optionally substituted alkyl group, an optionally substituted aryl group and an optionally substituted aralkyl group, R2 and R3 are independently selected from optionally substituted alkyl groups, optionally substituted aryl groups, CN and a hydrogen atom, R4 and R5 are independently selected from —C(O)OR7, —C(O)R7, —C(O)NR8R9 and CN, or R2 and R4 together form an optionally substituted phenyl ring or a 5- to 7-membered carbocyclic or heterocyclic ring, wherein the unit is present in the carbocyclic or heterocyclic ring adjacent to position 5 of the dihydropyridine ring and wherein the carbocyclic or heterocyclic ring optionally comprises additional substituents, or both R2 and R4 as well as R3 and R5 form either optionally substituted phenyl rings or 5- to 7-membered carbocyclic or heterocyclic rings, wherein the unit is present in the carbocyclic or heterocyclic rings adjacent to positions 3 and 5 of the dihydropyridine ring and wherein the carbocyclic or heterocyclic rings optionally comprise additional substituents, or one of the pairs R2/R4 and R3/R5 forms a 5- to 7-membered carbocyclic or heterocyclic ring, wherein the unit is present in the carbocyclic or heterocyclic ring adjacent to position 5 or 3 of the dihydropyridine ring and wherein the carbocyclic or heterocyclic ring optionally comprises additional substituents and the other pair forms an optionally substituted phenyl ring, or R2 and R4 or R3 and R1 form a 5- to 7-membered heterocyclic ring which can optionally comprise one or more substituents and which, in addition to the nitrogen atom it shares with the 1,4-dihydropyridine ring, optionally comprises additional nitrogen atoms, —NR13 groups, —S— or —O—, R6 is selected from an alkyl group optionally substituted with a halogen atom or a —C(O) group, an optionally substituted aryl group, an optionally substituted aralkyl group, an optionally substituted heterocyclic group and the group Y is an alkylene group or an arylene group, R7 is a hydrogen atom, aryl group, aralkyl group or alkyl group, wherein the alkyl group and the alkyl unit of the aralkyl group optionally comprise one or more C—C double and/or C—C triple bonds, and R8 and R9 are independently selected from a hydrogen atom, an optionally substituted alkyl group, an optionally substituted aryl group and an optionally substituted aralkyl group.

    Radiation-sensitive elements and their storage stability
    694.
    发明申请
    Radiation-sensitive elements and their storage stability 有权
    辐射敏感元件及其储存稳定性

    公开(公告)号:US20060051699A1

    公开(公告)日:2006-03-09

    申请号:US10536514

    申请日:2003-11-28

    Abstract: Radiation-sensitive element comprising (a) a substrate with at least one hydrophilic surface and (b) a radiation-sensitive coating on at least one hydrophilic surface of the substrate, wherein the coating comprises: (i) at least one free-radical polymerizable monomer and/or oligomer and/or polymer with at least one ethylenically unsaturated group each, (ii) at least one absorber selected from photoinitiators and sensitizers, which is capable of absorbing radiation of a wavelength in the range of 250 to 1,200 nm and (iii) at least one stabilizer comprising in its molecule at least one group capable of inhibiting free-radical polymerization, and at least one other group capable of sorption at the hydrophilic surface of the substrate.

    Abstract translation: 辐射敏感元件包括(a)具有至少一个亲水表面的基底和(b)基底的至少一个亲水表面上的辐射敏感涂层,其中所述涂层包括:(i)至少一种可自由基聚合的 具有至少一个烯键式不饱和基团的单体和/或低聚物和/或聚合物,(ii)至少一种选自光引发剂和敏化剂的吸收剂,其能够吸收波长在250-1200nm范围内的辐射和( iii)至少一种稳定剂在其分子中包含至少一个能够抑制自由基聚合的基团,以及至少一种能够在基材亲水表面吸附的其它基团。

    On-press developable lithographic printing plate precursor
    696.
    发明授权
    On-press developable lithographic printing plate precursor 失效
    印刷机上可印刷的平版印刷版前体

    公开(公告)号:US06969575B2

    公开(公告)日:2005-11-29

    申请号:US10647428

    申请日:2003-08-26

    Applicant: Toshifumi Inno

    Inventor: Toshifumi Inno

    Abstract: An on-press developable heat-sensitive lithographic printing plate precursor comprising: a support having a water-wettable surface; and an image forming layer, wherein the image forming layer comprises microcapsules containing a lipophilic compound and one of a leuco dye which forms a color by an action of an acid and a dye which reduces the maximum absorption intensity in a visible region by an action of an acid, an acid generator capable of generating an acid on heat application, and a light-heat converting substance.

    Abstract translation: 一种可印刷的可印刷的热敏平版印刷版原版,包括:具有可润湿表面的载体; 和图像形成层,其中所述图像形成层包含含有亲脂性化合物的微胶囊和通过酸和染料形成颜色的无色染料之一,所述无色染料通过下述作用降低可见光区域中的最大吸收强度 能够在加热时产生酸的酸,酸发生剂和光热转换物质。

    Directly imageable waterless planographic printing plate precursor
    698.
    发明授权
    Directly imageable waterless planographic printing plate precursor 有权
    直接成像无水平版印刷版前体

    公开(公告)号:US06964841B2

    公开(公告)日:2005-11-15

    申请号:US10372769

    申请日:2003-02-26

    Abstract: The invention is a directly imageable waterless planographic printing plate precursor comprising: at least a heat insulating layer, a heat sensitive layer, and an ink repellent layer that are provided in that order on a substrate, wherein a transmittance of the heat insulating layer for a light having a wavelength within a range of 400 to 650 nm is at most 15% over the entire range of the wavelength. The invention provides a directly imageable waterless planographic printing plate precursor that allows measurement of the dot area ratio on the printing plate with a densitometer or the like.

    Abstract translation: 本发明是一种可直接成像的无水平版印刷版原版,其特征在于,至少具有在基板上依次设置的绝热层,感热层和拒油墨层,其中,绝热层 波长在400至650nm范围内的光在波长的整个范围内至多为15%。 本发明提供一种可直接成像的无水平版印刷版原版,其允许用密度计等测量印版上的点面积比。

    Negative working, heat-sensitive lithographic printing plate precursor
    699.
    发明申请
    Negative working, heat-sensitive lithographic printing plate precursor 失效
    负性工作,热敏平版印刷版前体

    公开(公告)号:US20050238994A1

    公开(公告)日:2005-10-27

    申请号:US11113878

    申请日:2005-04-25

    Abstract: A negative-working lithographic printing plate precursor is disclosed comprising on a support having a hydrophilic surface or which is provided with a hydrophilic layer, a coating comprising an infrared absorbing agent, a first layer comprising an aqueous dispersion comprising hydrophobic thermoplastic polymer particles and a first hydrophobic binder, and a second layer located between said first layer and said support which comprises a second hydrophobic binder, characterized in that said first hydrophobic binder is a phenolic resin and said second hydrophobic binder is a polymer comprising at least one sulphonamide group.

    Abstract translation: 公开了一种负性平版印刷版原版,其包含在具有亲水性表面的支持体上,或者设置有亲水层,包含红外线吸收剂的涂层,第一层包含含有疏水性热塑性聚合物颗粒的水性分散体和第一层 疏水性粘合剂和位于所述第一层和所述载体之间的第二层,其包含第二疏水性粘合剂,其特征在于,所述第一疏水性粘合剂是酚醛树脂,所述第二疏水性粘合剂是包含至少一种磺酰胺基团的聚合物。

    Method of exposure recording on a planographic printing plate and an apparatus for practicing the method
    700.
    发明申请
    Method of exposure recording on a planographic printing plate and an apparatus for practicing the method 审中-公开
    平版印刷版上的曝光记录方法和实施该方法的装置

    公开(公告)号:US20050213171A1

    公开(公告)日:2005-09-29

    申请号:US11090181

    申请日:2005-03-28

    Inventor: Ichirou Miyagawa

    Abstract: A method of light exposure recording on a planographic printing plate, wherein the planographic printing plate includes a support and an image recording layer provided on the support, the image recording layer includes a radical polymerization initiator, the method comprising: irradiating the image recording layer with a predetermined amount of a first light, whereby the radical initiator generates a radical, the radical is quenched by free oxygen in the image recording layer, so that free oxygen in the image recording layer is exhausted and disappears from the image recording layer and that the image recording layer is supersensitized; and then rradiating the image recording layer with a second light as a recording light modulated on the basis of image information, so as to form a latent image corresponding to the image information on the image recording layer. Also provided is an apparatus for practicing the invention.

    Abstract translation: 一种在平版印刷版上进行曝光记录的方法,其中平版印刷版包括载体和设置在载体上的图像记录层,图像记录层包括自由基聚合引发剂,该方法包括:将图像记录层与 预定量的第一光,由此自由基引发剂产生自由基,自由基被图像记录层中的游离氧猝灭,使得图像记录层中的游离氧被排出并从图像记录层消失, 图像记录层超敏化; 然后使用第二光作为基于图像信息调制的记录光来对图像记录层进行辐照,以便形成与图像记录层上的图像信息对应的潜像。 还提供了一种用于实施本发明的装置。

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