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    Manufacturing process for aminoalkyl silanes
    71.
    发明授权
    Manufacturing process for aminoalkyl silanes 有权
    氨基烷基硅烷的制备方法

    公开(公告)号：US06423858B1

    公开(公告)日：2002-07-23

    申请号：US09991965

    申请日：2001-11-26

    申请人： Christoph Schwarz ,  Frank Kropfgans ,  Hartwig Rauleder ,  Hermann-Josef Korte

    发明人： Christoph Schwarz ,  Frank Kropfgans ,  Hartwig Rauleder ,  Hermann-Josef Korte

    IPC分类号： C07F710

    CPC分类号： C07F7/1892 ,  C07F7/20

    摘要： Aminoalkylsilanes of formula I: R1R2N—(CH2)y—Si(OR3)3−nR4n  (I), wherein R1 and R2 are each independently, identical of different, hydrogen, aryl, arylalkyl or C1-4-alkyl; R3 and R4 are each independently, identical or different, C1-8-alkyl or aryl; y is 2, 3 or 4 and n is 0 or 1, 2 or 3, are prepared by a process comprising: reacting an organosilane of formula II: X—(CH2)y—Si(OR3)3−nR4n  (II), wherein X is Cl, Br, I or F; and R3, R4, y and n are each as defined above with ammonia or an organic amine compound of the formula: HNR1R2  (III),  wherein R1 and R2 are each as defined above with at least one of R1 and R2 not being hydrogen in a liquid phase; evaporating ammonia or organic amine under reduced pressure while ammonium chloride or aminohydrochloride by-products, produced in the reaction of the first step, remains dissolved in the liquid phase; transferring the product mixture after said evaporation to another vessel operated at a lower pressure level of than the second stage, and allowing ammonium chloride or aminohydrochloride to crystallize; separating the crystalline ammonium chloride or aminohydrochloride from the crude product; and distilling the crude product to produce purified aminoalkylsilane product.

    摘要翻译： 式I的氨基烷基硅烷：其中R 1和R 2各自独立地为不同的氢，芳基，芳基烷基或C 1-4 - 烷基; R 3和R 4各自独立地，相同或不同，C 1-8 - 烷基或芳基; y为2,3或4，n为0或1,2或3的方法包括：使式II的有机硅烷：其中X为Cl，Br，I或F; R 3，R 4，y和n各自如上所定义，与氨或下式的有机胺化合物：其中R 1和R 2各自如上所定义，R 1和R 2中的至少一个在液相中不是氢;蒸发氨 或有机胺，同时在第一步骤的反应中产生的氯化铵或氨基盐酸盐副产物保持溶于液相;将所述蒸发之后的产物混合物转移到在低于 第二阶段，使氯化铵或氨基盐酸盐结晶;将结晶氯化铵或氨基盐酸盐与粗产物分离; 并将粗产物蒸馏以产生纯化的氨基烷基硅烷产物。

    Process for preparing vinylchlorosilanes
    73.
    发明授权
    Process for preparing vinylchlorosilanes 有权
    制备乙烯基氯硅烷的方法

    公开(公告)号：US06222056B1

    公开(公告)日：2001-04-24

    申请号：US09556404

    申请日：2000-04-24

    申请人： Stefan Bade ,  Hartwig Rauleder ,  Uwe Schoen ,  Franz-Michael Bollenrath

    发明人： Stefan Bade ,  Hartwig Rauleder ,  Uwe Schoen ,  Franz-Michael Bollenrath

    IPC分类号： C07F714

    CPC分类号： C07F7/122

    摘要： The invention relates to a process for preparing vinylchlorosilanes by thermal non-catalyzed reaction of chlorosilanes with vinyl chloride at from 550 to 700° C., using a ring-gap reactor which includes rapidly cooling the hot reaction gases after they have flowed through the ring-gap space, by quenching them with a liquid.

    摘要翻译： 本发明涉及一种通过氯代硅烷与氯乙烯在550-700℃下的热非催化反应制备乙烯基氯硅烷的方法，该方法包括一个环流反应器，该反应器包括在热反应气体流过环后快速冷却 间隙，用液体淬火。

    Process for preparing low-chloride or chloride-free alkoxysilanes
    74.
    发明授权
    Process for preparing low-chloride or chloride-free alkoxysilanes 有权
    制备低氯化物或无氯化物的烷氧基硅烷的方法

    公开(公告)号：US06150551A

    公开(公告)日：2000-11-21

    申请号：US432802

    申请日：1999-11-03

    申请人： Frank Kropfgans ,  Hartwig Rauleder

    发明人： Frank Kropfgans ,  Hartwig Rauleder

    IPC分类号： C07F7/04 ,  C07F7/18 ,  C07F7/08

    CPC分类号： C07F7/188 ,  C07F7/045

    摘要： A process for preparing an alkoxysilane with an acidic chloride content of less than 10 ppm by weight, comprising:reacting a chlorosilane with an alcohol in a water-free and solvent-free phase to form a product mixture containing alkoxysilane and residual acidic chloride, with removal of resultant hydrogen chloride from the product mixture,then adding liquid or gaseous ammonia, in an amount corresponding to a stoichiometric excess, based on the content of acidic chloride, to form an ammonia-containing product mixture,treating the ammonia-containing product mixture at a temperature between 10 and 50.degree. C., wherein the ammonia and acidic chloride undergo neutralization, to form a crude product, and optionally, then separating off a salt formed in the course of neutralization, from the crude product, andrecovering the alkoxysilane by distilling the crude product.

    摘要翻译： 一种制备酸性氯化物含量小于10重量ppm的烷氧基硅烷的方法，包括：在无水和无溶剂相中使氯代硅烷与醇反应，形成含有烷氧基硅烷和残余酸性氯化物的产物混合物， 从产物混合物中除去生成的氯化氢，然后加入相当于化学计量过量的液体或气态氨，基于酸性氯化物的含量，形成含氨产物混合物，处理含氨产物混合物 在10至50℃的温度下，其中氨和酸性氯化物进行中和，以形成粗产物，并且任选地将其在中和过程中从粗产物中分离出来，并回收烷氧基硅烷 通过蒸馏粗产物。

    Apparatus and method for sampling and IR-spectroscopic analysis of high-purity, hygroscopic liquids
    75.
    发明授权
    Apparatus and method for sampling and IR-spectroscopic analysis of high-purity, hygroscopic liquids 有权
    高纯度，吸湿性液体的取样和红外光谱分析的装置和方法

    公开(公告)号：US6142024A

    公开(公告)日：2000-11-07

    申请号：US177657

    申请日：1998-10-23

    申请人： Hartwig Rauleder ,  Klaus-Dieter Krieger ,  Lothar Zehe

    发明人： Hartwig Rauleder ,  Klaus-Dieter Krieger ,  Lothar Zehe

    IPC分类号： G01N1/00 ,  G01N1/10 ,  G01N21/3577 ,  G01N21/00

    CPC分类号： G01N21/3577

    摘要： An apparatus and method for the sampling and quantitative, IR-spectroscopic determination of impurities in hygroscopic liquids. The apparatus includes a stainless steel tube having a straight bore, a first end, and a second end. A first flange attachment is located at the first end of the stainless steel tube, and a second flange attachment is located at the second end of the stainless steel tube. First and second calcium fluoride plates are also located at the first and second ends of the steel tube, respectively. The first and second plates are oriented parallel to each other and perpendicular to the axis of the stainless steel tube. First and second outer flanges hold respective of the first and second plates in place at the first and second ends of the tube, respectively, and the first and second outer flanges are mechanically fixed to the first and second flange attachments, respectively. At least one seal separates the first plate from the first flange attachment and the first outer flange. Similarly, at least one seal separates the second plate from the second flange attachment and the second outer flange. First and second three-way taps are coupled by a first stainless steel line. A second stainless steel line couples the first three-way tap to the stainless steel tube, and a third stainless steel line couples the second three-way tap to the stainless steel tube. The method includes the steps of purging the first line with nitrogen gas and purging a cell space defined by the tube at least five times.

    摘要翻译： 用于抽吸和定量，红外光谱测定吸湿性液体杂质的装置和方法。 该装置包括具有直孔，第一端和第二端的不锈钢管。 第一法兰附件位于不锈钢管的第一端，第二法兰附件位于不锈钢管的第二端。 第一和第二氟化钙板也分别位于钢管的第一和第二端。 第一和第二板彼此平行且垂直于不锈钢管的轴线定向。 第一和第二外凸缘分别在管的第一和第二端处分别保持第一和第二板的适当位置，并且第一和第二外凸缘分别机械地固定到第一和第二凸缘附件。 至少一个密封件将第一板与第一凸缘附件和第一外凸缘分开。 类似地，至少一个密封件将第二板与第二凸缘附件和第二外凸缘分开。 第一和第二三通龙头通过第一根不锈钢线连接。 第二个不锈钢线将第一个三通龙头连接到不锈钢管上，第三个不锈钢线将第二个三通龙头连接到不锈钢管上。 该方法包括以下步骤：用氮气清洗第一管线，并将由管限定的电池空间清洗至少五次。

    Method and apparatus for the preparation of cyanoalkyl-alkoxysilanes
    79.
    发明授权
    Method and apparatus for the preparation of cyanoalkyl-alkoxysilanes 失效
    用于制备氰基烷基 - 烷氧基硅烷的方法和设备

    公开(公告)号：US4876337A

    公开(公告)日：1989-10-24

    申请号：US278736

    申请日：1988-12-02

    申请人： Hartwig Rauleder ,  Claus-Dietrich Seiler ,  Hans-Joachim Vahlensieck

    发明人： Hartwig Rauleder ,  Claus-Dietrich Seiler ,  Hans-Joachim Vahlensieck

    IPC分类号： C07F7/18

    CPC分类号： C07F7/1892

    摘要： In a method of preparing cyanoalkyl-akoxysilanes, which is suitable for the production of these silanes on a large technical scale, the reaction of a chloroalkyl-alkoxysilane with an alkali metal cyanide in the presence of a solvent takes place in a stirring reactor which is provided with means for loading these starting materials and with an outlet opening for the alkali metal chloride by-product, and which is connected through a bypass valve to a column with a superimposed condenser. After the reaction in the reactor has ended, first the solvent is distilled out through the column and then the main part of the cyanosilane, and then the rest of the cyanosilane is distilled out while bypassing the column. The alkali metal chloride is then removed from the reactor through a lock.

    摘要翻译： 在适用于大规模生产这些硅烷的氰基烷基 - 烷氧基硅烷的制备方法中，在溶剂存在下氯烷基烷氧基硅烷与碱金属氰化物的反应在搅拌反应器中进行， 提供了用于装载这些原料的装置和用于碱金属氯化物副产物的出口，并且通过旁通阀连接到具有叠加的冷凝器的塔。 在反应器中的反应结束后，首先通过柱蒸馏除去溶剂，然后将氰基硅烷的主要部分蒸馏掉，然后在绕过柱子的同时蒸馏掉其余的氰基硅烷。 然后通过锁从反应器中除去碱金属氯化物。