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1.发明授权
公开(公告)号：US4876337A
公开(公告)日：1989-10-24
申请号：US278736
申请日：1988-12-02
IPC分类号： C07F7/18
CPC分类号： C07F7/1892
摘要： In a method of preparing cyanoalkyl-akoxysilanes, which is suitable for the production of these silanes on a large technical scale, the reaction of a chloroalkyl-alkoxysilane with an alkali metal cyanide in the presence of a solvent takes place in a stirring reactor which is provided with means for loading these starting materials and with an outlet opening for the alkali metal chloride by-product, and which is connected through a bypass valve to a column with a superimposed condenser. After the reaction in the reactor has ended, first the solvent is distilled out through the column and then the main part of the cyanosilane, and then the rest of the cyanosilane is distilled out while bypassing the column. The alkali metal chloride is then removed from the reactor through a lock.
摘要翻译： 在适用于大规模生产这些硅烷的氰基烷基 - 烷氧基硅烷的制备方法中，在溶剂存在下氯烷基烷氧基硅烷与碱金属氰化物的反应在搅拌反应器中进行， 提供了用于装载这些原料的装置和用于碱金属氯化物副产物的出口，并且通过旁通阀连接到具有叠加的冷凝器的塔。 在反应器中的反应结束后，首先通过柱蒸馏除去溶剂，然后将氰基硅烷的主要部分蒸馏掉，然后在绕过柱子的同时蒸馏掉其余的氰基硅烷。 然后通过锁从反应器中除去碱金属氯化物。
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2.发明授权Odor-stabilized mercaptoalkyl alkoxysilanes and a method for their preparation 失效气味稳定的巯基烷基烷氧基硅烷及其制备方法
公开(公告)号：US4604476A
公开(公告)日：1986-08-05
申请号：US683385
申请日：1984-12-19
CPC分类号： C07F7/1892
摘要： The present invention relates to mercaptoalkyl alkoxysilanes and the permanent removal of the odorants contained in these compounds. These odorants form during the preparation of the said mercaptosilanes from halogen alkylsilanes with thiourea and ammonia. The removal of the odorants is performed by the admixture of compounds which contain oxirane groups. A subsequent purification, e.g., by distillation, after the addition of these compounds in accordance with the invention, is not necessary. The additive used in accordance with the invention also brings about a sustaining of the freedom from odor for several months.
摘要翻译： 本发明涉及巯基烷基烷氧基硅烷和永久除去这些化合物中所含的气味剂。 在用硫脲和氨从卤代烷基硅烷制备所述巯基硅烷期间形成这些气味剂。 气味剂的除去是通过混合含有环氧乙烷基团的化合物进行的。 在根据本发明添加这些化合物之后，例如通过蒸馏进行的后续纯化是不必要的。 根据本发明使用的添加剂还带来几个月的气味的维持。
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公开(公告)号：US4571427A
公开(公告)日：1986-02-18
申请号：US644770
申请日：1984-08-27
摘要： A method for the preparation of 2-chloroethyldichlorosilanes by the reaction of vinyldichlorosilanes with hydrogen chloride in the presence of ferric chloride or tantalum chloride is disclosed. In the presence of these anhydrous metal chlorides, this reaction can be performed in the temperature range between 30.degree. and 90.degree. C., without the formation to any appreciable extent of methyl or ethyl trichlorosilane or other cleavage products. The end products obtained can also be easily separated from the byproducts by vacuum distillation without the need to resort to additional measures. The vacuum distillation can also be performed in the presence of the metal chlorides.
摘要翻译： 公开了在氯化铁或氯化钽存在下通过乙烯基二氯硅烷与氯化氢的反应制备2-氯乙基二氯硅烷的方法。 在这些无水金属氯化物的存在下，该反应可以在30℃至90℃的温度范围内进行，而不会形成任何明显程度的甲基或乙基三氯硅烷或其它裂解产物。 获得的最终产物也可以通过真空蒸馏容易地与副产物分离，而不需要采取额外的措施。 真空蒸馏也可以在金属氯化物的存在下进行。
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公开(公告)号：US4224233A
公开(公告)日：1980-09-23
申请号：US26633
申请日：1979-04-03
CPC分类号： C07F7/14
摘要： An improved process for the preparation of alkylsilanes and/or alkylsilanes substituted at the alkyl group by an addition reaction in the presence of a platinum or palladium supported catalyst wherein the reaction mixture is heated to its boiling point, condensed and the condensate contacts the catalyst, the improvement residing in vaporizing the reaction mixture and maintaining the vapors in out of contact relationship with respect to the platinum or palladium supported catalyst and contacting the reaction mixture only after it has condensed with the platinum or palladium supported catalyst and recovering the condensed reaction product.
摘要翻译： 制备烷基硅烷和/或烷基硅烷的改进方法是在铂或钯担载催化剂存在下，通过加成反应在烷基上取代的烷基硅烷和/或烷基硅烷，其中将反应混合物加热至其沸点，冷凝，冷凝物与催化剂接触， 改进在于蒸发反应混合物并保持蒸气与铂或钯负载的催化剂脱离接触，并且仅在与铂或钯负载的催化剂缩合并回收冷凝的反应产物之后才使反应混合物接触。
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公开(公告)号：US4196139A
公开(公告)日：1980-04-01
申请号：US28427
申请日：1979-04-09
摘要： A process for the production of an ethylsilane, which comprises contacting vinyl chloride with hydrogen silane in the presence of a platinum or palladium catalyst at a pressure of not less than 5 bars.
摘要翻译： 一种乙基硅烷的制备方法，其包括在不低于5巴的压力下，在铂或钯催化剂的存在下使氯乙烯与氢硅烷接触。
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6.发明授权Sulfurous organic silicon compounds, a process for their preparation, and their use as adhesivizing agents 失效亚硫酸有机硅化合物，其制备方法及其作为粘合剂的用途
公开(公告)号：US4060539A
公开(公告)日：1977-11-29
申请号：US660952
申请日：1976-02-24
IPC分类号： C08K5/00 , C07F7/18 , C08F30/00 , C08F30/08 , C08G77/28 , C08J5/08 , C08K5/548 , C08L1/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L27/00 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L67/00 , C08L101/00
CPC分类号： C08J5/08 , C07F7/182 , C08G77/28 , C08J2367/06
摘要： A sulfurous organosilicon compound of the general formula ##STR1## IN WHICH R represents a C.sub.1-4 alkyl, a cycloalkyl, a C.sub.1-4 alkyloxyalkyl or a phenyl radical,R' = a branched or unbranched alkylene radical of 1-6 carbon atoms, or a phenylene or benzylene radical,R" = oxygen or sulfur atom,R'" = hydrogen or CH.sub.3,X = 1 or 2, andn = 1 or 2,Processes for its production and its use as an adhesivizing agent to join inorganic substances to organic substances.
摘要翻译： 一种具有通式的亚硫酸有机硅化合物（1）其中R表示C 1-4烷基，环烷基，C 1-4烷氧基烷基或苯基，R'= 1-6的支链或非支链亚烷基 碳原子或亚苯基或亚苯基，R“=氧或硫原子，R”=氢或CH 3，X = 1或2，N = 1 OR 2，其生产方法及其用途 将有机物质加入有机物质。
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公开(公告)号：US4234503A
公开(公告)日：1980-11-18
申请号：US971966
申请日：1978-12-21
CPC分类号： C07F7/1892
摘要： A process for preparing a gamma amino propyl alkoxy silane of the formula ##STR1## wherein R is an alkyl moiety of 1 to 4 carbon atoms, R' is methyl or phenyl, and y is 0, 1 or 2 which comprises contacting the corresponding gamma-chloropropyl alkoxy silane with ammonia under pressure at a temperature between 50.degree. and 90.degree. C. while stirring the reaction mixture.
摘要翻译： 一种制备式IMAMA的γ-氨基丙基烷氧基硅烷的方法，其中R是1至4个碳原子的烷基部分，R'是甲基或苯基，y是0,1或2，其包括使相应的γ 氯丙基烷氧基硅烷与氨在压力下在50至90℃的温度下搅拌反应混合物。
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公开(公告)号：US4228092A
公开(公告)日：1980-10-14
申请号：US000605
申请日：1979-01-02
摘要： An improvement in a process for the esterification of a organochlorosilane by feeding alcohol into a chlorosilane maintained within a reaction zone without said alcohol contacting said chlorosilane in the gas phase wherein the esterification is performed stepwise with extraction of hydrogen chloride which has developed, the improvement which comprises employing in at least a final esterification step an organochlorosilane of the formulaH.sub.a R.sub.b SiCl.sub.4-a-bwhereinR represents an optionally halogen-substituted alkyl radical which can also contain an oxygen or sulfur atom in the chain, or a halogen or a NO.sub.2 group or a protected phenolic group containing aryl radical,a equals 0, 1, or 2,b equals 1 or 2, anda+b amounts to a maximum of 3,said final esterification step being performed with the addition of heat.
摘要翻译： 通过将醇保持在反应区内的氯硅烷中而不使醇与气相中的氯代硅烷接触来改善有机氯代硅烷的酯化反应，其中通过萃取开发的氯化氢逐步进行酯化，其改进是 包括在至少最终酯化步骤中使用式HaRbSiCl4-ab的有机氯硅烷，其中R表示任选的卤素取代的烷基，其还可以在链中含有氧或硫原子，或卤素或NO 2基团或被保护的 含酚基的芳基，等于0,1或2，b等于1或2，a + b最多达3，所述最终酯化步骤是通过加热进行的。
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9.发明授权
公开(公告)号：US4226793A
公开(公告)日：1980-10-07
申请号：US946464
申请日：1978-09-28
CPC分类号： C07F7/04
摘要： An improvement in a process for forming an orthosilicic acid ester or an oligomer thereof by contacting a tetrachlorosilane or higher homolog thereof with a primary alcohol, the improvement which comprises introducing the alcohol directly into a tetrachlorosilane liquid phase without said alcohol touching the gas phase and, after completion of the reaction, removing hydrogen chloride formed during the reaction from the reaction zone.
摘要翻译： 通过使四氯硅烷或其高级同系物与伯醇接触来形成正硅酸酯或其低聚物的方法的改进，其包括将醇直接引入四氯硅烷液相中而没有所述醇与气相接触， 反应完成后，从反应区除去反应期间形成的氯化氢。
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公开(公告)号：US4029679A
公开(公告)日：1977-06-14
申请号：US502125
申请日：1974-08-30
IPC分类号： C23C22/48 , C07F9/40 , C09D5/08 , C23F11/167
CPC分类号： C09D5/086 , C07F9/40 , C23F11/1676
摘要： A method for protecting the surface of a metal surface which comprises applying to said surface an organophosphorus compound of the formula ##STR1## wherein A IS 0 OR 1R is a branched or unbranched chained bivalent alkylene radical of 1 to 12 carbon atoms which is substituted or unsubstituted and can contain in the chain structure --O--, --S--, ##STR2## R' is a branched or unbranched alkyl radical of 1 to 12 carbon atoms which can be halogen substituted and can contain in the chain structure ##STR3## X is an epoxy ring, halogen, alkylene, carboxylic acid ester residue, amino, isocyanato, isothiocyanato, urea, thiourea, urethano, alkyl substituted thio radical or the radical or a heterocyclic ring containing O, S or N in the ring structure; a new organophosphorus compounds having the formula set forth above and more particularly defined by specific chemical structures.
摘要翻译： 一种用于保护金属表面的方法，其包括向所述表面施加下式的有机磷化合物，其中A 0 OR 1 R是被取代的1至12个碳原子的支链或非支链链式二价亚烷基 或未取代的并且可以在链结构中包含-O - ， - S-，R'是具有1至12个碳原子的支链或非支链烷基，其可以被卤素取代并且可以含有链结构
X是环状环，卤素，亚烷基，羧酸酯残基，氨基，异氰酸酯基，异硫氰酸根合，脲基，硫脲，氨基甲酰基，烷基取代的硫基或环或在环结构中含有O，S或N的杂环; 具有上述式的新的有机磷化合物，更具体地由具体的化学结构定义。
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