公开(公告)号：US20030096908A1

公开(公告)日：2003-05-22

申请号：US09884173

申请日：2001-06-19

Applicant: 3M Innovative Properties Company

Inventor： Steven M. Heilmann ,  Babu N. Gaddam ,  Ahmed S. Abuelyaman ,  Duane D. Fansler ,  Todd D. Jones ,  Maureen A. Kavanagh ,  Kevin M. Lewandowski ,  Michael S. Wendland

IPC: C08L051/08 ,  C08G063/48 ,  C08G063/91 ,  C08L051/00

CPC classification number: C09D201/005 ,  C09D201/08

Abstract: The present invention provides novel compositions prepared from a first oligomer containing reactive functional groups capable of reaction at effective rates (at normal processing temperatures) with a co-reactive second component possessing functionality that is complementary to that of the first oligomer. The compositions may be used as coatings, including hard surface coatings, clear coatings, powder coatings and pattern coatings; as adhesives, including pressure sensitive adhesives and hot melt adhesives; as sealants; as optical coatings; as blown microfibers (BMF); as high refractive index optical materials; as barrier films; in microreplication; as low adhesion backsizes, (LABs) and as release coatings.

Abstract translation: 本发明提供由含有能够以有效速率（在正常加工温度下）与具有与第一低聚物互补的官能团的共反应性第二组分反应的反应性官能团的第一低聚物制备的新型组合物。 组合物可以用作涂层，包括硬表面涂层，透明涂层，粉末涂层和图案涂层; 作为粘合剂，包括压敏粘合剂和热熔粘合剂; 作为密封剂; 作为光学涂料; 作为吹制微纤维（BMF）; 作为高折射率光学材料; 作为阻挡膜; 微复制; （LAB）和脱模涂层。

公开(公告)号：US20020182417A1

公开(公告)日：2002-12-05

申请号：US09914561

申请日：2001-08-27

Inventor： Minoru Kurisaki ,  Takamasa Harada

IPC: B32B027/38

CPC classification number: C09D201/08 ,  C09D201/06 ,  Y10T428/31511 ,  Y10T428/31525 ,  Y10T428/31663

Abstract: The present invention is to provide a coating composition capable of forming a protective film excellent in adhesion properties. Such a coating composition comprises a specific polymer containing carboxyl group, a specific multifunctional epoxide-containing compound having two or more epoxy groups, an organic solvent, and an amino-containing silane coupling agent represented by the following general formula (I):H2NnullR1nullSinull(OR2)3nullnull(I)wherein, R1 is an unsubstituted alkylene group, and R2's are independently an unsubstituted alkyl group.

Abstract translation: 本发明提供能够形成粘合性优异的保护膜的涂料组合物。 这种涂料组合物包含含有羧基的特定聚合物，具有两个或多个环氧基的特定多官能环氧化物的化合物，有机溶剂和由以下通式（I）表示的含氨基的硅烷偶联剂：<段落 其中，R 1为未取代的亚烷基，且R 2独立地为未取代的烷基，其中R 1为未取代的烷基， 组。

公开(公告)号：US20010006994A1

公开(公告)日：2001-07-05

申请号：US09727136

申请日：2000-11-30

Inventor： Gert Dworak ,  Ulrike Kuttler

IPC: C08F008/30 ,  C08L075/00

CPC classification number: C09D201/08 ,  C09D175/04 ,  C08L2666/14

Abstract: Coating composition especially for preparing automotive surfacers, comprising an anionically stabilized resin, preferably a condensation product A of a carboxyl group-containing resin A1 and a hydroxyl group-containing resin A2, and a curing agent C, which becomes active even at room temperature or slightly elevated temperature of up to not more than 120null C., and comprises a mixture of an unblocked isocyanate C1 and a hydrophilic partially etherified amino resin C2.

Abstract translation: 涂料组合物特别用于制备汽车表面活性剂，其包含阴离子稳定的树脂，优选含羧基树脂A1和含羟基的树脂A2的缩合产物A和固化剂C，其即使在室温下也变得有活性，或 稍高的温度高达不高于120℃，并且包含未封端的异氰酸酯C1和亲水部分醚化的氨基树脂C2的混合物。

公开(公告)号：US5719234A

公开(公告)日：1998-02-17

申请号：US747341

申请日：1996-11-12

Applicant: Motoshi Yabuta ,  Masaaki Saika ,  Satoru Ito ,  Hiroyuki Okada ,  Yasumasa Okumura ,  Hiroshi Igarashi ,  Satoshi Ikushima

Inventor： Motoshi Yabuta ,  Masaaki Saika ,  Satoru Ito ,  Hiroyuki Okada ,  Yasumasa Okumura ,  Hiroshi Igarashi ,  Satoshi Ikushima

IPC: B05D1/36 ,  B05D7/00 ,  C08L43/04 ,  C08L83/04 ,  C09D133/06 ,  C09D137/00 ,  C09D143/04 ,  C09D163/00 ,  C09D183/04 ,  C09D201/08

CPC classification number: B05D7/532 ,  C09D133/064 ,  C09D143/04 ,  C09D201/08 ,  C08L2205/18 ,  C08L43/04 ,  C08L83/04 ,  Y10T428/2949 ,  Y10T428/2958 ,  Y10T428/31663

Abstract: An object of the present invention is to provide a heat-curable high solid coating composition capable of forming a coating film which is excellent in both acid resistance and scratch resistance, and a method for forming a topcoat using said composition. The present invention provides a heat-curable high solid coating composition comprising: (A) a carboxyl-containing compound, (B) a vinyl polymer having an epoxy group, a hydroxyl group and a hydrolyzable alkoxysilyl group in one molecule, (C) a reactive organopolysiloxane, and (D) a crosslinked particulate polymer. The present invention also provides a method for forming a topcoat using said composition.

Abstract translation: 本发明的目的是提供一种能够形成耐酸性和耐划伤性优异的涂膜的热固性高固体涂料组合物，以及使用该组合物形成面漆的方法。 本发明提供一种热固性高固体涂料组合物，其包含：（A）含羧基化合物，（B）一分子中具有环氧基，羟基和可水解烷氧基甲硅烷基的乙烯基聚合物，（C） 反应性有机聚硅氧烷，（D）交联的颗粒聚合物。 本发明还提供了使用所述组合物形成面漆的方法。

公开(公告)号：US5710208A

公开(公告)日：1998-01-20

申请号：US542544

申请日：1995-10-13

Applicant: Klaus Bederke ,  Carmen Flosbach ,  Eva Frigge ,  Walter Schubert

Inventor： Klaus Bederke ,  Carmen Flosbach ,  Eva Frigge ,  Walter Schubert

IPC: C09D133/10 ,  C08L33/06 ,  C09D133/04 ,  C09D133/06 ,  C09D167/00 ,  C09D167/02 ,  C09D167/06 ,  C09D171/02 ,  C09D175/04 ,  C09D201/00 ,  C09D201/08 ,  C08J3/00

CPC classification number: C09D171/02 ,  C09D133/064 ,  C09D167/06 ,  C09D201/08 ,  C08L33/068

Abstract: A binder composition, a coating composition containing this binder, a process for its production and use to produce single or multi-layer lacquer coatings, particularly in the automotive sector, are described. The binder composition contains A) 25 to 75 wt. % of one of more resins containing carboxyl groups, which may contain .alpha.,.beta.-unsaturated groups, with a number average molecular weight (Mn) of 500 to 10000 g/mol and an acid value of 15 to 200 mg KOH/g, B) 25 to 75 wt. % of one or more polyethers, polyesters, polyether/polyesters and/or (meth)acrylic copolymers with at least one .alpha.,.beta.-unsaturated group and at least one epoxy group per molecule, wherein the .alpha.,.beta.-unsaturated groups and epoxy groups are present in a numerical ratio of 20:80 to 80:20, with a number average molecular weight (Mn) of up to 10000 g/mol, C) 0 to 60 wt. % of one or more polyols with at least two hydroxyl functional groups per molecule, D.sub.1) 0 to 20 wt. % of one or more melamine resins, D.sub.2) 0 to 40 wt. % of one or more capped polyisocyanates, wherein the sum of the weight percentages of components A), B), C), D.sub.1) and D.sub.2) is 100 wt. %, together with E) 0 to 10 wt. % of one or more catalysts to catalyze the reaction of the carboxyl and epoxy groups, related to the sum of the weights of components A) to D.sub.2), and F) 0.1 to 10 wt. % of one or more thermally or photochemically activated initiators, related to the total weight of components A) and B).

Abstract translation: 描述了粘合剂组合物，含有该粘合剂的涂料组合物，其生产和用于生产单层或多层漆涂料的方法，特别是在汽车领域。 粘合剂组合物含有A）25〜75wt。 可以含有数均分子量（Mn）为500〜10000g / mol，酸值为15〜200mgKOH / g的α，β-不饱和基团的含羧基的树脂中的一种以上的羧基，B值 ）25〜75重量％ ％的一种或多种聚醚，聚酯，聚醚/聚酯和/或具有至少一个α，β-不饱和基团和每分子至少一个环氧基团的（甲基）丙烯酸共聚物，其中α，β-不饱和基团和环氧基团 以20:80至80:20的数值比存在，数均分子量（Mn）高达10000g / mol，C）0至60wt。 ％的一种或多种每分子具有至少两个羟基官能团的多元醇，D1）0-20重量％ ％的一种或多种三聚氰胺树脂，D2）0-40重量％ ％的一种或多种封端的多异氰酸酯，其中组分A），B），C），D1）和D2的重量百分比之和为100重量％。 ％，连同E）0〜10wt。 ％的一种或多种催化剂催化羧基和环氧基的反应，与组分A）至D2的重量之和相关），和F）0.1至10wt。 ％的一种或多种热或光化学活化的引发剂，与组分A）和B）的总重量有关。

公开(公告)号：US5124176A

公开(公告)日：1992-06-23

申请号：US347149

申请日：1989-05-03

Applicant: Alastair R. Marrion

Inventor： Alastair R. Marrion

IPC: C09D5/03 ,  C08G59/58 ,  C09D163/00 ,  C09D167/00 ,  C09D201/08

CPC classification number: C09D167/00 ,  C08G59/58 ,  C09D163/00 ,  C09D201/08 ,  Y10S525/934

Abstract: A powder coating composition comprises a component (A) containing carboxylic acid or anhydride functionality and a component (B) containing hydroxy functionality. The components (A) and (B) are both solids at temperatures up to 50.degree. C. and at least one of them is a synthetic resin having a glass transition temperature in the range 0.degree. to 120.degree. C. The carboxylic acid or anhydride-functional component (A) is a compound or polymer containing at least two cyclic carboxylic anhydride groups per molecule or is a compound containing a moiety of the formula: ##STR1## where X is a hydrogen atom or an alkyl group, or a cyclic anhydride thereof. The hydroxy-functional component (B) contains at least two hydroxy groups per molecule and contains at least one amine group in its molecule to catalyze the reaction of the carboxylic acid or anhydride groups of component (A) with the hydroxy groups of component (B). The composition is prepared by mixing the ingredients, extruding them at a temperature above the glass transition temperature of at least one of the components but below the fusion temperature, and comminuting the extrudate. The composition is applied to substrates and heated to cause fusion and reaction of the ingredients to cure the coating layer formed.

Abstract translation: 粉末涂料组合物包含含有羧酸或酸酐官能团的组分（A）和含有羟基官能团的组分（B）。 组分（A）和（B）在高达50℃的温度下都是固体，并且它们中的至少一种是玻璃化转变温度在0-120℃的合成树脂。羧酸或酸酐 官能组分（A）是每分子含有至少两个环状羧酸酐基团的化合物或聚合物，或者是含有下式的部分的化合物：其中X是氢原子或烷基，或环状酸酐 其中。 羟基官能组分（B）每分子含有至少两个羟基，并在其分子中含有至少一个胺基，以催化组分（A）的羧酸或酸酐基团与组分（B）的羟基反应 ）。 通过混合成分，在高于至少一种组分的玻璃化转变温度但低于熔融温度的温度下挤出组合物并粉碎挤出物来制备组合物。 将组合物施加到基底上并加热，使成分的熔融和反应固化形成的涂层。

公开(公告)号：US4602061A

公开(公告)日：1986-07-22

申请号：US716273

申请日：1985-03-26

Applicant: Jaap M. Akkerman

Inventor： Jaap M. Akkerman

IPC: C08G63/00 ,  C08F283/00 ,  C08G18/04 ,  C08G59/00 ,  C08G59/02 ,  C08G61/12 ,  C08G63/12 ,  C08G63/16 ,  C08G63/91 ,  C08G85/00 ,  C09D4/00 ,  C09D4/02 ,  C09D163/00 ,  C09D165/00 ,  C09D167/02 ,  C09D175/00 ,  C09D175/04 ,  C09D201/08 ,  C08G63/02

CPC classification number: C08G61/128 ,  C08F283/00 ,  C08G63/12 ,  C08G85/00 ,  C09D201/08

Abstract: An ambient temperature curable composition is prepared from a .alpha.,.beta.-ethylenically unsaturated carbonyl compound (such as trimethylol propane triacrylate) and a compound chosen from a particular class of compounds having an activated CH group (such as malonate group-containing oligomeric or polymeric esters). The coatings of the invention cure quickly without heating, and have excellent hardness.

Abstract translation: 由α，β-烯属不饱和羰基化合物（例如三羟甲基丙烷三丙烯酸酯）和选自特定类别的具有活化的CH基团的化合物（例如含丙二酸酯基的低聚或聚合酯）制备环境温度可固化组合物 ）。 本发明的涂层在不加热的情况下快速固化，并具有优异的硬度。

公开(公告)号：US4180612A

公开(公告)日：1979-12-25

申请号：US540633

申请日：1975-01-13

Applicant: Denis R. Pauze ,  Donald G. Pucci

Inventor： Denis R. Pauze ,  Donald G. Pucci

IPC: C08G69/00 ,  C08G18/08 ,  C08G63/00 ,  C08G63/685 ,  C08G63/78 ,  C08G69/44 ,  C08G73/00 ,  C08G73/06 ,  C08G73/16 ,  C09D5/25 ,  C09D179/08 ,  C09D201/08 ,  H01B3/30 ,  H01B3/42 ,  C08G18/64 ,  C08G63/68 ,  C08G63/70

CPC classification number: C08G63/6854 ,  C08G18/0823 ,  C08G69/44 ,  C08G73/16 ,  C09D201/08 ,  H01B3/306 ,  H01B3/307 ,  H01B3/421 ,  Y10S260/34 ,  Y10T428/31551 ,  Y10T428/31786

Abstract: The invention relates to polymeric coating compositions which are at least partially soluble in water.Polyesters, polyesterimides, polyesteramides, polyesteramideimides, polyester hydantoins and polyester urethanes are prepared with free carboxyl or carboxylic acid groups. At least part of the carboxylic acid groups are neutralized with amine containing material producing a coating composition which is at least partially soluble in water. The coating compositions are particularly useful as electric insulating coatings or wire enamels which are readily coated on a metallic or other substrate and when cured from coatings having good electrical and physical properties.

Abstract translation: 本发明涉及至少部分可溶于水的聚合物涂料组合物。 聚酰胺，聚酰亚胺，聚酯酰胺，聚酰胺酰亚胺，聚酯乙内酰脲和聚酯氨基甲酸酯与游离羧基或羧酸基团一起制备。 至少部分羧酸基团被含胺材料中和，产生至少部分可溶于水的涂料组合物。 涂料组合物特别可用作电绝缘涂层或电线搪瓷，其易于涂覆在金属或其它基材上，并且当从具有良好电学和物理性质的涂层固化时。

公开(公告)号：US4132686A

公开(公告)日：1979-01-02

申请号：US765360

申请日：1977-02-03

Applicant: Kazuaki Toyoshima ,  Michitoshi Koyanagi ,  Tameyuki Suzuki

Inventor： Kazuaki Toyoshima ,  Michitoshi Koyanagi ,  Tameyuki Suzuki

IPC: B05D1/36 ,  B05D7/00 ,  C09D167/00 ,  C09D201/08 ,  B44D1/44 ,  C09D3/52 ,  C09D3/64

CPC classification number: B05D7/52 ,  B05D1/36 ,  C09D167/00 ,  C09D201/08 ,  B05D2451/00 ,  Y10S524/906

Abstract: An improvement in a process for coating a surface with a aqueous paint composition containing as the primary film-forming components: a synthetic polycarboxylic acid resin as the main binder component; an amino resin as a heat curing cross-linking agent for the polycarboxylic acid resin and a neutralizing agent for neutralizing the acid groups of the polycarboxylic acid resin, is provided. The improvement is applying the aqueous paint composition to the surface as two compositions (A) comprising a synthetic polycarboxylic acid resin having a neutralization degree of 30 to 70% and an amino resin; and (B) comprising a synthetic polycarboxylic acid resin having a neutralication degree 30 to 80% higher than that of the polycarboxylic acid resin of (A) and an amino resin, or (C) a neutralizing agent comprising ammonia or an organic amine.

Abstract translation: 用包含作为主要成膜组分的水性涂料组合物涂覆表面的方法的改进：合成多元羧酸树脂作为主要粘合剂组分; 提供了作为多元羧酸树脂的热固化交联剂的氨基树脂和中和多元羧酸树脂的酸基的中和剂。 改进之处在于，将水性涂料组合物作为包含中和度为30〜70％的合成多元羧酸树脂和氨基树脂的两种组合物（A） 和（B）包含具有比（A）的多元羧酸树脂和氨基树脂高30-80％的中和度的合成多元羧酸树脂，或（C）包含氨或有机胺的中和剂。

公开(公告)号：US4125499A

公开(公告)日：1978-11-14

申请号：US807109

申请日：1977-06-16

Applicant: Jerald D. Howard

Inventor： Jerald D. Howard

IPC: C09D5/02 ,  C09D201/08 ,  B67B7/00 ,  C09D3/58 ,  C09D3/64 ,  C09D3/74

CPC classification number: C09D5/021 ,  C09D201/08

Abstract: A paint composition which can be applied from a spray can yet which can be cleaned with water. The composition comprises a water-soluble, neutralized resin film former contained in a water-soluble solvent, but has a maximum water content of 10 weight percent. Formulations can be provided to obtain coatings ranging from flat to high gloss.

Abstract translation: 可以从喷雾施用的涂料组合物还可以用水清洗。 该组合物包含水溶性中和的树脂成膜剂，其包含在水溶性溶剂中，但最大含水量为10重量％。 可以提供配方以获得从平光到高光泽的涂层。