摘要:
This invention record describes the production of a low vulnerability propellant (LOVA) ingredients utilizing mixtures of alkyl nitratoethyl nitramines (alkyl NENAs) and/or bis (2-nitroxyethyl) nitramine (DINA) with nitrocellulose. Described compositions provide lower freezing points and decreases sensitivity while maintaining or surpassing output realized with currently used nitroglycerins/nitrocellulose mixtures. A process to provide for the production of desired mixtures of alkyl NENAs with each other or with DINA in a safe, cost-effective co-nitration process is disclosed. The process involves mixing together predetermined amounts of precursors for each of alkyl NENAs and/or DINA to be present in the final mix. Nitrating the precursors followed by a catalyst reaction, wash and neutralization step.
摘要:
Disclosed is a method of forming tamper-proof coatings on electronic devices. The method comprises applying a coating of a silica precursor resin and a filler onto the electronic device, wherein the filler is one which reacts in an oxidizing atmosphere to liberate enough heat to damage the electronic device. The coated electronic device is then heated at a temperature sufficient to convert the silica precursor resin to a silica containing ceramic matrix.
摘要:
Solid composite propellants are prepared by combining solid fuel and oxidizer particles, hydroxy-terminated prepolymers, and bonding agents which have polar functional groups to bond to the oxidizer particles and hydroxyl groups converted to isocyanate groups to bond to the binder. These bonding agents replace the non-reacted precursors as well as aziridine-type bonding agents in common use.
摘要:
This invention is first, a difunctional poly(glycidyl nitrate) oligomer (PGN oligomer), second, nitrated PGN oligomer and third, the use of the nitrated PGN oligomer as a plasticizer, particularly as a plasticizer for binders used in and/or as energetic formulations. Examples of energetic formulations are propellants, pyrotechnics and explosives and other such compositions. More particularly, this invention is a difunctional poly(glycidyl nitrate) oligomer of the formula ##STR1## where n is 0 to 3, having a M.sub.n of from about 304 to about 994. Another embodiment is the nitrated difunctional poly(glycidyl nitrate) oligomer of the formula ##STR2## where n is 0 to 3, having a M.sub.n of from about 394 to about 1084. This invention also comprises a plasticizer for binder compounds, namely, the nitrated PGN oligomer above; preferably the plasticizer above is used wherein the binder compound is used in energetic formulations; and preferably the binder compound is an energetic compound; more preferably the energetic formulation is selected from the group consisting of propellants, pyrotechnics and explosives.
摘要:
Improved thermoplastic elastomer compositions having improved processing and mechanical characteristics without requiring addition of excessive quantities of plasticizer comprise at least one thermoplastic elastomer loaded with a crystalline modifier having a relatively low melting point. The modifier can be liquid at the processing temperature, resulting in increased ease in handling of the product. An exemplary crystallizable modifier is an alkylated pentacycloundecane dimer.
摘要:
A castable, energetic, plastic-bonded explosive containing glycidyl azide lymer (GAP) an energetic polymer binder combined with the energetic plasticizers trimethyloethane trinitrate (TMETN) and trimethylene glycol dinitrate (TEGDN) or bisdinitropropyl formal and acetal mixture (BDNPF/A), and the explosive solid cyclotetramethylene tetranitramine (HMX) or cyclotrimethylene trinitramine (RDX) having the desirable mechanical properties, insensitivity, and excellent aging properties at much higher solids loading and thus explosive performance than previous compositions. The invention uniquely combines the high energy of high solids loading combined with energetic polymers and plasticizers to provide the insensitivity of rubbery explosive compositions.
摘要:
A stable chlorine-free solid rocket propellant composition containing a low energy binder component having an HEX value not exceeding about 0 cal/gm and comprising, in combination, a nitrate salt and/or phase stabilized nitrate salt as oxidizer component, a Mg/Al alloy of limited Mg content as a fuel component, at least one energetic plasticizer component, and a burn rate catalyst.
摘要:
A method of manufacturing an oriented silicon steel sheet which achieves a high magnetic flux density while reducing the core loss. A silicon steel sheet containing Al and Sb as inhibitor components is cold-rolled once or a plurality of times. During cooling for annealing before final cold rolling, a small strain is created on the sheet and the temperature is within a certain range. Carbide precipitation is suitably controlled to precipitate carbides comparatively coarsely in grains.
摘要:
Low-vulnerability component of explosive ammunition and process for initiating a charge of low-sensitivity composite explosive. The subject of the present invention is a low-vulnerability component of explosive ammunition consisting of a preferably metallic enclosure 1 containing a charge 2 of low-sensitivity composite explosive E and, as initiating relay, a plane wave generator 3 consisting, on the one hand, of a cylindroconical cap 7 made of composite explosive A, the large base surface having a diameter d greater than the critical diameter of the explosive E, the cavity 8 of this cap 7 being filled with a composite explosive B and, on the other hand, of a reinforcer made of composite explosive C, of thickness e greater than 0.1 d, the detonation pressure of the explosive C being higher than that of the explosive E. The detonability index according to the test for detonability behind a barrier is between 90 and 200 cards in the case of the explosives A, B and C and lower than 90 cards in the case of the explosive E. The invention also relates to the process for initiating the charge 2 using the generator 3.
摘要:
An energetic composite made of a mixture of(1) a solid nitrate ester of a cyclodextrin or a mixture of cyclodextrins;nd(2) an energetic organic nitrate ester plasticizer.