Abstract:
The disclosed subject matter includes a new type of chemical reactor, described as hydrogen or oxygen electrochemical pumping catalytic membrane reactor. This new type of reactor is suitable for increasing the selectivity and the conversion rate of dehydrogenation, hydrogenation, deoxidation and oxidation reactions and namely in the direct amination reaction of hydrocarbons. This reactor can be used for the production of several chemical compounds, such as the direct amination of hydrocarbons and in particular for the synthesis of aniline from benzene. The disclosed subject matter includes a device and process wherein hydrogen is removed by electrochemical pumping of the hydrogen formed or by oxygen pumping so, as hydrogen is formed, it is oxidized. This new reactor exhibits benzene to aniline conversion higher than 40%.
Abstract:
An apparatus and method for generating a Contact Glow Plasma Discharge in an electrolyte such as 7% K2CO3. A Shrouded Toroidal Anode is partially submerged in the electrolyte directly above a Flat Torus Cathode (totally submerged in the electrolyte), spaced approximately 50 mm apart, and the two electrodes are arranged in a concentric manner. A potential difference is applied from the cathode to the anode causing gas to be formed on the cathode. This is followed by a contact glow plasma being formed on the surface of the cathode and electromagnetically confined by a Spheromark formed by the configuration of the electrodes. This confinement of the plasma prevents a plasma arc from consuming the anode, which in turn allows for the application of 12,000 Watts and the occurrence of “non-linear electron resonance heating”. The effects of nonlinear series resonance increase the total power dissipation by factors of 2-5 for low pressure capacitive plasmas. Thus explaining the 303% efficiency obtained with this apparatus.
Abstract:
A portable hydrogen and oxygen supply system produces gaseous hydrogen and gaseous oxygen from water. It separates the gasses and vents them into two separate chambers. The supply system creates water disassociation through an array of concentric hexagonal hydrogen collector tubes, anode rods and a cathode matrix, all of which are submersed in water. The anode rods and cathode matrix are supplied DC electrical current. The water separates (disassociates) as atomic hydrogen is drawn to the negatively charged anode rods and the atomic oxygen is drawn to the positively charged cathode matrix. The hydrogen, on its path to the anode, passes through the walls of the hydrogen collector tubes to be collected in the first chamber. The oxygen is unable to pass through the walls of the tubes, and remains outside the tubes to be collected in the second chamber.
Abstract:
The electrochemical cell consists of hollow tube and centralized copper rod. The tubes have first and second ends. The first end cap is used to close the first open end. The anolyte inlet is extended through the first end cap in anolyte compartment and catholyte inlet is extended through the first end cap in catholyte compartment. The anolyte and catholyte compartments are separated by ion exchange membrane fixed over inner hollow tube having holes on the surface. A first Teflon gasket has provision for inlet of anolyte and catholyte tube is secured between first tubes end and first end cap. The copper rod is placed at the center of the tubes acts as cathode. The circular ring works as scrapper to take out deposited copper is provided. A second end cap is used to close the second open. A second Teflon gasket is secured between second tubes end and second end cap. The second end cap has provision for anolyte outlet and comprises a conical dome to collect the deposited copper and transport it along with catholyte. The anolyte trappers and catholyte trappers are connected through the tubes to anolyte and catholyte half cells. The anolyte and catholyte are re-circulated through peristaltic pumps, one on each side.
Abstract:
A bipolar electrolytic cell particularly useful for electrochemical processes carried out with periodic reversal of polarity is provided. The cell is equipped with a series of concentric electrode pairs, the innermost pair and the outermost pair being connected to the poles of a DC generator and the intermediate pairs acting as bipolar electrodes. The different pairs of electrodes are arranged and connected in such a way that, at each stage of the process, the overall cathodic area is equal to the anodic area.
Abstract:
A method for recycling metallic material produced by an electrochemical material removal process. The method includes flowing an electrolyte solution between an anode workpiece and a cathode tool in a first electrolytic process, the first electrolytic process including applying a first electrolytic current and voltage between the anode workpiece and the cathode tool and thereby causing metal ions to be removed from the anode workpiece and dissolved and substantially retained in the electrolyte solution. The electrolyte solution with the metal ions therein is passed between an electrowinning cathode and an electrowinning anode in a second electrolytic process, the second electrolytic process including applying a second electrolytic current and voltage between the electrowinning cathode and the electrowinning anode and thereby causing the metal ions to be removed from the electrolyte solution and deposited onto the electrowinning cathode.
Abstract:
The application is directed towards methods for purifying an aluminum feedstock material. A method provides: (a) feeding an aluminum feedstock into a cell (b) directing an electric current into an anode through an electrolyte and into a cathode, wherein the anode comprises an elongate vertical anode, and wherein the cathode comprises an elongate vertical cathode, wherein the anode and cathode are configured to extend into the electrolyte zone, such that within the electrolyte zone the anode and cathode are configured with an anode-cathode overlap and an anode-cathode distance; and producing some purified aluminum product from the aluminum feedstock.
Abstract:
The invention provides a process and an apparatus for the production of a metal selected from metallic alkali metals, M, and alkaline earth metals, Mac from the molten salts thereof, the apparatus including at least an electrochemical cell with planar anodes and cathodes installed in the following sequence: {a-c-a)n to produce alkali metal or alkaline earth metals electrolytically!y from the respective chloride salts thereof, wherein n represents the number of times the sequence of anode-cathode-anode is repeated.
Abstract:
Various embodiments provide a process roasting a metal bearing material under oxidizing conditions to produce an oxidized metal bearing material, roasting the oxidized metal bearing material under reducing conditions to produce a roasted metal bearing material, and leaching the roasted metal bearing material in a basic medium to yield a pregnant leach solution.
Abstract:
Between an anode and a cathode, a salt melt containing a metal ion is separated from the anode by a gap across which an electric arc can be formed. The metal ion is deposited on the anode and subsequently removed.