公开(公告)号：US20100048073A1

公开(公告)日：2010-02-25

申请号：US12596476

申请日：2009-04-11

申请人： Yoshiaki Hirose ,  Tetsuya Yuki

发明人： Yoshiaki Hirose ,  Tetsuya Yuki

IPC分类号： B32B5/02 ,  B32B33/00 ,  B32B9/04 ,  D03D19/00 ,  D04H13/00

CPC分类号： C30B15/10 ,  B32B18/00 ,  C04B35/536 ,  C04B2235/656 ,  C04B2235/6582 ,  C04B2235/72 ,  C04B2237/363 ,  C04B2237/385 ,  C04B2237/704 ,  Y10T156/10 ,  Y10T428/30 ,  Y10T442/134 ,  Y10T442/60

摘要： An expanded graphite sheet with improved tensile strength is provided. By using an expanded graphite sheet with improved tensile strength as a lining for a carbonaceous crucible, a method of protecting a carbonaceous crucible is provided that reduces work hours remarkably, makes it possible to cover the inner surface of the crucible without breaking the sheet or producing gaps, and is suitable for increasing the size of the crucible, and a single-crystal pulling apparatus is also provided. An expanded graphite sheet (10) is characterized in that a reinforcing material (12) comprising carbon fibers is formed in a laminate form on at least one side of a substrate (11) made of an expanded graphite material. Another feature is interposing the expanded graphite sheet (10) between a quartz crucible and a carbonaceous crucible in which the quartz crucible is placed, to use the expanded graphite sheet as a lining for covering an inner surface of the carbonaceous crucible.

摘要翻译： 提供了具有提高拉伸强度的膨胀石墨片。 通过使用具有提高的拉伸强度的膨胀石墨片作为碳质坩埚的衬里，提供了保护碳质坩埚的方法，其显着地减少了工作时间，使得可以在不破坏片材的情况下覆盖坩埚的内表面或产生 间隙，并且适合于增加坩埚的尺寸，并且还提供单晶拉制装置。 膨胀石墨片（10）的特征在于，在由膨胀石墨材料制成的基板（11）的至少一侧上，层叠形成由碳纤维构成的增强材料（12）。 另一个特征是将膨胀石墨片（10）插入到石英坩埚和其中放置石英坩埚的碳质坩埚之间，使用膨胀石墨片作为覆盖碳质坩埚内表面的衬里。

公开(公告)号：US20090280413A1

公开(公告)日：2009-11-12

申请号：US12439311

申请日：2007-07-06

申请人： Naoto Ohta ,  Kazuhito Hoshi ,  Shingo Bito ,  Akio Yamanaka ,  Tomoyuki Okuni

发明人： Naoto Ohta ,  Kazuhito Hoshi ,  Shingo Bito ,  Akio Yamanaka ,  Tomoyuki Okuni

IPC分类号： H01M4/58

CPC分类号： H01M4/133 ,  C01B32/20 ,  H01M4/1393 ,  H01M4/583 ,  H01M10/0525 ,  H01M2004/021 ,  H01M2004/027

摘要： There is obtained a carbon material for lithium-ion secondary battery negative electrode, a low-crystalline carbon impregnated carbon material for lithium-ion secondary battery negative electrode, a negative electrode plate, and a lithium-ion secondary battery, each of which realizes a first charge/discharge cycle with less gas generation and provides a rapid charge/discharge. The carbon material is obtained by: blending and kneading a carbonaceous aggregate with a binder to form a composition; press molding the composition into an article; carbonizing the press molded article; graphitizing the article to obtain an artificial graphite block; milling the block; and carrying out particle size control. The carbon material has characteristics of: (1) R-value=(I1360/I1580)≧0.2, where R-value is defined by the ratio of D band to G band in Raman spectrum using Nd:YAG laser light of 532 nm wavelength; and (2) d(002)≧0.336 nm, and Lc(002)≦50 nm, where d(002) and Lc(002) are crystallographic parameters calculated by Gakushin-method. The carbon material is used for the negative electrode plate of a lithium-ion secondary battery, and used in the lithium-ion secondary battery having therein the negative electrode plate.

摘要翻译： 得到锂离子二次电池用负极用碳材料，锂离子二次电池用负极用低碳碳浸渍碳材料，负极板，锂离子二次电池，实现了 第一次充放电循环，气体产生较少，并提供快速充放电。 碳材料通过以下方式获得：将碳质骨料与粘合剂混合并捏合以形成组合物; 将组合物压制成制品; 将压制成型品碳化; 石墨化制品以获得人造石墨块; 铣块; 并进行粒度控制。 碳材料具有以下特征：（1）R值=（I1360 / I1580）> = 0.2，其中R值由使用Nd：YAG激光532nm的拉曼光谱中的D带与G带的比率定义 波长; 和（2）d（002）> = 0.336nm，Lc（002）<= 50nm，其中d（002）和Lc（002）是通过Gakushin方法计算的晶体参数。 碳材料用于锂离子二次电池的负极板，并用于其中具有负极板的锂离子二次电池中。

公开(公告)号：US07608235B2

公开(公告)日：2009-10-27

申请号：US11572938

申请日：2005-08-03

申请人： Akimasa Tasaka ,  Masashi Kodama ,  Udai Tanaka ,  Hitoshi Takebayashi ,  Tetsuro Tojo ,  Atsuhisa Mimoto

发明人： Akimasa Tasaka ,  Masashi Kodama ,  Udai Tanaka ,  Hitoshi Takebayashi ,  Tetsuro Tojo ,  Atsuhisa Mimoto

IPC分类号： C01B21/088 ,  C25B1/24 ,  C25B1/00

CPC分类号： C25B1/245 ,  C25B11/14

摘要： A carbon electrode for producing gaseous nitrogen trifluoride comprising a dense texture with an average pore size of 0.5 μm or less is provided. The carbon electrode contains a carbonaceous material, and 3 to 10 wt % of at least one selected from magnesium fluoride and aluminum fluoride which have a melting point not lower than the baking temperature of the carbonaceous material.

摘要翻译： 提供了一种用于生产气态三氟化氮的碳电极，其包含平均孔径为0.5μm或更小的致密结构。 碳电极含有碳质材料，并且具有熔点不低于碳质材料的烧成温度的3〜10重量％的选自氟化镁和氟化铝的至少一种。

公开(公告)号：US07351322B2

公开(公告)日：2008-04-01

申请号：US10702654

申请日：2003-11-07

申请人： Jiro Hiraiwa ,  Osamu Yoshimoto ,  Tetsuro Tojo

发明人： Jiro Hiraiwa ,  Osamu Yoshimoto ,  Tetsuro Tojo

IPC分类号： C25B9/00 ,  C25B1/24

CPC分类号： C25B1/245 ,  C25B15/02

摘要： A fluorine gas generator for generating fluorine gas by electrolysis of an electrolytic bath comprising a hydrogen fluoride-containing mixed molten salt in which generator the position of the electrolytic bath liquid surface in the electrolytic cell can be safely controlled even during suspension of electrolysis therein is provided. The generator comprises an anode chamber and a cathode chamber separated from each other by a partition wall and is provided with electrolytic bath liquid level controlling means for controlling the electrolytic bath liquid level in at least one of the anode chamber and cathode chamber during suspension of fluorine gas generation.

摘要翻译： 提供一种用于通过电解电解产生氟气的氟气发生器，其包括含氟化氢的混合熔盐，其中发电机即使在电解池中的电解停止期间电解槽液面的电解液液表面的位置也能够被安全地控制 。 发电机包括通过分隔壁彼此分离的阳极室和阴极室，并且设置有电解液液位控制装置，用于在氟的悬浮期间控制阳极室和阴极室中的至少一个中的电解液液位 天然气生成。

公开(公告)号：US07288180B2

公开(公告)日：2007-10-30

申请号：US10849174

申请日：2004-05-20

申请人： Tetsuro Tojo ,  Jiro Hiraiwa ,  Osamu Yoshimoto

发明人： Tetsuro Tojo ,  Jiro Hiraiwa ,  Osamu Yoshimoto

IPC分类号： C25C3/20

CPC分类号： C25B15/02 ,  C25B1/245

摘要： The invention provides a method and apparatus for current control in gas generators capable of generating a fluorine or fluoride gas by and in which the electrolysis can be maintained in an optimum condition, stable operation is possible and no manpower is demanded. According to the method of current control in gas generators for generating a fluorine or fluoride gas by electrolysis of an electrolytic bath 5 comprising a hydrogen fluoride-containing mixed molten salt using a carbon electrode as the anode 4a, the range of voltage fluctuation between the cathode 4b and anode 4a as occurring when a certain current is applied to the gas generator is measured, and current application is continued while varying the current amount to be applied according to the voltage fluctuation range.

摘要翻译： 本发明提供了一种用于气体发生器中的电流控制的方法和装置，其能够产生氟或氟化物气体，其中电解可以保持在最佳状态，稳定的操作是可能的，并且不需要人力。 根据使用碳电极作为阳极4a的包含含氟化氢的混合熔融盐的电解槽5产生氟或氟化物气体的气体发生器的电流控制方法， 测量向气体发生器施加一定电流时发生的阴极4b和阳极4a，并且根据电压波动范围改变要施加的电流量，继续施加电流。

公开(公告)号：US20060219570A1

公开(公告)日：2006-10-05

申请号：US11374080

申请日：2006-03-14

申请人： Tsuneto Furuta ,  Masaharu Uno ,  Yoshinori Nishiki ,  Tetsuro Tojo ,  Hitoshi Takebayashi ,  Masashi Kodama

发明人： Tsuneto Furuta ,  Masaharu Uno ,  Yoshinori Nishiki ,  Tetsuro Tojo ,  Hitoshi Takebayashi ,  Masashi Kodama

IPC分类号： C25B1/24 ,  C25C7/02

CPC分类号： C25B11/0442 ,  C25B1/245 ,  C25B11/12

摘要： The present invention provides an electrolytic anode for use in electrolytically synthesizing a fluorine-containing substance by using an electrolytic bath containing a fluoride ion including: an electroconductive substrate having a sure including an electroconductive carbonaceous material; and an electroconductive carbonaceous film having a diamond structure, the electroconductive carbonaceous film coating a part of the electroconductive carbonaceous substrate, and a method for electrolytically synthesizing a fluorine-containing substance using the electrolytic anode.

摘要翻译： 本发明提供了一种电解阳极，用于通过使用含有氟离子的电解槽电解合成含氟物质，所述电解液包括：具有包括导电性碳质材料的导电性基材; 和具有金刚石结构的导电性碳膜，导电性碳膜涂覆导电性碳质基材的一部分，以及使用电解阳极电解合成含氟物质的方法。

公开(公告)号：US20050006248A1

公开(公告)日：2005-01-13

申请号：US10497158

申请日：2002-12-09

申请人： Tetsuro Tojo ,  Jiro Hiraiwa ,  Hitoshi Takebayashi ,  Yoshitomi Tada

发明人： Tetsuro Tojo ,  Jiro Hiraiwa ,  Hitoshi Takebayashi ,  Yoshitomi Tada

IPC分类号： C25B1/24 ,  C25B15/00

CPC分类号： C25B1/245 ,  C25B15/00

摘要： An F2 gas generating apparatus for generating a high purity F2 gas by subjecting an electrolytic bath made of KF.2HF to electrolysis is characterized by comprising a preparing system for preparing KF.2HF from KF or KF.HF, an HF supplying system for supplying HF into the electrolytic bath and the preparing system, and an F2 gas generating system for generating the F2 gas by subjecting KF.2HF prepared by the preparing system to electrolysis.

摘要翻译： 通过使由KF.2HF制成的电解浴进行电解而生成高纯度F2气体的F2气体发生装置的特征在于包括用于从KF或KF.HF制备KF.2HF的制备系统，用于提供HF的HF供应系统 进入电解槽和制备系统，以及通过使由制备系统制备的KF.2HF电解产生F2气体的F2气体发生系统。

公开(公告)号：US20040253447A1

公开(公告)日：2004-12-16

申请号：US10849846

申请日：2004-05-21

申请人： Toyo Tanso Co., Ltd.

发明人： Hiroaki Ogura ,  Junji Toyota ,  Hiroshi Hayakawa ,  Hidehiko Nozaki

IPC分类号： B32B009/00

CPC分类号： C04B41/009 ,  B30B11/001 ,  C04B38/00 ,  C04B41/4823 ,  C04B41/5001 ,  C04B41/5059 ,  C04B41/5064 ,  C04B41/51 ,  C04B41/83 ,  C04B41/85 ,  C04B41/87 ,  C04B41/88 ,  Y10T428/30 ,  C04B35/52 ,  C04B38/0054 ,  C04B35/528

摘要： Long carbonaceous moldings and long carbonaceous products as well as methods of production thereof by which carbonaceous products can be obtained without allowing twisting or curving and with less frequent occurrence of cracking etc. even when subjecting the heat treatment and which are excellent in mass productivity are provided. The long carbonaceous moldings have an aspect ratio of 3 to 20 and showing fluctuations in the density thereof of not more than 0.05 Mg/m3 throughout the whole moldings.

摘要翻译： 提供长碳质成型体和长碳质物，以及即使在经受热处理并且具有优异的批量生产率的情况下，也可以提供可以获得碳质产物而不允许扭曲或弯曲并且发生较少裂纹的生产方法 。 该长碳质成型体的纵横比为3〜20，在整个模制品中，其密度波动不大于0.05Mg / m 3。

公开(公告)号：US20040057893A1

公开(公告)日：2004-03-25

申请号：US10251964

申请日：2002-09-23

申请人： TOYO TANSO CO., LTD.

发明人： Hiroshi Okubo ,  Toshiaki Sogabe ,  Tetsuro Tojo ,  Kyoko Noro ,  Hisanori Shinohara

IPC分类号： C01B031/30

CPC分类号： B82Y30/00 ,  B82Y40/00 ,  C01B32/15 ,  C01B32/152

摘要： A carbon material for producing endohedral metallofullerenes in a high yield is made of a mixture of a metal or metal compound with a carbonaceous material and is used in producing a endohedral metallofullerenes, wherein said carbon material contains a metal carbide and a bulk density of said carbon material is set to 1.80 g/cm3 or less.

摘要翻译： 用于以高产率生产内嵌金属富勒烯的碳材料由金属或金属化合物与碳质材料的混合物制成，并用于生产内嵌金属富勒烯，其中所述碳材料包含金属碳化物和所述碳的堆积密度 材料设定为1.80g / cm 3以下。

公开(公告)号：US20040055874A1

公开(公告)日：2004-03-25

申请号：US10661638

申请日：2003-09-15

申请人： Toyo Tanso Co., Ltd.

发明人： Jiro Hiraiwa ,  Osamu Yoshimoto ,  Tetsuro Tojo

IPC分类号： C25B001/24

CPC分类号： C25B15/00 ,  C25B1/245 ,  C25B9/00

摘要： A fluorine gas generator is provided with which the gases used and/or generated, in case of leakage thereof, can be prevented from mixing together as far as possible and, even in case of gas leakage into the outside of the generator system, the leakage gas can be treated safely and in which the maintenance, exchange and other operations are easy to carry out. The generator comprises a box-shaped body containing an electrolyzer for fluorine gas generation, and the box-shaped body is divided into two or more compartments, including a compartment containing the electrolyzer.

摘要翻译： 提供氟气发生器，可以防止在其泄漏的情况下使用和/或产生的气体尽可能地混合在一起，并且即使在气体泄漏到发电机系统的外部的情况下，泄漏 气体可以安全处理，维护，交换和其他操作容易进行。 发电机包括一个包含用于产生氟气的电解器的盒形体，并且盒形主体被分成两个或更多个隔间，包括一个包含电解槽的隔间。