摘要:
Paraffinic hydrocarbons of 2 to 16 carbon atoms are converted to aromatic in the presence of oxygen and a zeolite catalyst incorporating oxidative dehydrogenative metal or metal oxide components
摘要:
Cracking catalysts or catalyst supports prepared from mixtures comprising colloidal alumina, colloidal silica, a particulate weighting agent, and/or an active catalytic component possess excellent catalytic and physical properties. The catalysts in accordance with the invention also show excellent resistance to metal poisoning, and are also highly useful in non-cracking and/or hydroconversion processes.
摘要:
A method is disclosed for the conversion of synthesis gas to a liquid hydrocarbon product having a boiling range of less than 400.degree. F. at a 90% overhead utilizing a novel catalyst prepared from finely divided iron powder or iron oxide. The novel method involves contacting synthesis gas with a single particle catalyst containing iron, a crystalline acidic aluminosilicate zeolite having a silica-to-alumina ratio of at least 12, a pore size greater than about 5 Angstrom units, and a constraint index of about 1 to 12, and a matrix. The catalyst does not contain promoters.
摘要:
Isomerization of xylenes admixed with other alkyl aromatics of at least eight carbon atoms and with normal or slightly branched paraffins is conducted at 800.degree.-1000.degree. F. with a zeolite like zeolite ZSM-5 of reduced acid activity.
摘要:
Amorphous (e.g., silica-alumina) and/or crystalline (e.g. aluminosilicate zeolite) cracking catalysts having improved resistance to metal poisoning are provided when colloidal dispersions, such as silica and/or alumina are added thereto.
摘要:
A metal combustion promoter is introduced to the circulating inventory of catalyst in a catalytic cracking unit as a mixture of particles rich in metal with particles free of metal such that the net concentration of metal in the mixture is about 1 to 10 ppm. According to a preferred embodiment the particles rich in metal contain about 50 ppm pf platinum, iridium, osmium, palladium, rhodium, ruthenium or rhenium. When such mixtures are supplied to the circulating inventory, it is found that specific activity of the metal is enhanced in the sense that activity of the mixture for oxidation of carbon monoxide is higher than that of catalyst in which an equal amount of metal is evenly distributed among all the particles.