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    Use of copolymers based on vinyl monomers and carboxylic acid amides as a detergent additive
    81.
    发明授权
    Use of copolymers based on vinyl monomers and carboxylic acid amides as a detergent additive 失效
    使用基于乙烯基单体和羧酸酰胺的共聚物作为洗涤剂添加剂

    公开(公告)号：US5542951A

    公开(公告)日：1996-08-06

    申请号：US195861

    申请日：1994-02-10

    Applicant: Werner Antwerpen ,  Hermann Schindler ,  Gerd Reinhardt

    Inventor： Werner Antwerpen ,  Hermann Schindler ,  Gerd Reinhardt

    IPC: C11D3/00 ,  C11D3/37 ,  B08B3/08 ,  C11D3/32 ,  C11D17/06

    CPC classification number: C11D3/3769 ,  C11D3/0021 ,  C11D3/3773

    Abstract: Use of copolymers based on vinyl monomers and carboxylic acid amides as a detergent additiveThe present invention relates to the use of copolymers comprising75-95% by weight of the total amount of the monomer of at least one vinyl monomer which is free from carboxyl and amide groups,5-20% by weight of at least one carboxylic acid amide of the formula (I) ##STR1## in which R is a hydrogen atom or a methylol radical,R.sup.1 is a hydrogen atom or a C.sub.1 -C.sub.3 -alkyl radical andR.sup.2 is a hydrogen atom or a methyl radicaland if appropriate together with not more than 5% by weight of a copolymerizable unsaturated carboxylic acid, as a detergent additive for preventing the reabsorption of detached dyestuffs and dyestuff degradation products.

    Abstract translation: 使用基于乙烯基单体和羧酸酰胺的共聚物作为洗涤剂添加剂本发明涉及包含75-95重量％的至少一种不含羧基的乙烯基单体的单体总量的共聚物的用途，以及 酰胺基团，5-20重量％的式（I）的至少一种羧酸酰胺其中R是氢原子或羟甲基，R1是氢原子或C1-C3-烷基 R2为氢原子或甲基，如果合适的话，不大于5重量％的可共聚的不饱和羧酸作为用于防止分离的染料和染料降解产物再吸收的洗涤剂添加剂。

    Aqueous suspensions of peroxycarboxylic acids
    83.
    发明授权
    Aqueous suspensions of peroxycarboxylic acids 失效
    过氧羧酸的水悬浮液

    公开(公告)号：US5391324A

    公开(公告)日：1995-02-21

    申请号：US829740

    申请日：1992-01-31

    Applicant: Gerd Reinhardt ,  Vera Friderichs ,  Ulrike Rudolf

    Inventor： Gerd Reinhardt ,  Vera Friderichs ,  Ulrike Rudolf

    IPC: C11D1/72 ,  C11D1/825 ,  C11D3/39 ,  C11D3/395 ,  C11D17/08 ,  D06L3/00 ,  D06L3/02 ,  C11D3/33 ,  C11D1/722

    CPC classification number: C11D1/8255 ,  C11D3/3947 ,  C11D1/72

    Abstract: Storage-stable aqueous suspensions of organic peracids containing 1 to 50% by weight of a surfactant mixture composed of 1 to 4 parts by weight of a C.sub.8 -C.sub.22 -fatty alcohol, ethoxylated with 1 to 5 units of ethylene oxide, and 4 to 1 parts by weight of a C.sub.8 -C.sub.22 -fatty alcohol, ethoxylated with 6 to 25 units of ethylene oxide, and, if appropriate, additionally other customary components.By using two different surfactants, it is possible to set very different viscosity values in these suspensions, from low viscosity to pasty formulations.

    Abstract translation: 含有1至50重量％表面活性剂混合物的有机过酸的储存稳定水性悬浮液，其由1至4重量份的由1至5个单位的环氧乙烷乙氧基化的C 8 -C 22脂肪醇和4至1个 重量的C 6 -C 22脂肪醇，用6至25单位的环氧乙烷乙氧基化，以及如果合适的话另外还有其它常规组分。 通过使用两种不同的表面活性剂，可以在这些悬浮液中从低粘度到糊状配方设定非常不同的粘度值。

    Stable peroxycarboxylic acid granules
    84.
    发明授权
    Stable peroxycarboxylic acid granules 失效
    稳定的过氧羧酸乳液颗粒

    公开(公告)号：US5246620A

    公开(公告)日：1993-09-21

    申请号：US687236

    申请日：1991-04-18

    Applicant: Hanspeter Gethoffer ,  Gerd Reinhardt ,  Gerhard Noltner ,  Christoph Porz

    Inventor： Hanspeter Gethoffer ,  Gerd Reinhardt ,  Gerhard Noltner ,  Christoph Porz

    IPC: A01N37/22 ,  A01N43/40 ,  A01N43/46 ,  C11D3/37 ,  C11D3/39 ,  C11D3/395 ,  C11D7/54

    CPC classification number: C11D3/3784 ,  C11D3/3761 ,  C11D3/3945

    Abstract: Stable peroxycarboxylic acid granules, consisting essentially of (1) an imidoperoxycarboxylic acid or a salt thereof of the formula ##STR1## wherein A is a group of the formulae ##STR2## n is the number 0, 1 or 2, R.sup.1 is hydrogen, chlorine, bromine, C.sub.1 -C.sub.20 -alkyl, C.sub.1 -C.sub.20 -alkenyl, aryl or alkylaryl,R.sup.2 is hydrogen, chlorine, bromine or a group of the formula --SO.sub.3 M, --CO.sub.2 M or --OSO.sub.3 M,M is hydrogen, an alkali metal or ammonium ion or one equivalent of an alkaline earth metal ion andX is C.sub.1 -C.sub.19 -alkylene or arylene, and(2) an inorganic sulfate and/or phosphate salt and/or a nonoxidizable surfactant as granulation auxiliary and a copolymer based on alkenylaminomethylenephosphonic acids as a film-forming coating substance.

    Abstract translation: 稳定的过氧羧酸颗粒，其主要由（1）式（I）所示的亚氨基过氧羧酸或其盐组成，其中A是下式的基团：n是数字0,1或2 ，R1是氢，氯，溴，C1-C20-烷基，C1-C20-烯基，芳基或烷基芳基，R2是氢，氯，溴或式-SO3M，-CO2M或-OSO3M的基团，M是氢 ，碱金属或铵离子或一当量碱土金属离子，X为C 1 -C 19 - 亚烷基或亚芳基，（2）无机硫酸盐和/或磷酸盐和/或不可氧化的表面活性剂作为造粒助剂和 基于链烯基氨基亚甲基膦酸的共聚物作为成膜涂层物质。

    Process for the preparation of ureidoperoxycarboxylic acids
    85.
    发明授权
    Process for the preparation of ureidoperoxycarboxylic acids 失效
    制备尿嘧啶羧酸的方法

    公开(公告)号：US5235099A

    公开(公告)日：1993-08-10

    申请号：US793815

    申请日：1991-11-18

    Applicant: Wolf-Dieter Muller ,  Frank Jaekel ,  Peter Naumann ,  Gerd Reinhardt

    Inventor： Wolf-Dieter Muller ,  Frank Jaekel ,  Peter Naumann ,  Gerd Reinhardt

    IPC: B01J27/02 ,  A01N47/28 ,  A01N47/30 ,  A01N47/32 ,  B01J31/02 ,  B01J31/08 ,  C07B61/00 ,  C07C407/00 ,  C07C409/40 ,  C11D3/39

    CPC classification number: A01N47/28 ,  A01N47/30 ,  A01N47/32 ,  C07C407/00 ,  C11D3/3945 ,  C07C2101/14

    Abstract: A process for the preparation of ureidoperoxycarboxylic acids of the formula ##STR1## in which x is the number 1 or 2,A,if x is 1,is hydrogen, C.sub.1 -C.sub.20 -alkyl, aryl, preferably phenyl, or haloaryl, preferably chlorophenyl, orif x is 2,is C.sub.1 -C.sub.20 -alkylene or arylene, preferably phenylene,B is a group of the formula ##STR2## in which n is a number from 1 to 20,m is the number 0, 1 or 2,R.sup.1 is C.sub.1 -C.sub.20 -alkyl andR.sup.2 is in each case hydrogen or C.sub.1 -C.sub.20 -alkyl, which comprises dissolving carbamoyllactams of the formula ##STR3## in which x, A and B have the abovementioned meanings, in a one- to six-fold, preferably a one- to three-fold, amount by weight of a strong catalyst acid, by then adding water in a one- to ten-fold molar excess, relative to the carbamoyllactam, to the solution of the carbamoyllactam in the catalyst acid and by heating the reaction mixture to form the ureidocarboxylic acid, by then adding to the reaction mixture an aqueous hydrogen peroxide solution in a one- to ten-fold, preferably a two- to four fold, molar excess per oxidizable carboxyl group of the ureidocarboxylic acid formed in the preceding reaction step, and by then precipitating the resulting ureidoperoxycarboxylic acid from the reaction mixture.These compounds are suitable as bleaches, oxidants and disinfectants.

    Abstract translation: 制备式A [NHCONHBCOOOH] x的脲基过氧羧酸的方法，其中x为数1或2，如果x为1，则为A，为C 1 -C 20烷基，芳基，优选苯基或卤代芳基 ，优选氯苯基，或如果x为2，则为C 1 -C 20亚烷基或亚芳基，优选亚苯基，B为下式的基团：其中n为1至20的数，m为数 0,1或2，R 1是C 1 -C 20烷基，R 2在各自的情况下是氢或C 1 -C 20 - 烷基，其包括将式（ⅩⅧ）的氨基甲酰基内酰胺溶解在其中x，A和B具有上述含义， 以强的催化剂酸的重量比为1至6倍，优选1至3倍，然后将相对于氨基甲酰基内酰胺的1至10倍摩尔过量的水加入到 催化剂中的氨基甲酰基内酰胺，并加热反应混合物形成脲基羧酸，然后向反应混合物中加入过氧化氢水溶液 在上述反应步骤中形成的脲基羧酸的每个可氧化羧基的摩尔过量为十倍，优选为二至四倍，然后从反应混合物中沉淀所得的脲基过氧羧酸。 这些化合物适合作为漂白剂，氧化剂和消毒剂。

    Use of triacylated ethanolamines as liquid, water-miscible peroxide activators
    87.
    发明授权
    Use of triacylated ethanolamines as liquid, water-miscible peroxide activators 失效
    使用三酰化乙醇胺作为液体，水混溶性过氧化物活化剂

    公开(公告)号：US5045222A

    公开(公告)日：1991-09-03

    申请号：US449990

    申请日：1989-12-13

    Applicant: Hajime Endo ,  Hanspeter Gethoffer ,  Fritz-Feo Grabley ,  Gerd Reinhardt

    Inventor： Hajime Endo ,  Hanspeter Gethoffer ,  Fritz-Feo Grabley ,  Gerd Reinhardt

    IPC: C11D3/395 ,  C11D3/39 ,  C11D7/32 ,  C11D7/54 ,  D06L3/02

    CPC classification number: C11D3/3917

    Abstract: Use of triacylated ethanolamines as liquid, water-miscible peroxide activatorsTriacylated ethanolamines of the formula(RCO)(R.sub.1 CO)N-(CH.sub.2).sub.2 -OCOR.sub.2where R, R.sub.1 and R.sub.2, which may be identical to or different from one another, are each alkyl, alkenyl or aryl, and the total number of carbon atoms in the molecule is from 8 to 14, are liquid and readily water-miscible. Owing to these properties, they are very useful as peroxide activators in liquid detergent compositions.

    Abstract translation: 使用三酰化乙醇胺作为液体，水混溶性过氧化物活化剂式（RCO）（R1CO）N-（CH2）2-OCOR2的三酰化乙醇胺其中R，R 1和R 2可以彼此相同或不同， 每个烷基，烯基或芳基，并且分子中的总碳原子数为8至14，是液体且容易与水混溶。 由于这些性质，它们作为液体洗涤剂组合物中的过氧化物活化剂是非常有用的。

    Derivatives, having an inhibitory action against protease and an antiphlogistic action, of the trypsin-kallikrein inhibitor obtained from cattle organs (BPTI), their preparation and their use as medicaments
    88.
    发明授权
    Derivatives, having an inhibitory action against protease and an antiphlogistic action, of the trypsin-kallikrein inhibitor obtained from cattle organs (BPTI), their preparation and their use as medicaments 失效
    从牛器官（BPTI）获得的胰蛋白酶激肽释放酶抑制剂对蛋白酶和消炎作用具有抑制作用的衍生物，其制备及其作为药物的用途

    公开(公告)号：US4153687A

    公开(公告)日：1979-05-08

    申请号：US847886

    申请日：1977-11-02

    Applicant: Eugen Schnabel ,  Gerd Reinhardt ,  Horst D. Schlumberger ,  Ernst Truscheit ,  Harold Tschesche

    Inventor： Eugen Schnabel ,  Gerd Reinhardt ,  Horst D. Schlumberger ,  Ernst Truscheit ,  Harold Tschesche

    IPC: C07G99/00 ,  A61K38/00 ,  A61K38/55 ,  A61P29/00 ,  A61P37/00 ,  C07K14/81 ,  A61K37/00 ,  C07C103/52

    CPC classification number: C07K14/8117 ,  A61K38/00

    Abstract: The invention provides derivatives of kallikrein-trypsin inhibitor (BPTI) in which one or both of the 10- or 21-tyrosine residues are linked, in the o-position relative to the phenolic hydroxyl group, to an aptionally substituted carbocyclic or heterocyclic aromatic radical via an azo group and the other if only one of the said residues is substituted is either unsubstituted or carries a nitro group or an amino group in the o-position relative to the phenolic hydroxyl group.The azo-BPTI derivatives of the invention can be used, as medicaments for the therapy of diseases which are caused either by over-production of proteases as a result of increased liberation from the zymogens or of release during cell decomposition or by a deficiency or lack of natural indogenous inhibitors of these enzymes in organs and tissue fluids. Diseases which have this type of etiology are the various forms of shock and post-traumatic or post-operative complications, disorders in blood clotting and acute and chronic inflammatory reactions and, in particular, also chronic inflammatory reactions with necrotic and degenerative damage to connective tissue, such as pancreatitis and also vasculitides, glomerulonephritides, rheumatoid arthritis and other collagenoses caused by immune complexes and also arthritides caused by deposits due to metabolic processes (gout), but also degenerative changes in the elastic elements of vascular walls (arterioscleroses) or in the lung (pulmonary emphysema).

    Abstract translation: 本发明提供激肽释放酶 - 胰蛋白酶抑制剂（BPTI）的衍生物，其中10位或21位酪氨酸残基中的一个或两者在相对于酚羟基的o位置连接到易位的碳环或杂环芳族基团 如果只有一个所述残基被取代，则通过偶氮基团和另一个是未取代的或在相对于酚羟基的o位置携带硝基或氨基。

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