公开(公告)号：US4803148A

公开(公告)日：1989-02-07

申请号：US59991

申请日：1987-06-09

申请人： Toru Harada ,  Kozo Sato

发明人： Toru Harada ,  Kozo Sato

IPC分类号： G03F7/004 ,  G03C1/00 ,  G03C1/498 ,  G03F7/028 ,  G03F7/06 ,  G03F7/105 ,  G03C5/54 ,  G03C1/68

CPC分类号： G03F7/0285 ,  G03F7/105

摘要： A light-sensitive material comprising a light-sensitive layer containing silver halide, a reducing agent, a polymerizable compound and a leuco dye provided on a support, characterized in that the leuco dye is a compound having the following formula (I): ##STR1## in which A is --O-- or ##STR2## and R is a substituent having a positive substituent constant (.sigma.); one of X and Y is nitrogen and the other is carbon; each of R.sup.1 and R.sup.2 is an alkyl group, a cycloalkyl group or an aralkyl group; each of R.sup.3 and R.sup.4 is an alkyl group, an alkoxy group, a cycloalkyl group, an aralkyl group or an aryloxy group; each of l, m and n is 1 or 2.

摘要翻译： 一种感光材料，其包含含有卤化银，还原剂，可聚合化合物和设置在载体上的无色染料的感光层，其特征在于所述无色染料是具有下式（I）的化合物：（I）其中A是-O-或，R是具有正取代基常数（sigma）的取代基; X和Y之一是氮，另一个是碳; R1和R2各自为烷基，环烷基或芳烷基; R 3和R 4各自为烷基，烷氧基，环烷基，芳烷基或芳氧基; l，m和n分别为1或2。

公开(公告)号：US4761360A

公开(公告)日：1988-08-02

申请号：US18365

申请日：1987-02-24

申请人： Kozo Sato ,  Soichiro Yamamoto

发明人： Kozo Sato ,  Soichiro Yamamoto

IPC分类号： G03F7/004 ,  G03C1/498 ,  G03F7/028 ,  G03C1/72

CPC分类号： G03F7/0285 ,  Y10S430/114 ,  Y10S430/12 ,  Y10S430/121 ,  Y10S430/16

摘要： A light-sensitive material comprising a light-sensitive layer which contains silver halide, a reducing agent and a polymerizable compound provided on a support, characterized in that the light-sensitive layer further contains a silver diazotate having the following formula:Ar--N.dbd.N--O--Ag(L).sub.nin which Ar is an aryl group or a heterocyclic group, each of which may have one or more substituent groups; L is a ligand; and n is 0, 1 or 2. Image-forming methods utilizing the light-sensitive materials are also disclosed.

摘要翻译： 一种感光材料，其包含含有卤化银，还原剂和设置在载体上的可聚合化合物的感光层，其特征在于，所述感光层还含有下式的重铬酸银：Ar-N = NO-Ag（L）n，其中Ar是芳基或杂环基，其各自可以具有一个或多个取代基; L是配体; 并且n是0,1或2.还公开了利用感光材料的图像形成方法。

公开(公告)号：US4675277A

公开(公告)日：1987-06-23

申请号：US780132

申请日：1985-09-25

申请人： Kozo Sato ,  Hiroshi Kitaguchi ,  Hiroyuki Hirai

发明人： Kozo Sato ,  Hiroshi Kitaguchi ,  Hiroyuki Hirai

IPC分类号： G03C8/40 ,  G03C1/34 ,  G03C1/498 ,  G03C7/00 ,  G03C1/06

CPC分类号： G03C1/49845 ,  Y10S430/156

摘要： A heat developable light-sensitive material comprising a support having provided thereon at least a light-sensitive silver halide, a binder, and a compound capable of ring-closure to produce a benzimidazole ring upon heat development can be developed to an increased maximum density with less fogging at a relatively low temperature in a short period of time.

摘要翻译： 包含其上提供有至少一种感光卤化银，粘合剂和能够闭合以在热显影时产生苯并咪唑环的化合物的支持体的可热显影的感光材料可以发展成具有增加的最大密度， 在较短的时间内在相对较低的温度下减少雾化。

公开(公告)号：US4657848A

公开(公告)日：1987-04-14

申请号：US782811

申请日：1985-10-02

申请人： Kozo Sato ,  Yoshiharu Yabuki ,  Hiroyuki Hirai ,  Ken Kawata

发明人： Kozo Sato ,  Yoshiharu Yabuki ,  Hiroyuki Hirai ,  Ken Kawata

IPC分类号： G03C1/06 ,  G03C1/498 ,  G03C7/00 ,  G03C8/40 ,  G03C1/02

CPC分类号： G03C1/49845 ,  G03C8/4086 ,  Y10S430/156

摘要： A heat-developable light-sensitive material is described, containing a compound represented by formula (I) ##STR1## wherein R.sub.1 represents a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted alkynyl group, a substituted or unsubstituted aralkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted heterocyclic group, a substituted or unsubstituted alkylene group, a substituted or unsubstituted cycloalkylene group, a substituted or unsubstituted alkenylene group, a substituted or unsubstituted alkynylene group, a substituted or unsubstituted aralkylene group, a substituted or unsubstituted arylene group, or a substituted or unsubstituted divalent heterocyclic group; R.sub.2 represents a hydrogen atom, a substituted or unsubstituted alkyl group; R.sub.3 represents an alkyl group, an alkoxyl group, a halogen atom, an acylamino group, a sulfonylamino group, an alkylamino group, a dialkylamino group, an alkylsulfonyl group, an arylsulfonyl group, a cyano group, a substituted or unsubstituted carbamoyl group, a substituted or unsubstituted sulfamoyl group or an alkoxycarbonyl group; X represents a divalent group selected from ##STR2## (wherein R.sub.4 represents a hydrogen atom, a substituted or unsubstituted alkyl group), ##STR3## (wherein R.sub.5 represents a substituted or unsubstituted alkyl group), and ##STR4## M represents an alkali metal, an alkaline earth metal, a quaternary ammonium group, or an ammonium group represented by BH (wherein B represents an organic base); l is an integer of 0 to 3; and m and n are each an integer of 1 or 2, such that the electric charge of carboxylate anion is equivalent to that of M.This material is improved in activity and storage stability. That is, the material providing an image of high density and decreased fog, and which even when stored under high temperature/high humidity conditions, maintained good photographic performance.

公开(公告)号：US4650749A

公开(公告)日：1987-03-17

申请号：US769274

申请日：1985-08-26

申请人： Kozo Sato ,  Yoshiharu Yabuki ,  Hiroyuki Hirai ,  Ken Kawata

发明人： Kozo Sato ,  Yoshiharu Yabuki ,  Hiroyuki Hirai ,  Ken Kawata

IPC分类号： G03C8/40 ,  B41M5/26 ,  C07C51/00 ,  C07C59/58 ,  C07C59/64 ,  C07C59/66 ,  C07C67/00 ,  C07C239/00 ,  C07C279/02 ,  C07C301/00 ,  C07C311/03 ,  C07D207/22 ,  C07D231/12 ,  C07D231/56 ,  C07D233/60 ,  C07D235/06 ,  C07D235/22 ,  C07D249/18 ,  C07D257/04 ,  C07D317/30 ,  C07D317/46 ,  C07D521/00 ,  G03C1/06 ,  G03C1/498 ,  G03C7/00 ,  G03C1/02

CPC分类号： G03C1/49845 ,  Y10S430/156

摘要： A heat developable light-sensitive material containing a compound represented by formula (I) or (II) ##STR1## wherein R.sub.1 and R.sub.2 each represents a hydrogen atom, an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aralkyl group, an aryl group, a heterocyclic group, a carboxyl group or a salt thereof, a halogen atom, a cyano group, an alkylsulfonyl or arylsulfonyl group, a sulfamoyl group, a carbamoyl group, an alkoxycarbonyl or aryloxycarbonyl group, a di- or mono-alkylphosphoryl or arylphosphoryl group, a di- or mono-alkylphosphinyl or arylphosphinyl group, an alkylsulfinyl or arylsulfinyl group, an acyl group, an amino group, an acylamino group, an acyloxy group or a group represented by X; X represents a decarboxylation accelerating group; or any two of R.sub.1, R.sub.2, and X may combine to form a ring; and the groups represented by R.sub.1, R.sub.2 and X may further be substituted with a substituent; B represents an organic base; and n represents 1 when B represents a monoacid base or 2 when B represents a diacid base, provided that when ##STR2## is a free dibasic acid, n is 1/2 of the above described numbers, respectively.The heat developable light-sensitive material containing a base precursor represented by formula (I) or (II) has excellent stability during preservation before use, and provides a color image having a high color density and low fog in a short time.

摘要翻译： 含有式（I）或（II）表示的化合物的热显影性感光材料其中R 1和R 2各自表示氢原子，烷基，环烷基， 烯基，炔基，芳烷基，芳基，杂环基，羧基或其盐，卤素原子，氰基，烷基磺酰基或芳基磺酰基，氨磺酰基，氨基甲酰基， 烷氧基羰基或芳氧基羰基，二 - 或单烷基磷酰基或芳基磷酰基，二 - 或单烷基氧膦基或芳基氧膦基，烷基亚磺酰基或芳基亚磺酰基，酰基，氨基，酰氨基，酰氧基或 由X代表的组; X表示脱羧加成基团; 或者R1，R2和X中的任何两个可以结合形成环; 并且由R 1，R 2和X表示的基团可以进一步被取代基取代; B表示有机碱; 当B代表一酸基时，n表示1，B表示二酸基时，n表示1，条件是当为游离二元酸时，n分别为上述数字的1/2。 含有由式（I）或（II）表示的碱前体的可热显影的感光材料在使用前的保存期间具有优异的稳定性，并且在短时间内提供具有高着色密度和低雾度的彩色图像。

公开(公告)号：US4640892A

公开(公告)日：1987-02-03

申请号：US769275

申请日：1985-08-26

申请人： Ken Kawata ,  Yoshiharu Yabuki ,  Kozo Sato ,  Hiroyuki Hirai

发明人： Ken Kawata ,  Yoshiharu Yabuki ,  Kozo Sato ,  Hiroyuki Hirai

IPC分类号： G03C1/06 ,  G03C1/498 ,  G03C7/00 ,  G03C8/40 ,  G03C1/02

CPC分类号： G03C1/49845 ,  G03C8/4086 ,  Y10S430/156

摘要： A heat-developable color photographic light-sensitive material comprises a support having thereon at least one layer containing the novel base precursor. This heat-developable color photographic light-sensitive material provides a high maximum density and low fog by heat-developing at a relatively low temperature and for a short period of time.

摘要翻译： 可热显影的彩色照相感光材料包括其上具有至少一层含有新型碱性前体的层的载体。 该可热成像的彩色照相感光材料通过在相对低的温度下和短时间内的热显影提供高的最大密度和低的雾度。

公开(公告)号：US4640891A

公开(公告)日：1987-02-03

申请号：US768655

申请日：1985-08-23

申请人： Yoshiharu Yabuki ,  Kozo Sato ,  Ken Kawata ,  Hiroyuki Hirai

发明人： Yoshiharu Yabuki ,  Kozo Sato ,  Ken Kawata ,  Hiroyuki Hirai

IPC分类号： G03C1/06 ,  G03C1/498 ,  G03C7/00 ,  G03C8/40 ,  G03C5/24

CPC分类号： G03C8/4086 ,  G03C1/49845 ,  G03C8/4033 ,  Y10S430/156

摘要： A heat developable light-sensitive material having an excellent stability with time and capable of providing a high quality image is disclosed, which contains a base precursor represented by the following general formula (I): ##STR1## wherein A represents an organic residue represented by the following formula (II): ##STR2## X represents an electron attractive substituent having a Hammett's sigma value of more than 0;l represents an integer of 1 to 5 and, when l represents 2 or more, a plurality of Xs may be the same or different;Y represents a substituent having a Hammett's sigma value of 0 or less;k represents an integer of 0 to 5 and, when k represents 2 or more, a plurality of Ys may be the same or different;Z represents a divalent organic residue selected from the group consisting of --C.dbd.C--, --O--, --S--, and --NR-- (wherein R represents a hydrogen atom or a substituent selected from the group consisting of an alkyl group, an alkenyl group, an aralkyl group, an aryl group, and an acyl group);the broken line in the general formula (II) represents that the cyclic compound containing Z may optionally be fused with a benzene ring;B represents a mono- or diacidic base having a pKa value of 7 or more and containing 12 or less carbon atoms; andn and m represent an integer of 1 or 2 and are in such relation that the number of positive charge is equal to that of negative charge.

摘要翻译： 公开了一种具有优异的时间稳定性和能够提供高质量图像的可热显影的感光材料，其包含由以下通式（I）表示的碱前体：其中A表示有机物 由下式（II）表示的残基：X表示哈米特σ值大于0的吸电子取代基; l表示1〜5的整数，当l表示2以上时，多个X可以相同或不同， Y表示哈米特σ值为0以下的取代基; k表示0〜5的整数，当k表示2以上时，多个Y可以相同或不同， Z表示选自-C = C，-O-，-S-和-NR-的二价有机残基（其中R表示氢原子或选自烷基， 烯基，芳烷基，芳基和酰基）; 通式（II）中的虚线表示含有Z的环状化合物可任意地与苯环稠合; B表示pKa值为7以上且含有12个以下碳原子的单或二酸碱基; 并且n和m表示1或2的整数，并且与正电荷的数量等于负电荷的数量相关联。

公开(公告)号：US4629676A

公开(公告)日：1986-12-16

申请号：US775273

申请日：1985-09-12

申请人： Yoshihide Hayakawa ,  Masato Satomura ,  Kozo Sato

发明人： Yoshihide Hayakawa ,  Masato Satomura ,  Kozo Sato

IPC分类号： G03F7/028 ,  G03C1/40 ,  G03C5/54 ,  G03F7/00

CPC分类号： G03F7/0285

摘要： An image forming method is disclosed, comprising forming a latent image by imagewise exposing a recording material including a light-sensitive silver salt, a reducing agent, a polymerizable compound, and a binder, on a support, and subsequently subjecting said recording material to a substantially uniform heating at about 80.degree. C. or more under conditions substantially not containing water, thereby forming a polymeric compound in areas where the latent image of the light-sensitive silver salt has formed.

摘要翻译： 公开了一种图像形成方法，包括通过在载体上将包含感光性银盐，还原剂，可聚合化合物和粘合剂的记录材料成像曝光来形成潜像，然后将所述记录材料 在基本上不含水的条件下在约80℃或更高温度下基本均匀地加热，从而在形成感光性银盐的潜像的区域中形成聚合物。

公开(公告)号：US4499172A

公开(公告)日：1985-02-12

申请号：US595149

申请日：1984-03-30

申请人： Hiroyuki Hirai ,  Kozo Sato

发明人： Hiroyuki Hirai ,  Kozo Sato

IPC分类号： C07C51/377 ,  C07C57/42 ,  C07C57/60 ,  G03C1/498 ,  G03C8/40 ,  G03C1/40 ,  G03C1/06 ,  G03C5/54

CPC分类号： G03C8/4086 ,  C07C51/377 ,  C07C57/42 ,  C07C57/60 ,  G03C1/49845 ,  Y10S430/156

摘要： A heat-developable color light-sensitive material comprising a support having thereon at least a light-sensitive silver halide, a binder, a dye releasing redox compound which is capable of reducing the light-sensitive silver halide and is capable of reacting with the light-sensitive silver halide by heating to release a hydrophilic dye and a salt of an alkylcarboxylic acid having a triple bond between the .alpha.-position carbon atom and the .beta.-position carbon atom with an organic base as a base precursor.The heat-developable color light-sensitive material containing the novel base precursor has good stability during preservation and provides a color image having a high color density and low fog in a short time by a simple procedure. A method of forming a color image using the heat-developable color light-sensitive material is also disclosed.

摘要翻译： 一种可热显色的感光材料，其包括其上具有至少一种感光卤化银，粘合剂，释放染料的氧化还原化合物的载体，其能够还原感光卤化银并且能够与光反应 通过加热以释放亲水染料和在α-位碳原子和β-位碳原子之间具有三键的烷基羧酸的盐与作为基础前体的有机碱。 含有新型碱性前体的可热显色的感光材料在保存期间具有良好的稳定性，并且通过简单的程序在短时间内提供具有高色密度和低雾度的彩色图像。 还公开了使用可热显色的感光材料形成彩色图像的方法。

公开(公告)号：US4390616A

公开(公告)日：1983-06-28

申请号：US212010

申请日：1980-12-01

申请人： Kozo Sato ,  Ken Iwakura ,  Akira Igarashi

发明人： Kozo Sato ,  Ken Iwakura ,  Akira Igarashi

IPC分类号： B41M5/145 ,  B41M5/327 ,  C09B11/24 ,  C09B11/28 ,  G03C1/52

CPC分类号： C09B11/24 ,  B41M5/1455 ,  B41M5/3275 ,  Y10S428/913 ,  Y10S428/914

摘要： Recording members having excellent light resistance are obtained by using as a dye precursor specific diarylaminofluoran compounds.

摘要翻译： 通过使用染料前体特异性二芳基氨基荧烷化合物，可获得耐光性优异的记录材料。