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公开(公告)号:US06830840B1
公开(公告)日:2004-12-14
申请号:US10019975
申请日:2001-10-23
申请人: Kazuhito Hatoh , Osamu Sakai , Hideo Ohara , Junji Niikura , Hisaaki Gyoten , Toshihiro Matsumoto , Teruhisa Kanbara
发明人: Kazuhito Hatoh , Osamu Sakai , Hideo Ohara , Junji Niikura , Hisaaki Gyoten , Toshihiro Matsumoto , Teruhisa Kanbara
IPC分类号: H01M804
CPC分类号: H01M8/04119 , H01M8/04007 , H01M8/04029 , H01M8/04089 , H01M8/04328 , H01M8/04335 , H01M8/04365 , H01M8/04388 , H01M8/04395 , H01M8/045 , H01M8/04507 , H01M8/04589 , H01M8/04708 , H01M8/04716 , H01M8/04723 , H01M8/04753 , H01M8/04768 , H01M8/04835 , H01M8/04843 , H01M8/0491 , H01M8/04992 , H01M8/1007 , H01M2300/0082
摘要: The present invention discloses an operation method for a polymer electrolyte fuel cell in an optimum operating condition by regulating the cell by a function represented by a gas flow rate and the difference between a saturated steam pressure and an actual steam pressure, by regulating an in-plane temperature distribution obtained by a cooling water flow direction and by the regulations of a cooling water inlet temperature and a cooling water flow amount; a gas supply amount; a supplied moisture amount; and a current density.
摘要翻译: 本发明公开了一种通过调节由气体流量和饱和蒸汽压力与实际蒸汽压力之间的差异表示的功能来调节电池的处于最佳工作状态的聚合物电解质燃料电池的操作方法, 通过冷却水流动方向获得的平面温度分布和冷却水入口温度和冷却水流量的规定; 供气量; 供应的水分量; 和电流密度。
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公开(公告)号:US06790552B2
公开(公告)日:2004-09-14
申请号:US10270238
申请日:2002-10-15
申请人: Susumu Kobayashi , Masato Hosaka , Kazuhito Hatoh , Hikaru Murakami , Mikio Takezawa , Takayuki Onishi
发明人: Susumu Kobayashi , Masato Hosaka , Kazuhito Hatoh , Hikaru Murakami , Mikio Takezawa , Takayuki Onishi
IPC分类号: H01M804
CPC分类号: H01M8/0273 , H01M8/0263 , H01M8/0271 , H01M8/0276 , H01M8/1023 , H01M8/1039 , H01M8/242 , H01M8/2465 , H01M8/2483
摘要: A polymer electrolyte fuel cell in which neither cross leakage nor outward leakage occurs with the application of low clamping pressures. The polymer electrolyte fuel cell a membrane electrode assembly (MEA) including a polymer electrolyte membrane, a gasket covering the periphery of the electrolyte membrane, and an anode and cathode attached to the electrolyte membrane; and conductive separator plates sandwiching the MEA therebetween. The gasket has seal ribs surrounding each of the manifold apertures, the anode and the cathode, as well as seal ribs formed on both sides of each of gas passages connecting the fuel gas manifold apertures with the anode and gas passages connecting the oxidant gas manifold apertures with the cathode. These seal ribs, except for in the gas passages, are pressed against the separator plates by clamping pressure of the cell stack to form gas sealing sections.
摘要翻译: 一种聚合物电解质燃料电池,其中施加低的夹紧压力时不会发生交叉泄漏或向外泄漏。 聚合物电解质燃料电池包括聚合物电解质膜,覆盖电解质膜周围的垫圈和附着在电解质膜上的阳极和阴极的膜电极组件(MEA) 以及将MEA夹在其间的导电隔板。 垫圈具有围绕每个歧管孔,阳极和阴极的密封肋,以及形成在每个气体通道的两侧上的密封肋,其将燃料气体歧管孔与连接氧化剂气体歧管孔的阳极和气体通道连接 与阴极。 除了气体通道之外,这些密封肋通过夹住电池堆的压力而压靠隔板,形成气体密封部分。
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公开(公告)号:US06531236B1
公开(公告)日:2003-03-11
申请号:US09497058
申请日:2000-02-02
申请人: Kazuhito Hatoh , Eiichi Yasumoto , Kazufumi Nishida , Hisaaki Gyoten , Teruhisa Kanbara , Hideo Ohara , Makoto Uchida , Yasushi Sugawara , Toshihiro Matsumoto
发明人: Kazuhito Hatoh , Eiichi Yasumoto , Kazufumi Nishida , Hisaaki Gyoten , Teruhisa Kanbara , Hideo Ohara , Makoto Uchida , Yasushi Sugawara , Toshihiro Matsumoto
IPC分类号: H01M802
CPC分类号: H01M8/02 , C08L23/22 , H01M8/0213 , H01M8/0221 , H01M8/0226 , H01M8/0228 , H01M8/0263 , H01M8/0267 , H01M8/0271 , H01M8/04029 , H01M8/04074 , H01M8/04119 , H01M8/241 , H01M8/2483 , H01M2300/0082 , Y02P70/56
摘要: The present invention provides a polymer electrolyte fuel cell stack that includes a cell laminate having a plurality of unit cells, which are laid one upon another and each of which includes a polymer electrolyte membrane, a pair of electrodes that are arranged across the polymer electrolyte membrane and respectively have a catalytic reaction layer, a separator having means for feeding a supply of fuel gas containing hydrogen gas to one of the electrodes, and another separator having means for feeding a supply of oxidant gas to the other of the electrodes. In the polymer electrolyte fuel cell stack, a sealing portion is disposed at least in the vicinity of each electrode. The polymer electrolyte fuel cell stack of the present invention has excellent durability and productivity. Gasket sealing portions, a sealing portion for cooling water, and sealing portions for water and gas in an internal humidifying unit are constituted by a polymer compound that has polyisobutylene as the backbone structure. This arrangement ensures the high reliability.
摘要翻译: 本发明提供了一种聚合物电解质燃料电池堆,其包括具有多个单位电池的电池层叠体,所述电池层叠体彼此叠放并且各自包括聚合物电解质膜,跨所述聚合物电解质膜布置的一对电极 分别具有催化反应层,隔板,其具有将含有氢气的燃料气体供给到其中一个电极的装置,另一个隔板具有用于向另一个电极供给氧化剂气体的装置。 在聚合物电解质型燃料电池堆中,密封部至少设置在各电极附近。 本发明的高分子电解质型燃料电池堆具有优异的耐久性和生产率。 垫片密封部分,冷却水用密封部分和内部加湿单元中的水和气体密封部分由具有聚异丁烯作为骨架结构的高分子化合物构成。 这种安排确保了高可靠性。
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公开(公告)号:US06187464B1
公开(公告)日:2001-02-13
申请号:US09322948
申请日:1999-05-28
IPC分类号: H01M800
CPC分类号: H01M8/1086 , H01M4/926 , H01M8/0273 , H01M8/04119 , H01M8/04223 , H01M8/04291 , H01M8/04302 , H01M8/1004 , H01M8/241 , H01M8/2457 , H01M8/2483 , H01M2300/0082 , Y02P70/56
摘要: A method for activating a polymer electrolyte type fuel cell comprising at least one unit cell which is configured by including a proton conductive polymer electrolyte, an electrode layer having a catalytic activity arranged on the both faces of said polymer electrolyte membrane and a gas-supplying path is disclosed. This method comprises at least one of the step (a) of enhancing the catalytic activity of said electrode and the step (b) of giving a wetting condition to said polymer electrolyte. According to the present invention, it is possible to readily activate the fuel cell and to cause the same to demonstrate a high cell performance.
摘要翻译: 一种激活聚合物电解质型燃料电池的方法,包括至少一个单元电池,该单元电池通过包括质子传导性聚合物电解质,具有排列在所述聚合物电解质膜的两面上的催化活性的电极层和气体供给路径 被披露。 该方法包括增强所述电极的催化活性的步骤(a)和向所述聚合物电解质提供润湿条件的步骤(b)中的至少一个。 根据本发明,可以容易地激活燃料电池并使其能够表现出高的电池性能。
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公开(公告)号:US5288562A
公开(公告)日:1994-02-22
申请号:US820509
申请日:1992-01-14
申请人: Noboru Taniguchi , Junji Niikura , Kazuhito Hatoh , Takaharu Gamo
发明人: Noboru Taniguchi , Junji Niikura , Kazuhito Hatoh , Takaharu Gamo
CPC分类号: H01M8/0247 , H01M8/0232 , H01M8/0258 , H01M8/2425 , H01M2008/1293 , H01M2300/0074 , H01M8/0206 , Y02P70/56
摘要: A solid electrolyte fuel cell having a multi-layer structure of flat unit cells composed of a solid electrolyte, a first electrode and a second electrode with metal bipolar plates as gas barriers and collectors preferably made of foam metal or a foam alloy interposed between the adjacent unit cells. A fuel gas and an oxidizing gas are supplied to the fuel cell so that they flow in the directions crossing each other with the solid electrolyte interposed therebetween. The metal bipolar plate is preferably provided with grooves so that the fuel gas and the oxidizing gas can be uniformly distributed over the plate.
摘要翻译: 一种固体电解质燃料电池,其具有由固体电解质,第一电极和金属双极板作为气体阻挡层的第二电极构成的平坦单元电池的多层结构,并且优选由发泡金属或泡沫合金制成的集电体, 单元格单元格 将燃料气体和氧化气体供给到燃料电池,使得它们以固体电解质插入其间彼此交叉的方向流动。 金属双极板优选地设置有槽,使得燃料气体和氧化气体可以均匀地分布在板上。
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公开(公告)号:US5244753A
公开(公告)日:1993-09-14
申请号:US942373
申请日:1992-09-09
申请人: Noboru Taniguchi , Junji Niikura , Kazuhito Hatoh , Takaharu Gamo
发明人: Noboru Taniguchi , Junji Niikura , Kazuhito Hatoh , Takaharu Gamo
IPC分类号: H01M8/12
CPC分类号: H01M8/1213 , H01M8/1246 , Y02E60/525 , Y02P70/56
摘要: This invention provides a solid electrolyte fuel cell operable with high efficiency even in the temperature range of about 850.degree. to 650.degree. C., The invention is characterized by the use of a novel perovskite double oxide of the composition A.sub.X B.sub.Y O.sub.3-.alpha.. The fabrication of the electrolyte, air electrode and fuel electrode layers by tape casting has contributed to marked improvement in processability and productivity.
摘要翻译: 本发明提供即使在约850℃至650℃的温度范围内也可高效运行的固体电解质燃料电池。本发明的特征在于使用组合物AXBYO3-α的新型钙钛矿双氧化物。 通过带状铸造制造电解质,空气电极和燃料电极层有助于加工性和生产率的显着提高。
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公开(公告)号:US4997729A
公开(公告)日:1991-03-05
申请号:US290189
申请日:1988-12-27
申请人: Kazuhito Hatoh , Junji Niikura , Hisaaki Gyoten , Noboru Taniguchi , Takaharu Gamo , Yoshio Moriwaki , Tsutomu Iwaki
发明人: Kazuhito Hatoh , Junji Niikura , Hisaaki Gyoten , Noboru Taniguchi , Takaharu Gamo , Yoshio Moriwaki , Tsutomu Iwaki
CPC分类号: H01M4/9041 , H01M4/8621 , H01M8/142 , H01M2004/8684 , H01M2008/147 , H01M2300/0051 , Y02E60/526 , Y10S420/90
摘要: An anode for high temperature fuel cell containing metal hydrides or hydrogen absorbing alloys at least in part of the anode material of high temperature fuel cell operating while consuming a gas containing hydrogen, or a gas substantially containing hydrogen, as the fuel. In particular, at least in part of the anode for molten carbonate fuel cell, either metal hydrides or hydrogen absorbing alloys is used, and the performance of the anode is enhanced, and it contributes to extension of the life of the anode.
摘要翻译: 一种用于高温燃料电池的阳极,其含有至少部分高温燃料电池的负极材料中的金属氢化物或吸氢合金,同时消耗含氢的气体或基本上含有氢的气体作为燃料。 特别地,至少部分用于熔融碳酸盐燃料电池的阳极,使用金属氢化物或吸氢合金,并且提高阳极的性能,并且有助于延长阳极的寿命。
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公开(公告)号:US08951447B2
公开(公告)日:2015-02-10
申请号:US13119117
申请日:2010-04-26
申请人: Noboru Taniguchi , Kenichi Tokuhiro , Takahiro Suzuki , Tomohiro Kuroha , Takaiki Nomura , Kazuhito Hatoh
发明人: Noboru Taniguchi , Kenichi Tokuhiro , Takahiro Suzuki , Tomohiro Kuroha , Takaiki Nomura , Kazuhito Hatoh
IPC分类号: H01B1/02 , B01J35/00 , B01J23/00 , B01J23/08 , B01J23/10 , B01J23/62 , C01B3/04 , C01B13/02 , C01G25/00 , C25B1/00
CPC分类号: B01J35/004 , B01J23/002 , B01J23/08 , B01J23/10 , B01J23/62 , B01J2523/00 , C01B3/042 , C01B13/0207 , C01G25/006 , C01P2002/52 , C01P2002/54 , C01P2002/72 , C01P2002/77 , C01P2002/84 , C01P2004/34 , C01P2006/40 , C25B1/003 , Y02E60/364 , B01J2523/25 , B01J2523/32 , B01J2523/48 , B01J2523/375 , B01J2523/33
摘要: The optically pumped semiconductor according to the present invention is an optically pumped semiconductor that is a semiconductor of a perovskite oxide. The optically pumped semiconductor has a composition represented by a general formula: BaZr1-xMxO3-α, where M denotes at least one element selected from trivalent elements, x denotes a numerical value more than 0 but less than 0.8, and α denotes an amount of oxygen deficiency that is a numerical value more than 0 but less than 1.5. The optically pumped semiconductor has a crystal system of a cubic, tetragonal, or orthorhombic crystal. When lattice constants of the crystal system are referred to as a, b, and c, provided that a≦b≦c, conditions that 0.41727 nm≦a, b, c≦0.42716 nm and a/c≧0.98 are satisfied.
摘要翻译: 根据本发明的光泵浦半导体是作为钙钛矿氧化物的半导体的光泵浦半导体。 光泵浦半导体具有由通式BaZr1-xMxO3-α表示的组成,其中M表示选自三价元素中的至少一种元素,x表示大于0但小于0.8的数值,α表示 氧缺乏是数值超过0但小于1.5的缺氧。 光泵浦半导体具有立方晶,四方晶或正交晶体的晶体系。 如果晶体系的晶格常数被称为a,b和c,条件是满足0.41727nm≦̸ a,b,c≦̸ 0.42716nm和a /c≥0.98的条件。
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公开(公告)号:US20120285823A1
公开(公告)日:2012-11-15
申请号:US13522855
申请日:2011-01-19
申请人: Takahiro Suzuki , Takaiki Nomura , Kazuhito Hatoh , Noboru Taniguchi , Tomohiro Kuroha , Kenichi Tokuhiro
发明人: Takahiro Suzuki , Takaiki Nomura , Kazuhito Hatoh , Noboru Taniguchi , Tomohiro Kuroha , Kenichi Tokuhiro
CPC分类号: C25B1/003 , C01B3/042 , C01B2203/066 , Y02E60/364 , Y02E60/368
摘要: A hydrogen generation device (100) of the present invention includes: a transparent substrate (1); a photocatalytic electrode (4) formed of a transparent conductive layer (2) and a photocatalytic layer (3) disposed on the transparent substrate (1); a counter electrode (8) connected electrically to the transparent conductive layer (2); a water-containing electrolyte solution layer provided between the photocatalytic electrode (3) and the counter electrode (8); a separator (6) that separates the electrolyte solution layer into a first electrolyte solution layer (5) in contact with the photocatalytic electrode (4) and a second electrolyte solution layer (7) in contact with the counter electrode (8); a first gas outlet (14) for discharging a gas generated in the first electrolyte solution layer (5); and a second gas outlet (15) for discharging a gas generated in the second electrolyte solution layer (7). The photocatalytic electrode (4) and the counter electrode (8) are arranged so that a surface of the photocatalytic layer (3) and a surface of the counter electrode (8) face each other. The separator (6) allows an electrolyte in the electrolyte solution layer to pass therethrough and prevents hydrogen gas and oxygen gas in the electrolyte solution layer from passing therethrough.
摘要翻译: 本发明的氢产生装置(100)包括:透明基板(1); 由透明导电层(2)和设置在透明基板(1)上的光催化层(3)形成的光催化电极(4); 与所述透明导电层(2)电连接的对电极(8); 设置在光催化剂电极(3)和对电极(8)之间的含水电解液层; 将电解质溶液层分离成与光催化剂电极(4)接触的第一电解质溶液层(5)和与反电极(8)接触的第二电解液层(7)的分离器(6)。 用于排出在第一电解质溶液层(5)中产生的气体的第一气体出口(14); 和用于排出在第二电解质溶液层(7)中产生的气体的第二气体出口(15)。 光催化剂电极(4)和对电极(8)的配置使得光催化剂层(3)的表面和对置电极(8)的表面彼此面对。 分离器(6)允许电解质溶液层中的电解质通过,防止电解质溶液层中的氢气和氧气通过。
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公开(公告)号:US08236146B2
公开(公告)日:2012-08-07
申请号:US12811034
申请日:2009-10-29
申请人: Takaiki Nomura , Takahiro Suzuki , Kenichi Tokuhiro , Tomohiro Kuroha , Noboru Taniguchi , Kazuhito Hatoh , Shuzo Tokumitsu
发明人: Takaiki Nomura , Takahiro Suzuki , Kenichi Tokuhiro , Tomohiro Kuroha , Noboru Taniguchi , Kazuhito Hatoh , Shuzo Tokumitsu
CPC分类号: H01M8/0656 , C25B1/003 , H01G9/205 , H01M16/006 , H01M2008/1095 , Y02E10/542 , Y02E60/366 , Y02P20/135
摘要: A photoelectrochemical cell (100) includes: a semiconductor electrode (120) including a conductor (121) and an n-type semiconductor layer (122); a counter electrode (130) connected electrically to the conductor (121); an electrolyte (140) in contact with the surfaces of the n-type semiconductor layer (122) and the counter electrode (130); and a container (110) accommodating the semiconductor electrode (120), the counter electrode (130) and the electrolyte (140). The photoelectrochemical cell (100) generates hydrogen by irradiation of the n-type semiconductor layer (122) with light. In the semiconductor electrode (120), relative to the vacuum level, (I) the band edge levels of the conduction band and the valence band in the surface near-field region of the n-type semiconductor layer (122), respectively, are equal to or higher than the band edge levels of the conduction band and the valence band in the junction plane near-field region of the n-type semiconductor layer (122) with the conductor (121), (II) the Fermi level of the junction plane near-field region of the n-type semiconductor layer (122) is higher than the Fermi level of the surface near-field region of the n-type semiconductor layer (122), and (III) the Fermi level of the conductor (121) is higher than the Fermi level of the junction plane near-field region of the n-type semiconductor layer (122).
摘要翻译: 光电化学电池(100)包括:包括导体(121)和n型半导体层(122)的半导体电极(120); 与所述导体(121)电连接的对电极(130); 与所述n型半导体层(122)和所述对电极(130)的表面接触的电解液(140)。 以及容纳半导体电极(120),对电极(130)和电解质(140)的容器(110)。 光电化学电池(100)通过用光照射n型半导体层(122)来产生氢。 在半导体电极(120)中,相对于真空度,(I)分别在n型半导体层(122)的表面近场区域中的导带和价带的带边缘电平为 等于或高于具有导体(121)的n型半导体层(122)的结平面近场区中的导带和价带的带边缘电平,(II)是所述导体的费米能级 n型半导体层(122)的接面平面近场区域高于n型半导体层(122)的表面近场区域的费米能级,(III)导体的费米能级 (121)高于n型半导体层(122)的结面近场区域的费米能级。
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