AMMONIA DECOMPOSITION CATALYST
    83.
    发明申请
    AMMONIA DECOMPOSITION CATALYST 审中-公开
    氨基酸分解催化剂

    公开(公告)号:US20110306489A1

    公开(公告)日:2011-12-15

    申请号:US13203376

    申请日:2010-02-18

    IPC分类号: B01J21/18

    摘要: Disclosed is an ammonia decomposition catalyst which is obtained by heat-treating a complex at a temperature of 360° C. to 900° C. in a reducing atmosphere, wherein the complex containing a polymer having a molecular weight of 1,000 to 500,000 represented by the formula [I], a transition metal coordinated with the polymer, and an activated carbon or a carbon nanotube added thereto. In a case of using the carbon nanotube, an alkali metal compound or an alkaline earth metal compound is added to the heat-treated complex. R1 represents H or hydrocarbon having 1 to 10 carbon atoms, R2 and R3 each represent H, halogen, nitro, acyl, ester, carboxyl, formyl, nitrile, sulfone, aryl, or alkyl group having 1 to 15 carbon atoms, X and Y each represent H or OH, Z represents CH or N, R4 and R5 each represent H, OH, ether, amino, aryl, or alkyl group having 1 to 15 carbon atoms, x represents a real number of 1 to 2, y represents a real number of 1 to 3, and n represents a real number of 2 to 120. The amount of the transition metal deposited on the catalyst can be increased without deteriorating the dispersion of the metal, so that the amount of the catalyst required to obtain a desired activity can be reduced.

    摘要翻译: 公开了一种氨还原催化剂,其通过在还原气氛中在360℃至900℃的温度下热处理络合物获得,其中所述络合物含有分子量为1,000至500,000的聚合物,其由 式[I],与聚合物配位的过渡金属,和加入其中的活性炭或碳纳米管。 在使用碳纳米管的情况下,向热处理复合体中添加碱金属化合物或碱土金属化合物。 R1表示H或碳原子数1〜10的烃,R2和R3各自表示H,卤素,硝基,酰基,酯,羧基,甲酰基,腈,砜,芳基或碳原子数1〜15的烷基,X和Y 各自表示H或OH,Z表示CH或N,R 4和R 5各自表示H,OH,醚,氨基,芳基或具有1至15个碳原子的烷基,x表示1至2的实数,y表示 实数1〜3,n表示2〜120的实数。可以提高沉积在催化剂上的过渡金属的量,而不会使金属的分散性恶化,从而获得所需催化剂的量 可以减少所需的活动。

    AMMONIA SYNTHESIS PROCESS
    84.
    发明申请
    AMMONIA SYNTHESIS PROCESS 失效
    氨基酸合成方法

    公开(公告)号:US20110286907A1

    公开(公告)日:2011-11-24

    申请号:US13143619

    申请日:2009-12-22

    IPC分类号: C01C1/04

    摘要: The invention provides a process for efficient synthesis of ammonia. The process includes a water-splitting step in which water is decomposed to obtain a first source gas comprising hydrogen and oxygen, a first oxygen removal step in which the oxygen contained in the first source gas is at least partially separated and removed by an oxygen separating membrane or hydrogen separating membrane to obtain a second source gas having a lower oxygen concentration than the first source gas, a second oxygen removal step in which the oxygen in the second source gas is reacted with hydrogen to produce water for removal, or is adsorbed onto an adsorption medium for removal, to obtain a third source gas having a lower oxygen concentration than the second source gas, and an ammonia synthesis step in which the hydrogen in the third source gas is reacted with nitrogen to synthesize ammonia.

    摘要翻译: 本发明提供了一种有效合成氨的方法。 该方法包括水分解步骤,其中水被分解以获得包含氢和氧的第一源气体,第一氧除去步骤,其中通过氧分离将至少部分地分离和除去第一源气体中所含的氧 膜或氢分离膜,以获得具有比第一源气体低的氧浓度的第二源气体;第二氧除去步骤,其中第二源气体中的氧与氢反应以产生除去水或吸附到 用于除去的吸附介质,以获得具有比第二源气体低的氧浓度的第三源气体,以及氨合成步骤,其中第三源气体中的氢与氮反应以合成氨。

    FUEL CELL SYSTEM
    85.
    发明申请
    FUEL CELL SYSTEM 审中-公开
    燃油电池系统

    公开(公告)号:US20110236782A1

    公开(公告)日:2011-09-29

    申请号:US13120095

    申请日:2008-09-22

    IPC分类号: H01M8/04

    摘要: The power generation performance of a fuel cell is improved by reducing a concentration overvoltage of an anode, without increasing the cost thereof. A fuel cell system is provided with a fuel cell that generates electricity by means of electrochemical reactions between a fuel containing liquefied ammonia and an oxidizing agent, a fuel supply unit that supplies the fuel to the fuel cell, an oxidizing agent supply unit that supplies the oxidizing agent to the fuel cell, a temperature measurement unit that measures the temperature of the fuel cell, and a control unit that controls the pressure of the fuel to be supplied from the fuel supply unit to the fuel cell in accordance with the temperature of the fuel cell.

    摘要翻译: 通过降低阳极的浓度过电压来提高燃料电池的发电性能,而不增加其成本。 燃料电池系统设置有通过包含液化氨和氧化剂的燃料之间的电化学反应产生电力的燃料电池,向燃料电池供应燃料的燃料供给单元,供给燃料电池单元 氧化剂到燃料电池,温度测量单元,其测量燃料电池的温度;以及控制单元,其根据所述燃料电池的温度控制从燃料供应单元供应到燃料电池的燃料的压力 燃料电池。

    FUEL CELL SYSTEM
    86.
    发明申请
    FUEL CELL SYSTEM 有权
    燃油电池系统

    公开(公告)号:US20110236779A1

    公开(公告)日:2011-09-29

    申请号:US12679174

    申请日:2008-10-17

    IPC分类号: H01M8/04

    摘要: A fuel cell system whose fuel loss caused by the crossover of the fuel is small and which can be operated economically. The fuel cell system includes a fuel cell 10, a primary feeding system 12 for feeding a primary fuel which is a liquid fuel to the fuel cell 10, a secondary feeding system 13 for feeding a secondary fuel which is a liquid fuel whose saturation vapor pressure is lower than that of the primary fuel to the fuel cell 10, a ECU 30 for controlling each part so that the primary fuel in the fuel cell is replaced with the secondary fuel when terminating the operation of the fuel cell 10.

    摘要翻译: 燃料电池系统,其由燃料的交叉引起的燃料损失小并且可以经济地运行。 燃料电池系统包括燃料电池10,用于将作为液体燃料的一次燃料供给到燃料电池10的初级进料系统12,用于供给作为液体燃料的二次燃料的二次进料系统13,该二次燃料的饱和蒸汽压 低于燃料电池10的主要燃料的燃料电池10,用于控制每个部分的ECU 30,使得在终止燃料电池10的操作时燃料电池中的主要燃料被替换为二次燃料。

    Fuel cell with a tension in an in-plane direction
    89.
    发明授权
    Fuel cell with a tension in an in-plane direction 有权
    在平面方向上具有张力的燃料电池

    公开(公告)号:US07510792B2

    公开(公告)日:2009-03-31

    申请号:US11026411

    申请日:2005-01-03

    摘要: A fuel cell includes a diffusion layer formed in a sheet having a small thickness. The fuel cell is assembled with a tension imposed on the sheet in an in-plane direction of the sheet. The tension is imposed on the diffusion layer from a frame disposed outside the fuel cell. The tension is of such a magnitude as to prevent a portion of the sheet positioned corresponding to a gas passage of a separator from being deformed when the fuel cell is assembled and has a tightening force thereby applied thereto. The tension is adjustable according to a fuel cell operating condition. These structures can prevent a separator rib from pushing into a membrane, maintaining the gas passability of the diffusion layer well.

    摘要翻译: 燃料电池包括形成在具有小厚度的片材中的扩散层。 燃料电池以片材的面内方向施加在片材上的张力组装。 从设置在燃料电池外侧的框架施加在扩散层上的张力。 张力具有如此大的程度,以防止当燃料电池组装时对应于隔板的气体通道定位的片材的一部分变形并且具有由此施加的紧固力。 张力可根据燃料电池工作条件进行调节。 这些结构可以防止分隔肋推入膜中,保持扩散层的气体通过性良好。

    CATALYST USING HYDRAZONE COMPOUND, HYDRAZONE POLYMER COMPOUND, AND CATALYST USING HYDRAZONE POLYMER COMPOUND
    90.
    发明申请
    CATALYST USING HYDRAZONE COMPOUND, HYDRAZONE POLYMER COMPOUND, AND CATALYST USING HYDRAZONE POLYMER COMPOUND 有权
    使用HYDRAZONE化合物的催化剂,HYDRAZONE聚合物化合物和使用HYDRAZONE POLYMER化合物的催化剂

    公开(公告)号:US20090062506A1

    公开(公告)日:2009-03-05

    申请号:US12201433

    申请日:2008-08-29

    IPC分类号: C08G73/06 C07F19/00

    CPC分类号: C08G8/28 C08G8/10

    摘要: A catalyst obtained by calcining a hydrazone metal complex in which at least one catalytic metal species is coordinated to a hydrazone compound represented by a General Formula (1) below, a hydrazone polymer compound including at least a structural unit derived from a hydrazone compound represented by the General Formula (1) below as a repeating unit, and a catalyst obtained by calcining a hydrazone polymer metal complex in which at least one catalytic metal species is coordinated to a hydrazone polymer compound including at least a structural unit derived from a hydrazone compound represented by the General Formula (1) below: wherein, Py represents a 2-pyridyl group, a 3-pyridyl group, or a 4-pyridyl group.

    摘要翻译: 通过煅烧其中至少一种催化金属与下述通式(1)表示的腙化合物配位的腙金属络合物获得的催化剂,至少包含衍生自腙化合物的结构单元的腙聚合物化合物, 作为重复单元的通式(1)表示的腙系化合物和通过煅烧腙聚合物金属络合物而获得的催化剂,其中至少一种催化金属物质与至少包含衍生自表示的腙化合物的结构单元的腙高分子化合物配位 通式(1)表示:其中,Py表示2-吡啶基,3-吡啶基或4-吡啶基。