公开(公告)号：US20080183001A1

公开(公告)日：2008-07-31

申请号：US11882335

申请日：2007-08-01

申请人： Takanobu Tsudera ,  Tohru Kubota ,  Ayumu Kiyomori

发明人： Takanobu Tsudera ,  Tohru Kubota ,  Ayumu Kiyomori

IPC分类号： C07F7/10

CPC分类号： C07F7/0889

摘要： A method for producing an isocyanate group-containing siloxane compound is provided. In this method, a halogenated siloxane compound represented by the following general formula (1): or the following general formula (2) wherein R1, R2, R3, and R4 are independently hydrogen atom, a monovalent hydrocarbon group containing 1 to 8 carbon atoms, or a siloxy group represented by OSiR5R6R7 wherein R8, R6, and R7 are a monovalent hydrocarbon group containing 1 to 8 carbon atoms, X is a halogen atom, n is an integer of 1 to 10, a is 0, 1, or 2, and b is an integer of 2 to 9; is reacted with a cyanate salt represented by the following general formula (3): Mm+(OCN)m   (3) wherein M represents an alkali metal or an alkaline earth metal, and m is 1 or 2. The isocyanate group-containing siloxane compound produced is represented by the following general formula (4): or the following general formula (5): wherein R1, R2, R3, R4, n, q, and a are as defined above.

摘要翻译： 提供含异氰酸酯基的硅氧烷化合物的制造方法。 在该方法中，由以下通式（1）表示的卤代硅氧烷化合物或其中R 1，R 2，R 2， > 3，R 4独立地是氢原子，含有1至8个碳原子的一价烃基或由OSiR 5 R表示的甲硅烷氧基， 其中R 8，R 6和R 7是一价的，其中R 8，R 6和R 7是一价 含有1〜8个碳原子的烃基，X为卤素原子，n为1〜10的整数，a为0,1或2，b为2〜9的整数。 与由以下通式（3）表示的氰酸盐反应：<？in-line-formula description =“In-line formula”end =“lead”？> M + （3）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中M表示碱金属或碱土金属，m为1或 所制备的含异氰酸酯基的硅氧烷化合物由以下通式（4）表示：或下列通式（5）表示：其中R 1，R 2， R 3，R 4，n，q和a如上定义。

公开(公告)号：US07351313B2

公开(公告)日：2008-04-01

申请号：US10506668

申请日：2003-03-07

申请人： Hiroyuki Hasegawa ,  Tohru Kubota ,  Shinro Mashiko

发明人： Hiroyuki Hasegawa ,  Tohru Kubota ,  Shinro Mashiko

IPC分类号： C25B9/04

CPC分类号： B82Y10/00 ,  C25D9/02 ,  H01L51/0048 ,  H01L51/0078 ,  H01L51/0504 ,  Y10S977/72 ,  Y10S977/762 ,  Y10S977/899 ,  Y10T29/49117 ,  Y10T29/49155 ,  Y10T29/49156

摘要： The object of the present invention is to provide a nano-scale molecular assembly such as a conductive nano-wire. Specifically, there is provided an electrolytic apparatus for forming a molecular assembly, including two electrodes and an electrolytic cell holding an electrolyte and the two electrodes, wherein the gap between the two electrodes is from 1 nm to 100 μm, by allowing the electrolytic cell to hold an electrolyte containing molecules that is to constitute the molecular assembly, and applying a voltage across the two electrodes in the state wherein the electrolyte and the two electrodes are in contact.

摘要翻译： 本发明的目的是提供诸如导电纳米线的纳米级分子组件。 具体地说，提供了一种用于形成分子组件的电解装置，包括两个电极和一个保持电解质的电解槽和两个电极，其中两个电极之间的间隙为1nm至100μm，通过使电解槽 保持含有构成分子组件的分子的电解质，并且在电解质和两个电极接触的状态下在两个电极之间施加电压。

公开(公告)号：US20060264649A1

公开(公告)日：2006-11-23

申请号：US11435936

申请日：2006-05-18

申请人： Katsuhiro Uehara ,  Tohru Kubota

发明人： Katsuhiro Uehara ,  Tohru Kubota

IPC分类号： C07F7/04

CPC分类号： C07F7/21

摘要： Novel cyclic siloxane compounds have both an aliphatic unsaturation-containing organic group and fluorinated alkyl groups within the molecular structure. When used to form silicone fluids and rubbers, they are useful as a modifier for giving novel physical properties thereto and when used as polymerizable monomers, they are effective for improving the performance of polymers or forming polymers with novel physical properties.

摘要翻译： 新的环状硅氧烷化合物在分子结构中具有含脂族不饱和键的有机基团和氟化烷基。 当用于形成硅氧烷流体和橡胶时，它们可用作赋予其新的物理性质的改性剂，并且当用作可聚合单体时，它们对于改善具有新物理性能的聚合物或形成聚合物的性能是有效的。

公开(公告)号：US07112710B2

公开(公告)日：2006-09-26

申请号：US11186845

申请日：2005-07-22

申请人： Ayumu Kiyomori ,  Tohru Kubota

发明人： Ayumu Kiyomori ,  Tohru Kubota

IPC分类号： C07F7/18

CPC分类号： C07F7/188

摘要： By reacting α,β-unsaturated carboxylic esters with hydrosilanes or hydrosiloxanes in the presence of a catalytic amount of tris(pentafluorophenyl)borane, silyl ketene acetals or disilyl ketene acetals with high purity are produced in high yields.

摘要翻译： 通过使α，β-不饱和羧酸酯与氢硅烷或氢硅氧烷在催化量的三（五氟苯基）硼烷存在下反应，以高产率生产出高纯度的甲硅烷基乙烯酮缩醛或二甲硅烷基乙烯酮缩醛。

公开(公告)号：US07053233B2

公开(公告)日：2006-05-30

申请号：US11104588

申请日：2005-04-13

申请人： Yoichi Tonomura ,  Tohru Kubota

发明人： Yoichi Tonomura ,  Tohru Kubota

IPC分类号： C07F7/04

CPC分类号： C07F7/10 ,  C07F7/1804

摘要： A silane compound of the following formula (1) having two or more protected functional groups A-R—Si(CH3)nX3-n  (1) wherein A represents a group of the following formula wherein R1, R2 and R3 each independently represent a monovalent hydrocarbon group having 1 to 10 carbon atoms, a is an integer of 1 to 10, and b is an integer of 1 to 10, or wherein R1, R2 and R3 are as defined above, R represents a linear or branched, divalent hydrocarbon group having 2 to 10 carbon atoms, X represents a halogen atom or an organoxy group having 1 to 10 carbon atoms, and n is 0, 1 or 2 is prevented from the reaction of the functional groups per self when undergoing modification or treatment. When the protection is removed after introduction of the protected functional groups, quantitative and efficient introduction of the two or more functional groups is ensured, resulting in more developed effects of modification and addition.

摘要翻译： 具有两个以上被保护官能团的下式（1）的硅烷化合物<？in-line-formula description =“In-line Formula”end =“lead”→> AR-Si（CH 3） （1）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中A表示 下式的基团其中R 1，R 2和R 3各自独立地表示具有1至10个碳原子的一价烃基， a为1〜10的整数，b为1〜10的整数，或者R 1，R 2，R 3， R表示碳原子数2〜10的直链状或支链状的二价烃基，X表示卤素原子或碳原子数1〜10的有机氧基，n为0,1或2， 当进行改性或处理时，每个自身的官能团的反应。 引入保护的官能团之后，当保护被去除时，确保了两个或更多个官能团的定量和有效的引入，从而导致更显着的改性和添加效果。

公开(公告)号：US06875881B2

公开(公告)日：2005-04-05

申请号：US10854197

申请日：2004-05-27

申请人： Yasufumi Kubota ,  Tohru Kubota ,  Satoshi Onai ,  Koji Sakuta ,  Akira Yamamoto

发明人： Yasufumi Kubota ,  Tohru Kubota ,  Satoshi Onai ,  Koji Sakuta ,  Akira Yamamoto

IPC分类号： C07B61/00 ,  C07F7/08 ,  C07F7/18

CPC分类号： C07F7/0874

摘要： A branched tetrasiloxane is prepared by preforming a liquid mixture of a disiloxane compound, an alcohol and an acid catalyst, adding a trialkoxysilane compound to the mixture for reaction, and adding water to the reaction mixture for co-hydrolysis, thereby forming a branched tetrasiloxane. The method is capable of preparing a branched tetrasiloxane, especially methyltris(trimethylsiloxy)silane having a sufficiently high purity to use as cosmetic oil in good yields.

摘要翻译： 通过预先制备二硅氧烷化合物，醇和酸催化剂的液体混合物，向混合物中加入三烷氧基硅烷化合物进行反应，并将水加入到用于共水解的反应混合物中，从而形成支链四硅氧烷，制备支链四硅氧烷。 该方法能够制备具有足够高纯度的支链四硅氧烷，特别是甲基三（三甲基甲硅烷氧基）硅烷，以高产率用作化妆油。

公开(公告)号：US06518447B2

公开(公告)日：2003-02-11

申请号：US09985528

申请日：2001-11-05

申请人： Yoichi Tonomura ,  Tohru Kubota ,  Yasufumi Kubota

发明人： Yoichi Tonomura ,  Tohru Kubota ,  Yasufumi Kubota

IPC分类号： C07F708

CPC分类号： C07F7/12 ,  C07F7/188

摘要： Chlorosilane compounds having a thexyl group which is a bulky substituent group are novel. The compounds are useful silylating agents because stable silylated products are obtained due to the bulky substituent group.