公开(公告)号：US07918982B2

公开(公告)日：2011-04-05

申请号：US11961445

申请日：2007-12-20

申请人： Hiroyuki Hasegawa ,  Tohru Kubota ,  Shinro Mashiko

发明人： Hiroyuki Hasegawa ,  Tohru Kubota ,  Shinro Mashiko

IPC分类号： C25D5/02 ,  C25B3/00

CPC分类号： B82Y10/00 ,  C25D9/02 ,  H01L51/0048 ,  H01L51/0078 ,  H01L51/0504 ,  Y10S977/72 ,  Y10S977/762 ,  Y10S977/899 ,  Y10T29/49117 ,  Y10T29/49155 ,  Y10T29/49156

摘要： The object of the disclosure is to provide a nano-scale molecular assembly such as a conductive nano-wire. Specifically, there is provided an electrochemical apparatus for forming a molecular assembly, including two electrodes and an electrochemical cell holding an electrolytic solution and the two electrodes, wherein the gap between the two electrodes is from 1 nm to 100 μm, by allowing the electrochemical cell to hold an electrolytic solution containing molecules that is to constitute the molecular assembly, and applying a voltage across the two electrodes in the state wherein the electrolyte and the two electrodes are in contact.

摘要翻译： 本公开的目的是提供纳米级分子组件，例如导电纳米线。 具体地说，提供一种用于形成分子组件的电化学装置，包括两个电极和一个保持电解液的电化学电池和两个电极，其中两个电极之间的间隙为1nm至100μm，通过允许电化学电池 以保持含有构成分子组装体的分子的电解液，并且在电解质和两个电极接触的状态下，在两个电极之间施加电压。

公开(公告)号：US20050138804A1

公开(公告)日：2005-06-30

申请号：US10506668

申请日：2003-03-07

申请人： Hiroyuki Hasegawa ,  Tohru Kubota ,  Shinro Mashiko

发明人： Hiroyuki Hasegawa ,  Tohru Kubota ,  Shinro Mashiko

IPC分类号： C25D1/04 ,  C25D9/02 ,  H01L51/00 ,  H01L51/05 ,  H01L51/30 ,  H01B13/00 ,  B05B5/025 ,  H05K3/02

CPC分类号： B82Y10/00 ,  C25D9/02 ,  H01L51/0048 ,  H01L51/0078 ,  H01L51/0504 ,  Y10S977/72 ,  Y10S977/762 ,  Y10S977/899 ,  Y10T29/49117 ,  Y10T29/49155 ,  Y10T29/49156

摘要： The object of the present invention is to provide a nano-scale molecular assembly such as a conductive nano-wire. Specifically, there is provided an electrolytic apparatus for forming a molecular assembly, including two electrodes and an electrolytic cell holding an electrolyte and the two electrodes, wherein the gap between the two electrodes is from 1 nm to 100 μm, by allowing the electrolytic cell to hold an electrolyte containing molecules that is to constitute the molecular assembly, and applying a voltage across the two electrodes in the state wherein the electrolyte and the two electrodes are in contact.

摘要翻译： 本发明的目的是提供诸如导电纳米线的纳米级分子组件。 具体地说，提供了一种用于形成分子组件的电解装置，包括两个电极和一个保持电解质的电解槽和两个电极，其中两个电极之间的间隙为1nm至100μm，通过使电解槽 保持含有构成分子组件的分子的电解质，并且在电解质和两个电极接触的状态下在两个电极之间施加电压。

公开(公告)号：US20110162968A1

公开(公告)日：2011-07-07

申请号：US13034122

申请日：2011-02-24

申请人： Hiroyuki Hasegawa ,  Tohru Kubota ,  Shinro Mashiko

发明人： Hiroyuki Hasegawa ,  Tohru Kubota ,  Shinro Mashiko

IPC分类号： C25D1/04 ,  B82Y40/00

CPC分类号： B82Y10/00 ,  C25D9/02 ,  H01L51/0048 ,  H01L51/0078 ,  H01L51/0504 ,  Y10S977/72 ,  Y10S977/762 ,  Y10S977/899 ,  Y10T29/49117 ,  Y10T29/49155 ,  Y10T29/49156

摘要： The object of the disclosure is to provide a nano-scale molecular assembly such as a conductive nano-wire. Specifically, there is provided an electrochemical apparatus for forming a molecular assembly, including two electrodes and an electrochemical cell holding an electrolytic solution and the two electrodes, wherein the gap between the two electrodes is from 1 nm to 100 μm, by allowing the electrochemical cell to hold an electrolytic solution containing molecules that is to constitute the molecular assembly, and applying a voltage across the two electrodes in the state wherein the electrolyte and the two electrodes are in contact.

摘要翻译： 本公开的目的是提供纳米级分子组件，例如导电纳米线。 具体地说，提供一种用于形成分子组件的电化学装置，包括两个电极和一个保持电解液的电化学电池和两个电极，其中两个电极之间的间隙为1nm至100μm，通过允许电化学电池 以保持含有构成分子组装体的分子的电解液，并且在电解质和两个电极接触的状态下，在两个电极之间施加电压。

公开(公告)号：US07351313B2

公开(公告)日：2008-04-01

申请号：US10506668

申请日：2003-03-07

申请人： Hiroyuki Hasegawa ,  Tohru Kubota ,  Shinro Mashiko

发明人： Hiroyuki Hasegawa ,  Tohru Kubota ,  Shinro Mashiko

IPC分类号： C25B9/04

CPC分类号： B82Y10/00 ,  C25D9/02 ,  H01L51/0048 ,  H01L51/0078 ,  H01L51/0504 ,  Y10S977/72 ,  Y10S977/762 ,  Y10S977/899 ,  Y10T29/49117 ,  Y10T29/49155 ,  Y10T29/49156

摘要： The object of the present invention is to provide a nano-scale molecular assembly such as a conductive nano-wire. Specifically, there is provided an electrolytic apparatus for forming a molecular assembly, including two electrodes and an electrolytic cell holding an electrolyte and the two electrodes, wherein the gap between the two electrodes is from 1 nm to 100 μm, by allowing the electrolytic cell to hold an electrolyte containing molecules that is to constitute the molecular assembly, and applying a voltage across the two electrodes in the state wherein the electrolyte and the two electrodes are in contact.

摘要翻译： 本发明的目的是提供诸如导电纳米线的纳米级分子组件。 具体地说，提供了一种用于形成分子组件的电解装置，包括两个电极和一个保持电解质的电解槽和两个电极，其中两个电极之间的间隙为1nm至100μm，通过使电解槽 保持含有构成分子组件的分子的电解质，并且在电解质和两个电极接触的状态下在两个电极之间施加电压。

公开(公告)号：US07056446B2

公开(公告)日：2006-06-06

申请号：US10662886

申请日：2003-09-16

申请人： Takashi Nagase ,  Tohru Kubota ,  Shinro Mashiko

发明人： Takashi Nagase ,  Tohru Kubota ,  Shinro Mashiko

IPC分类号： B44C1/22

CPC分类号： H01L21/0332 ,  G01N27/07 ,  H01L21/32139 ,  H01L21/76838 ,  Y10S977/722

摘要： A method of easily manufacturing a nano-gap electrode by using a focused ion beam lithography includes a layer depositing step of depositing an electrode layer and a metal mask layer in this order on an insulating substrate, a mask pattern forming step of etching the metal mask layer by using the focused ion beam and thereby forming a mask pattern, a dry etching step of transferring a pattern to the electrode layer by dry etching, and a wet etching step of removing the metal mask layer by using a solution that selectively dissolves the metal mask layer compared to the electrode layer.

摘要翻译： 通过使用聚焦离子束光刻法容易地制造纳米间隙电极的方法包括在绝缘基板上依次沉积电极层和金属掩模层的层沉积步骤，蚀刻金属掩模的掩模图案形成步骤 通过使用聚焦离子束形成掩模图案的干蚀刻步骤，通过干蚀刻将图案转印到电极层的干蚀刻步骤以及通过使用选择性溶解金属的溶液去除金属掩模层的湿蚀刻步骤 掩模层与电极层相比。

公开(公告)号：US08541631B2

公开(公告)日：2013-09-24

申请号：US12975931

申请日：2010-12-22

申请人： Ayumu Kiyomori ,  Yusuke Itoh ,  Tohru Kubota

发明人： Ayumu Kiyomori ,  Yusuke Itoh ,  Tohru Kubota

IPC分类号： C07C41/09

CPC分类号： H01L21/306 ,  C09D4/00

摘要： A solid material is subjected to surface treatment by chemically bonding onto a surface of the solid material a stabilized monofunctional silanol represented by R1R2R3SiOH. R1, R2 and R3 may be the same or different, and each represent a substituent group independently selected from a substituted or unsubstituted, monovalent hydrocarbon group having from 1 to 40 carbon atoms or a substituted or unsubstituted, monovalent heterocyclic group having from 1 to 100 carbon atoms. The monofunctional silanol has a dehydrative self-condensation rate lower than triethylsilanol.

摘要翻译： 通过在固体材料的表面上化学键合由R1R2R3SiOH表示的稳定的单官能硅烷醇，对固体材料进行表面处理。 R 1，R 2和R 3可以相同或不同，各自表示独立地选自具有1至40个碳原子的取代或未取代的一价烃基或具有1至100个取代或未取代的1价杂环基的取代基 碳原子。 单官能硅烷醇具有低于三乙基硅烷醇的脱水自缩缩速率。

公开(公告)号：US08436166B2

公开(公告)日：2013-05-07

申请号：US12797721

申请日：2010-06-10

申请人： Yoichi Tonomura ,  Tohru Kubota

发明人： Yoichi Tonomura ,  Tohru Kubota

IPC分类号： C07F7/10

CPC分类号： C08K5/544 ,  C07F7/081

摘要： Vinylsilane compounds having a specific amino group, typically diethylaminopropyldimethylvinylsilane, N-methylpiperazinylpropyldimethylvinylsilane, and bistrimethylsilylaminopropyldimethylvinylsilane are novel and useful as a modifier for polymers.

摘要翻译： 具有特定氨基的乙烯基硅烷化合物通常是二乙基氨基丙基二甲基乙烯基硅烷，N-甲基哌嗪基丙基二甲基乙烯基硅烷和双三甲基甲硅烷基氨基丙基二甲基乙烯基硅烷作为聚合物的改性剂。

公开(公告)号：US08049027B2

公开(公告)日：2011-11-01

申请号：US12582026

申请日：2009-10-20

申请人： Takayuki Honma ,  Tohru Kubota ,  Ayumu Kiyomori

发明人： Takayuki Honma ,  Tohru Kubota ,  Ayumu Kiyomori

IPC分类号： C07F7/04 ,  C07F7/07 ,  C07F7/08

CPC分类号： C07F7/1804

摘要： An organosilicon compound having an amino group is provided. This compound is represented by the following general formula (1): wherein R1 and R2 respectively represent an unsubstituted or substituted aliphatic monovalent hydrocarbon group containing 1 to 10 carbon atoms with the proviso that the R1 and R2 may together form a ring with the nitrogen atom to which they are bonded, and that R1 and R2 may contain a heteroatom; R3 and R4 independently represent an unsubstituted or substituted monovalent hydrocarbon group containing 1 to 10 carbon atoms; and n represents an integer of 0 to 2. Use of this compound enables production of a polymer product having excellent mechanical properties, high heat resistance, and high transparency. The solution of this compound is stable, and can be stored for a long time, and when used for a polymer modifying agent, it facilitates introduction of amino group and hydroxy group.

摘要翻译： 提供具有氨基的有机硅化合物。 该化合物由以下通式（1）表示：其中R 1和R 2分别表示含有1至10个碳原子的未取代或取代的脂族一价烃基，条件是R 1和R 2可以与氮原子一起形成环 它们与它们键合，并且R 1和R 2可以含有杂原子; R3和R4独立地表示含有1至10个碳原子的未取代或取代的一价烃基; n表示0〜2的整数。该化合物的使用能够制造具有优异的机械性能，高耐热性和高透明性的聚合物制品。 该化合物的溶液是稳定的，可以长时间储存​​，当用于聚合物改性剂时，有利于氨基和羟基的引入。

公开(公告)号：US20100105938A1

公开(公告)日：2010-04-29

申请号：US12606520

申请日：2009-10-27

申请人： Yoichi Tonomura ,  Tohru Kubota

发明人： Yoichi Tonomura ,  Tohru Kubota

IPC分类号： C08F230/08

CPC分类号： C07F7/0838

摘要： A silyl (meth)acrylate compound containing a siloxy group having a bulky substituent is provided. The compound is represented by the following general formula (1): wherein R1 and R2 are independently a C3-10 monovalent branched hydrocarbon group having a hydrocarbon group at α or β position or a monovalent C3-10 cyclic hydrocarbon group; R3, R4, and R5 are independently an unsubstituted or substituted C1-20 hydrocarbon group or a siloxy group represented by the following general formula (2): —OSiR7R8R9  (2) wherein R7, R8, and R9 are independently an unsubstituted or substituted C1-20 hydrocarbon group; and R6 is hydrogen atom or methyl group. This compound is hydrolyzed at a reduced speed, and use of a polymer obtained by copolymerization with an alkyl methacrylate is capable of suppressing attachment of marine organisms to the ship with no or reduced biocide, and this polymer is useful for a hydrolytic self-polishing paint.

摘要翻译： 提供含有大体积取代基的甲硅烷氧基的甲基（甲基）丙烯酸酯化合物。 该化合物由以下通式（1）表示：其中R 1和R 2独立地为在α或bgr具有烃基的C 3-10单价支链烃基; 位置或一价C 3-10环烃基; R3，R4和R5独立地为未取代或取代的C 1-20烃基或由以下通式（2）表示的甲硅烷氧基：-OSiR7R8R9（2）其中R7，R8和R9独立地为未取代或取代的C1 -20烃基; R6是氢原子或甲基。 该化合物以降低的速度水解，并且使用通过与甲基丙烯酸烷基酯共聚得到的聚合物能够抑制海洋生物与没有或减少的杀生物剂的船舶的附着，并且该聚合物可用于水解自抛光涂料 。

公开(公告)号：US07202375B2

公开(公告)日：2007-04-10

申请号：US10854180

申请日：2004-05-27

申请人： Yoichi Tonomura ,  Tohru Kubota

发明人： Yoichi Tonomura ,  Tohru Kubota

IPC分类号： C07F7/10

CPC分类号： C07F7/12

摘要： Bissilylamino group-bearing chlorosilane compounds of formula (1): [(CH3)3Si]2NCH2CH2CH2Si(CH3)nCl3−n   (1) wherein n is 0 or 1 are novel. They are useful as silane coupling agents and surface treating agents. They can be readily converted, through reaction with alcohols, to bissilyl group-bearing alkoxysilane compounds which are useful as intermediates for the synthesis of aminopropyl-modified silicone oil. The invention also provides an industrially advantageous method capable of preparing the bissilylamino group-bearing chlorosilane compounds.

摘要翻译： 含二甲苯基氨基的氯硅烷化合物