摘要:
A thermoplastic vulcanizate comprising a) a dynamically vulcanized rubber, b) a thermoplastic resin, and c) optionally a synthetic oil, where the thermoplastic vulcanizate is substantially devoid of mineral oils.
摘要:
An improved process for the preparation of thermoplastic vulcanizates from butyl rubbers by hydrosilylation crosslinking of acrylic or alkacrylic functionalized copolymers of isobutylene and paramethylstyrene is disclosed. The functionalization results in lower compression and tension set than when using conventional butyl rubbers. Other physical properties of the thermoplastic vulcanizate are improved consistent with more efficient crosslinking of the functionalized copolymer.
摘要:
Desirable thermoplastic vulcanizates can be prepared from a polar engineering thermoplastic; a halogenated copolymer of p-alkylstyrene and an isomonoolefin having from 4 to 7 carbon atoms; and either an ethylene rubbery polymer or a diene based rubbery polymer or combinations thereof. The ethylene rubbery polymer desirably has at least one pendant carboxylic acid group, amine group, epoxy group, hydroxyl group or an anhydride of two carboxylic acid groups or combinations thereof. Desirable diene based rubbery polymers include epoxidized natural rubber and epoxidized homopolymers and copolymers of dienes.
摘要:
A thermoplastic elastomer is formed from a thermoplastic polymer such as a polyester, polycarbonate, or combinations thereof or a polyamide, which polymer is melt blended with an acrylic rubber. The acrylic rubber desirably has from about 0.5 to about 5 mole percent repeat units from halogen (desirably chlorine) containing monomer. Subsequently the acrylic rubber is crosslinked with 2,5-mercapto-1,3,4-thiadiazole or a derivative thereof. Such a thermoplastic elastomer may have a compression set less than 50% making it useful in applications involving continuous use under compression.
摘要:
A thermoplastic elastomer comprising a triblend of engineering resin, dynamically vulcanized alloy of thermoplastic olefin polymer and elastomeric copolymer, and a compatibilizer for the engineering resin and alloy. The compositions retain structural integrity at high temperature, and have good tensile properties, elongation and fluid resistance.
摘要:
The thermoplastic elastomer compositions contain a continuous phase or matrix of an engineering thermoplastic such as ester polymer and a discontinuous phase of an acrylic rubber which is cured substantially by using epoxidized oils. The cured composition which can be dynamically vulcanized has good physical properties such as tensile strength, elongation, and high temperature resistance.
摘要:
A thermoplastic elastomer composition prepared by dynamically vulcanizing a composition comprised (A) polyolefin 5-50 wt. parts, (B) brominated butyl rubber 5-50 wt. parts, (C) polychloroprene rubber 5-50 wt. parts and (D) process oil 10-50 wt. parts in the presence of peroxide is disclosed.
摘要:
The present invention relates to a process for manufacturing a shaped article such as tubes, and hoses comprising processing a fiber-reinforced thermoplastic polymer in an extruder apparatus.
摘要:
A thermoplastic vulcanizate comprising a dynamically-cured rubber, a thermoplastic polymer, and at least 2 percent by weight, based on the total weight of the thermoplastic vulcanizate, of a polyalphaolefin oligomer, where the polyalphaolefin oligomer is characterized by a kinematic viscosity per ASTM D445 at 100° C. of at least 35 cSt.
摘要:
Disclosed herein are low Shore A Hardness thermoplastic vulcanizate compositions having high Rebound values. In at least one exemplary embodiment, the compositions include a dispersed at least partially vulcanized rubber component; a thermoplastic component; and process oil; wherein the weight ratio of the thermoplastic component to the rubber component ranges from 80:20 to 15:85; and the thermoplastic component comprises more than 80 wt % of a polypropylene (preferably a random propylene copolymer) having a melting point less than about 105° C. The compositions can be used in molded products, consumer goods and the like.