摘要:
A controlled free-radical polymerization process for forming end-functionalized polymers is disclosed, particularly by degenerative iodine transfer. The end-functionalized polymers are characterized by a polydispersity less than 2.5 and a predetermined molecular weight. The end-functionalized polymers are useful as reactive intermediates in condensation polymerization, chain polymerization and heterogeneous polymerization reactions.
摘要:
Methods for the addition polymerization of cycloolefins using a cationic Group 10 metal complex and a weakly coordinating anion of the formula:null(Rnull)zM(Lnull)x(Lnull)ynullb nullWCAnulldwherein null(Rnull)zM(Lnull)x(Lnull)ynull is a cation complex where M represents a Group 10 transition metal; Rnull represents an anionic hydrocarbyl containing ligand; Lnull represents a Group 15 neutral electron donor ligand; Lnull represents a labile neutral electron donor ligand; x is 1 or 2; and y is 0, 1, 2, or 3; and z is 0 or 1, wherein the sum of x, y, and z is 4; and nullWCAnull represents a weakly coordinating counteranion complex; and b and d are numbers representing the number of times the cation complex and weakly coordinating counteranion complex are taken to balance the electronic charge on the overall catalyst complex.
摘要翻译:使用阳离子第10族金属络合物和下式的弱配位阴离子进行环烯加成聚合的方法:式中,[(R')zM(L')x( L“)y] b [WCA] d in-line-formula>其中[(R')zM(L')x(L”)y]是阳离子络合物,其中M表示第10族过渡金属 ; R'表示含阴离子烃基的配体; L'表示15族中性电子给体配体; L“表示不稳定的中性电子给体配体; x为1或2; y为0,1,2或3; 且z为0或1,其中x,y和z之和为4; 和[WCA]代表弱协调的对抗综合体; b和d是表示阳离子络合物和弱配位对映离子络合物在总体催化剂络合物上平衡电子电荷的次数的数字。
摘要:
The present invention relates to cyclic polymers and their use in photolithographic applications. The cyclic polymers contain a pendant acid labile functional group and a functional group containing a protected hydroxyl moiety. The polymers are post modified by deprotecting the pendant hydroxyl moiety and reacting the deprotected hydroxyl containing moiety with a coreactant. The post-functionalized polymers find application in chemically amplified photoresist compositions.
摘要:
A very high-solids polymeric dispersion, having a very low percentage of volatile organic compound is prepared by dispersing a plasticized liquid acrylic polymer in water and blending with another high molecular weight polymer dispersion and/or latex in water. This plasticized acrylic polymer dispersion has been found to be useful in combination with high molecular weight polymer dispersion and/or latex containing some smaller diameter particles in the preparation of sealant, caulk, adhesive and coating compositions. Such compositions have a polydisperse particle size distribution due to the larger plasticized liquid acrylic particles and the smaller high molecular weight polymer particles which facilitates higher particle packing densities and hence higher solids content without any undue adverse effect on the dispersion stability and rheological properties. The resulting compositions are more environmentally friendly than solvent based systems, dry quickly, and exhibit good physical properties for sealant use.
摘要:
A method for polymerizing at least one unsaturated monomer in the presence of a latex results in a high solids dispersion of polymer particles with lower viscosities than traditionally observed. A significant wt. % of the polymer from added monomers can be present in large particles, having nonspherical shapes. Some of the original latex particles are retained during the polymerization and these increase the solids content and lower the viscosity by packing in the interstices between large particles. The total polymer solids content can easily be varied from 70 to 92 or more wt. %. The viscosities at very high solids contents become paste-like but the materials still are stable to storage and further handling without causing the dispersion to separate into an agglomerated polymer portion and released water. The dispersions are useful to form sealants, membranes, etc., either with or without other additives. A preferred use is as an acrylate water-based caulking compound where the high solids and thixotropy of the dispersion allows for formation of a water-based caulk with low shrinkage.
摘要:
The invention relates to the field of high temperature composites made by the chemical vapor infiltration and deposition of a binding matrix within a porous structure. More particularly, the invention relates to pressure gradient processes for forcing infiltration of a reactant gas into a porous structure, apparatus for carrying out those processes, and the resulting products. The invention is particularly suited for the simultaneous CVI/CVD processing of large quantities (hundreds) of aircraft brake disks.
摘要:
The invention is directed to a damped brake rod for use in an aircraft landing gear, the landing gear comprising a strut and a wheel and brake assembly carried on the strut. The brake rod connects the wheel and brake assembly to the strut and bears an axial load during braking. The brake rod is laterally damped to dissipate lateral vibrations imparted to the brake rod during braking.
摘要:
A deployment control for an inflatable escape slide for use in a structure such as an aircraft is disclosed wherein the escape slide has an inboard end and an toe end. The inboard end of the slide is suitably attached to an egress on the structure for deployment and extension of the slide by inflation means whereby the slide extends from an elevated egress to a ground support. The slide has inflatable tubes with a slide surface. The inflation means is operative upon actuation to provide pressurized fluids to the tubes which will inflate and distend the tubes into a longitudinally extending escape slide under the control of a restraining control device (or devices). Such device is operative upon pressurization of the tubes to deploy an outboard portion of the slide to which one end of the device is connected to move relative to the inboard end of the slide to which the other end of the device is connected at a controlled rate for a predetermined length of the slide.