公开(公告)号：US07988781B2

公开(公告)日：2011-08-02

申请号：US12034936

申请日：2008-02-21

Applicant: Tsuneo Komiyama ,  Osamu Yamakawa ,  Tetsuhiro Honjo ,  Akito Higuchi

Inventor： Tsuneo Komiyama ,  Osamu Yamakawa ,  Tetsuhiro Honjo ,  Akito Higuchi

IPC: C04B12/04

CPC classification number: C04B28/24 ,  C04B2111/00431 ,  C04B2111/00551 ,  F27D1/0006 ,  C04B14/041 ,  C04B14/042 ,  C04B14/10 ,  C04B14/303 ,  C04B14/324 ,  C04B20/008

Abstract: A non-settling refractory mortar is provided, which includes 100 mass % of a ceramic powder such as cordierite, mullite, alumina, or silicon carbide, 0.5 to 1.5 mass % of a clay mineral, and a colloidal oxide solution, in which the Ca content in the total solid component is defined at 0.01 to 0.5 mass % as converted to oxide so as to be provided with a thixotropic property. As a result, the coating performance is not lowered if stored for a long period after kneading, the dimension change rate after coating is small, and cracks or gaps are not formed on the coat surface. The median diameter of ceramic powder is preferred to be 10 to 50 μm, and in order to reduce the dimension change rate after coating, the content of particles of 0.1 to 5 μm in ceramic powder is desired to be 1 to 20%.

Abstract translation: 提供了一种非沉降的耐火砂浆，其包括100质量％的陶瓷粉末如堇青石，莫来石，氧化铝或碳化硅，0.5至1.5质量％的粘土矿物和胶体氧化物溶液，其中Ca 总固体成分中的含量被定义为0.01〜0.5质量％转化为氧化物，从而具有触变性。 结果，如果在捏合之后长时间储存​​，涂布后的尺寸变化率小，并且在涂层表面上不形成裂缝或间隙，则涂层性能不降低。 陶瓷粉末的中值粒径优选为10〜50μm，为了降低涂布后的尺寸变化率，陶瓷粉末的粒径为0.1〜5μm的粒子的含量优选为1〜20％。

公开(公告)号：US20090149311A1

公开(公告)日：2009-06-11

申请号：US12035082

申请日：2008-02-21

Applicant: Tsuneo Komiyama ,  Osamu Yamakawa ,  Tetsuhiro Honjo ,  Akito Higuchi

Inventor： Tsuneo Komiyama ,  Osamu Yamakawa ,  Tetsuhiro Honjo ,  Akito Higuchi

IPC: C04B35/14 ,  C04B35/01 ,  C04B35/00

CPC classification number: C04B28/24 ,  C04B35/195 ,  C04B35/6263 ,  C04B35/66 ,  C04B2111/00431 ,  C04B2111/32 ,  C04B2111/343 ,  C04B2235/3201 ,  C04B2235/3418 ,  C04B2235/3481 ,  C04B2235/5436 ,  C04B2235/5481 ,  C04B2235/72 ,  C04B2235/96 ,  C04B14/041 ,  C04B20/0076 ,  C04B14/042

Abstract: The invention relates to a Monolithic refractory material used in refractories and refractory ceramic products, and more particularly to a Monolithic refractory material having low expansibility, high strength, and crack extension resistance used for the purpose of repairing, protecting, modifying, filling, and forming the surface, adhesive surface, interface, or joint of low-expansion fire bricks and refractory ceramic products. The Monolithic refractory material of the invention is a Monolithic refractory material prepared by kneading cordierite powder, having a median diameter in a range of 10 to 50 μm, and a sharp mountain-like particle size distribution in which the content of particles smaller than 10 μm is 1% or more to 36% or less, the content of particles ranging from 10 μm or more to 50 μm or less is 50% or more to 75% or less, and the content of particles of 51 μm or more is 1% or more to 14% or less, and a solvent composed of water and alumina sol or silica sol solution.

Abstract translation: 本发明涉及耐火材料和耐火陶瓷制品中使用的整体耐火材料，更具体地说涉及用于修复，保护，改性，填充和成型的具有低膨胀性，高强度和抗裂延伸性的单片耐火材料 低膨胀火砖和耐火陶瓷制品的表面，粘合剂表面，界面或接头。 本发明的整体耐火材料是通过捏合10〜50μm的中值粒径的堇青石粉末和小于10μm的颗粒含量的尖锐的山状粒度分布制备的单片耐火材料 为1％以上至36％以下，粒径在10μm以上至50μm以下的粒子的含量为50％以上至75％以下，51μm以上的粒子的含量为1％ 或更多至14％或更低，以及由水和氧化铝溶胶或硅溶胶溶液组成的溶剂。

公开(公告)号：US20090145334A1

公开(公告)日：2009-06-11

申请号：US12034936

申请日：2008-02-21

Applicant: Tsuneo Komiyama ,  Osamu Yamakawa ,  Tetsuhiro Honjo ,  Akito Higuchi

Inventor： Tsuneo Komiyama ,  Osamu Yamakawa ,  Tetsuhiro Honjo ,  Akito Higuchi

IPC: C04B14/10

CPC classification number: C04B28/24 ,  C04B2111/00431 ,  C04B2111/00551 ,  F27D1/0006 ,  C04B14/041 ,  C04B14/042 ,  C04B14/10 ,  C04B14/303 ,  C04B14/324 ,  C04B20/008

Abstract: The non-settling refractory mortar of the invention contains 100 parts of ceramic powder such as cordierite, mullite, alumina, or silicon carbide, 0.5 to 1.5 parts of clay mineral, and colloidal oxide solution, in which the Ca content in total solid component is defined at 0.01 to 0.5% as converted to oxide so as to be provided with thixotropic property. As a result, the coating performance is not lowered if stored for a long period after kneading, the dimension change rate after coating is small, and cracks or gaps are not formed on the coat surface. The median diameter of ceramic powder is preferred to be 10 to 50 μm, and in order to reduce the dimension change rate after coating, the content of particles of 0.1 to 5 μm in ceramic powder is desired to be 1 to 20%.

Abstract translation: 本发明的非沉降耐火砂浆含有100份陶瓷粉末如堇青石，莫来石，氧化铝或碳化硅，0.5至1.5份粘土矿物和胶体氧化物溶液，其中总固体成分中的Ca含量为 定义为0.01至0.5％，转化为氧化物以提供触变性。 结果，如果在捏合之后长时间储存​​，涂布后的尺寸变化率小，并且在涂层表面上不形成裂缝或间隙，则涂层性能不降低。 陶瓷粉末的中值粒径优选为10〜50μm，为了降低涂布后的尺寸变化率，陶瓷粉末中的0.1〜5μm的粒子的含量优选为1〜20％。

公开(公告)号：US07833923B2

公开(公告)日：2010-11-16

申请号：US12035082

申请日：2008-02-21

Applicant: Tsuneo Komiyama ,  Osamu Yamakawa ,  Tetsuhiro Honjo ,  Akito Higuchi

Inventor： Tsuneo Komiyama ,  Osamu Yamakawa ,  Tetsuhiro Honjo ,  Akito Higuchi

IPC: C04B35/03 ,  C04B35/04 ,  C04B35/00

CPC classification number: C04B28/24 ,  C04B35/195 ,  C04B35/6263 ,  C04B35/66 ,  C04B2111/00431 ,  C04B2111/32 ,  C04B2111/343 ,  C04B2235/3201 ,  C04B2235/3418 ,  C04B2235/3481 ,  C04B2235/5436 ,  C04B2235/5481 ,  C04B2235/72 ,  C04B2235/96 ,  C04B14/041 ,  C04B20/0076 ,  C04B14/042

Abstract: A monolithic refractory material is provided by a method including the steps of kneading cordierite powder having a median diameter in a range of 10 to 50 μm, and having a sharp mountain-like particle size distribution in which the content of particles smaller than 10 μm is 1% or more to 36% or less, the content of particles ranging from 10 μm or more to 50 μm or less is 50% or more to 75% or less, and the content of particles of 51 μm or more is 1% or more to 14% or less, and a solvent including water and alumina sol or silica sol solution.

Abstract translation: 通过包括以下步骤的方法提供整体耐火材料：将中值粒径在10至50μm范围内的堇青石粉末捏合，并且具有尖锐的山形粒度分布，其中小于10μm的颗粒的含量为 1％以上且36％以下，10μm以上且50μm以下的粒子的含量为50％以上且75％以下，51μm以上的粒子的含量为1％以上 多于14％或更少，以及包括水和氧化铝溶胶或硅溶胶溶液的溶剂。

公开(公告)号：US07820278B2

公开(公告)日：2010-10-26

申请号：US12034970

申请日：2008-02-21

Applicant: Tsuneo Komiyama ,  Osamu Yamakawa ,  Tetsuhiro Honjo ,  Akito Higuchi

Inventor： Tsuneo Komiyama ,  Osamu Yamakawa ,  Tetsuhiro Honjo ,  Akito Higuchi

IPC: B32B3/26

CPC classification number: C04B38/0022 ,  C04B28/24 ,  C04B35/195 ,  C04B35/66 ,  C04B2111/00431 ,  C04B2235/3418 ,  C04B2235/3481 ,  C04B2235/349 ,  C04B2235/5208 ,  Y10T428/249979 ,  C04B38/0054 ,  C04B38/0067 ,  C04B14/041 ,  C04B14/10 ,  C04B14/46 ,  C04B14/042

Abstract: A refractory mortar cured material is formed in the surface or joint portions of a ceramic refractory material, such as fire bricks used in the lining of melting furnace or firing furnace used at high temperature, and includes ceramic particles with an inorganic binder having silanol group that are kneaded together with water. The kneaded mortar is applied on the surface of a ceramic base material. The average particle size of ceramic particles in the refractory mortar is 10 to 50 μm, and the difference between the 90% particle size and the 10% particle size is 10 μm or more to 60 μm or less. The average pore size of the refractory mortar cured material is 5 to 25 μm, and the width of pore size distribution is 20 to 80 μm, so that the cracks are suppressed. In addition, the bulk density is 0.9 to 1.5 g/cm3.

Abstract translation: 陶瓷耐火材料的表面或接合部分形成耐火灰浆固化材料，例如在熔化炉衬里或在高温下使用的焙烧炉中使用的火砖，并且包括具有硅烷醇基的无机粘合剂的陶瓷颗粒， 与水一起捏合。 将捏合的砂浆施加在陶瓷基材的表面上。 难熔砂浆中的陶瓷粒子的平均粒径为10〜50μm，90％粒径和10％粒径的差为10μm以上至60μm以下。 难熔灰浆固化物的平均孔径为5〜25μm，孔径分布的宽度为20〜80μm，抑制了裂纹。 此外，堆积密度为0.9〜1.5g / cm 3。

公开(公告)号：US20100025324A1

公开(公告)日：2010-02-04

申请号：US12496952

申请日：2009-07-02

Applicant: Tsuneo Komiyama ,  Akito Higuchi ,  Hiroyuki Hotta

Inventor： Tsuneo Komiyama ,  Akito Higuchi ,  Hiroyuki Hotta

IPC: B01D29/03 ,  B28B1/00

CPC classification number: C22B9/023 ,  Y02P10/234

Abstract: A filtering medium for molten metal which is excellent in inclusion removal performance and durability and further may provide sufficient throughput and a method for producing the same. A filtering medium for molten metal in the present invention includes a two-layered structure of a macropore ceramic layer at the inflow side and a micropore ceramic layer at the outflow side. The average pore diameter of the micropore ceramic layer is from 100 to 500 μm and the average pore diameter of the macropore ceramic layer is 1.1 to 3.0 times as large as that of the micropore ceramic layer. When respective layers are formed of aggregates bonded with an inorganic binder and the inorganic binder has a needle crystal structure with an aspect ratio of 2 to 50, the inside of filtering medium may be contributed to the filtration and the compatibility between inclusion-trapping performance and lifetime may be ensured.

Abstract translation: 包含去除性能和耐久性优异的熔融金属过滤介质，还可以提供足够的通量及其制造方法。 本发明的熔融金属用过滤介质包括流入侧的大孔陶瓷层和流出侧的微孔陶瓷层的两层结构。 微孔陶瓷层的平均孔径为100〜500μm，大孔陶瓷层的平均孔径为微孔陶瓷层的平均孔径的1.1〜3.0倍。 当各层由与无机粘合剂结合的聚集体形成，无机粘合剂具有长宽比为2〜50的针状结晶时，过滤介质的内部可能有助于过滤，并且夹杂性能与 可以确保寿命。

公开(公告)号：US06696130B1

公开(公告)日：2004-02-24

申请号：US09534491

申请日：2000-03-24

Applicant: Yoshiyuki Kasai ,  Takashi Harada ,  Yukinari Shibagaki ,  Akito Higuchi

Inventor： Yoshiyuki Kasai ,  Takashi Harada ,  Yukinari Shibagaki ,  Akito Higuchi

IPC: B32B312

CPC classification number: C04B38/0006 ,  Y10T428/1314 ,  Y10T428/24149 ,  Y10T428/249953 ,  Y10T428/249967 ,  C04B35/195 ,  C04B35/622 ,  C04B38/0054 ,  C04B38/0074

Abstract: A ceramic honeycomb structure has an open frontal area of 50% to 85%, a porosity of 0.1% to 10%, and a proportion of the volume of pores of 1 &mgr;m or larger in diameter, in total pore volume, of 20% or more; a regenerative thermal oxidizer using the ceramic honeycomb structure. The ceramic honeycomb structure has a small porosity and, therefore, has a sufficient heat accumulation capacity and hardly causes floating by gas pressure; has controlled pore diameters and, therefore, hardly shows adsorption of VOC or the like, or rupture; and has controlled contraction and, therefore, has a large GSA.

Abstract translation: 陶瓷蜂窝结构体的开放式前部面积为50％〜85％，孔隙率为0.1％〜10％，总孔体积的1μm以上的孔体积的比例为20％， 更多; 使用陶瓷蜂窝结构的再生式热氧化剂。 陶瓷蜂窝结构体的孔隙率小，因此具有足够的蓄热能力，并且几乎不会由于气体压力而浮动; 具有受控的孔径，因此几乎不显示VOC等的吸附或破裂; 并受到控制收缩，因此具有较大的GSA。

公开(公告)号：US20090169848A1

公开(公告)日：2009-07-02

申请号：US12034970

申请日：2008-02-21

Applicant: Tsuneo Komiyama ,  Osamu Yamakawa ,  Tetsuhiro Honjo ,  Akito Higuchi

Inventor： Tsuneo Komiyama ,  Osamu Yamakawa ,  Tetsuhiro Honjo ,  Akito Higuchi

IPC: B32B3/26

CPC classification number: C04B38/0022 ,  C04B28/24 ,  C04B35/195 ,  C04B35/66 ,  C04B2111/00431 ,  C04B2235/3418 ,  C04B2235/3481 ,  C04B2235/349 ,  C04B2235/5208 ,  Y10T428/249979 ,  C04B38/0054 ,  C04B38/0067 ,  C04B14/041 ,  C04B14/10 ,  C04B14/46 ,  C04B14/042

Abstract: The refractory mortar cured material of the invention formed in the surface or joint portions of a ceramic refractory material such as fire bricks used in the lining of melting furnace or firing furnace used at high temperature is composed by kneading ceramic particles with an inorganic binder having silanol group together with water, and forming the kneaded mortar on the surface of a ceramic base material. The average particle size of ceramic particles in the refractory mortar is 10 to 50 μm, the difference of 90% particle size and 10% particle size is 10 μm or more to 60 μm or less, the average pore size of the refractory mortar cured material is 5 to 25 μm, and the width of pore size distribution is 20 to 80 μm, so that the cracks may be suppressed. More preferably, the bulk density is 0.9 to 1.5 g/cm3.

Abstract translation: 形成于陶瓷耐火材料的表面或接合部分的本发明的耐火灰浆固化材料是通过将陶瓷颗粒与具有硅烷醇的无机粘合剂混合而构成的。 与水一起组合，并在陶瓷基材的表面上形成捏合的砂浆。 耐火砂浆中的陶瓷粒子的平均粒径为10〜50μm，粒径90％，粒径为10％的粒子的平均粒径为10μm〜60μm，耐火灰浆固化物的平均孔径 为5〜25μm，孔径分布的宽度为20〜80μm，可以抑制裂纹。 更优选地，堆积密度为0.9〜1.5g / cm 3。