公开(公告)号：US4424273A

公开(公告)日：1984-01-03

申请号：US378767

申请日：1982-05-17

Applicant: Simone Franco ,  Alberto Valsecchi

Inventor： Simone Franco ,  Alberto Valsecchi

IPC: C08J7/04 ,  G03C1/91 ,  G03C1/93 ,  G03C1/78 ,  B32B27/06 ,  B32B27/36 ,  G03C1/96

CPC classification number: G03C1/93 ,  Y10T428/31797

Abstract: The present invention relates to an improved photographic polyester support base coated with a first hydrophobic subbing layer and a second hydrophilic subbing layer, the improvement consisting of having said second subbing layer derived from a hardener containing, aqueous coating composition including (1) gelatin, (2) a vinyl addition polymer compound and (3) a low viscosity highly sulfonated water soluble polyacetal compound derived from the reaction of an aldehyde sulfonic acid compound with a polyvinyl alcohol compound, the relative quantities of said gelatin and vinyl addition polymer compound to the polyacetal compound being such as to provide good adhesion characteristics without any significant loss in antistatic properties.

Abstract translation: 本发明涉及涂覆有第一疏水性底层和第二亲水底层的改进的照相聚酯支撑体，该改进包括由含有（1）明胶，（ 2）乙烯基加成聚合物化合物和（3）衍生自醛磺酸化合物与聚乙烯醇化合物的反应的低粘度高度磺化的水溶性聚缩醛化合物，所述明胶和乙烯基加成聚合物与聚缩醛的相对量 化合物可以提供良好的粘附特性，而没有任何明显的抗静电性能的损失。

公开(公告)号：US5604083A

公开(公告)日：1997-02-18

申请号：US568732

申请日：1995-12-05

Applicant: Alberto Valsecchi ,  Giorgio Spazzapan ,  Renzo Torterolo ,  Soonkun Kang

Inventor： Alberto Valsecchi ,  Giorgio Spazzapan ,  Renzo Torterolo ,  Soonkun Kang

IPC: B32B7/02 ,  B32B27/32 ,  C08G73/02 ,  C09D137/00 ,  C09D139/04 ,  C09D201/00 ,  C09K3/16 ,  G03C1/89

CPC classification number: G03C1/89 ,  C08G73/0233 ,  C09K3/16 ,  Y10T428/31797 ,  Y10T428/31855 ,  Y10T428/31935

Abstract: The invention is directed to an antistatic polymeric film base comprising a polymeric film having coated on at least one side thereof an antistatic layer comprising the reaction product of (1) a water-soluble, electrically conductive polymer containing carboxylic groups and (2) a water-soluble polymer containing oxazoline groups, and to a photographic element comprising at least one silver halide emulsion layer on said antistatic polymeric film base. This antistatic layer may be present as a backing layer on the side of the film base opposite the silver halide emulsion layer, as a subbing layer between the film base and the emulsion layer in a single or double side coated photographic element, and/or as a subbing layer between the film base and a different backing layer.

Abstract translation: 本发明涉及一种抗静电聚合物膜基底，其包含在其至少一侧上涂覆有聚合物膜的抗静电层，其包含（1）含有羧基的水溶性导电聚合物和（2）水的反应产物 - 含有恶唑啉基的可溶性聚合物，以及在所述抗静电聚合物膜基材上包含至少一个卤化银乳剂层的照相元件。 该抗静电层可以作为背衬层存在于与卤化银乳剂层相对的膜底侧上，作为在单层或双面涂布的照相元件中的膜基底和乳剂层之间的底层，和/或 薄膜基底和不同背衬层之间的底层。

公开(公告)号：US5709985A

公开(公告)日：1998-01-20

申请号：US556471

申请日：1995-11-13

Applicant: Eric D. Morrison ,  Paola Puppo ,  Alberto Valsecchi ,  Elio Martino ,  William L. Kausch ,  Renzo Torterolo

Inventor： Eric D. Morrison ,  Paola Puppo ,  Alberto Valsecchi ,  Elio Martino ,  William L. Kausch ,  Renzo Torterolo

IPC: C08F214/08 ,  C08K3/20 ,  C09D127/08 ,  C09D133/02 ,  C09D133/06 ,  C09D135/00 ,  C09K3/16 ,  G03C1/005 ,  G03C1/053 ,  G03C1/85 ,  G03C1/89

CPC classification number: C09K3/16 ,  G03C1/005 ,  G03C1/053 ,  G03C1/85 ,  G03C1/853 ,  G03C1/89

Abstract: A photographic element comprising a polymeric film base, a silver halide emulsion layer, and an antistatic layer comprising a colloidal vanadium oxide and a vinyl addition polymer dispersion in a dry weight ratio of from 1:30 to 1:500. The antistatic layer may be present as a backing layer on the side of the base opposite the silver halide emulsion layer, as a subbing layer between the base and the emulsion layer in a single or double side coated photographic element, and/or as a subbing layer between the base and a different backing layer. No barrier layer is used over the antistatic layer.

公开(公告)号：US4582782A

公开(公告)日：1986-04-15

申请号：US618876

申请日：1984-06-08

Applicant: Alberto Valsecchi

Inventor： Alberto Valsecchi

IPC: B32B27/08 ,  B32B27/00 ,  C08J7/04 ,  C09D5/00 ,  C09K3/16 ,  G03C1/85 ,  G03C1/89 ,  G03C1/94

CPC classification number: G03C1/89 ,  Y10T428/31511 ,  Y10T428/31663 ,  Y10T428/31971

Abstract: A photographic base is protected against the adverse effects resulting from the accumulation of static electrical charges by providing it with a first antistatic hydrophilic layer and a second protective hydrophobic layer coated onto said first layer, said first layer having been formed by coating onto said base a liquid coating composition comprising a hydrophilic non-diffusing sulfonated polymer in the presence of an epoxy-silane compound. The antistatic base is particularly useful for photographic elements comprising at least one photosensitive image-forming layer, on one side thereof, and the first antistatic layer and the second protective layer on the opposite side thereof. The antistatic layer is durable, abrasion-resistant, non-tacky and can withstand the aqueous photographic processings without adverse effects.

Abstract translation: 通过提供照相底座来防止由于静电荷的积累而产生的不利影响，其中提供了第一抗静电亲水层和涂覆在所述第一层上的第二保护性疏水层，所述第一层通过涂覆在所述基底上形成 在环氧硅烷化合物存在下包含亲水性非扩散磺化聚合物的液体涂料组合物。 抗静电基底特别适用于包含至少一个光敏图像形成层的照相元件，其一侧，以及其相对侧上的第一抗静电层和第二保护层。 抗静电层耐用，耐磨，不粘，可承受水性摄影处理，无不良影响。

公开(公告)号：US4262088A

公开(公告)日：1981-04-14

申请号：US77192

申请日：1979-09-20

Applicant: Angelo Vallarino ,  Alberto Valsecchi

Inventor： Angelo Vallarino ,  Alberto Valsecchi

IPC: G03C1/835 ,  G03C1/84

CPC classification number: G03C1/835

Abstract: A photographic material containing a removable antihalo layer comprising an antihalo agent and a mixture of two copolymers of a low alkymethacrylate and acrylic or methacrylic acid.

Abstract translation: 包含可除去的抗卤素层的照相材料，其包含抗卤代剂和低甲基丙烯酸甲酯和丙烯酸或甲基丙烯酸的两种共聚物的混合物。

公开(公告)号：US06348305B2

公开(公告)日：2002-02-19

申请号：US09770011

申请日：2001-01-25

Applicant: Paola Puppo ,  Alberto Valsecchi ,  Carlo Barlocco

Inventor： Paola Puppo ,  Alberto Valsecchi ,  Carlo Barlocco

IPC: G03C193

CPC classification number: G03C1/93 ,  Y10T428/31536 ,  Y10T428/31551 ,  Y10T428/31562 ,  Y10T428/31565 ,  Y10T428/31598

Abstract: A photographic element comprising a film support base, an adhesion promoting layer, a subbing layer and at least one light-sensitive silver halide emulsion layer, wherein the adhesion promoting layer is close to the support and contains a silane compound and a polyurethane, and the subbing layer, selected within the group consisting of a hydrophilic colloidal layer or a layer comprising a continuous gelled network of inorganic particles, is positioned between the adhesion promoting layer and the emulsion layer. The present invention also refers to a photographic element comprising a film support base having coated on one side thereof at least one light-sensitive silver halide emulsion layer and on the opposite side thereof an adhesion promoting layer and at least one auxiliary layer, wherein the adhesion promoting layer is close to the support and contains a silane compound and a polyurethane. The present invention further refers to a film support base having coated on at least one side thereof an adhesion promoting layer and a subbing layer, wherein the adhesion promoting layer is close to the support and contains a silane compound and a polyurethane and the subbing layer is selected within the group consisting of a hydrophilic colloidal layer or a layer comprising a continuous gelled network of inorganic particles. Finally, the present invention also refers to a film support base having coated on one side thereof an adhesion promoting layer and at least an auxiliary layer, wherein the adhesion promoting layer is close to the support and contains a silane compound and a polyurethane binder and the auxiliary layer is an antistatic layer, a magnetic layer, a protective layer or a lubricant layer. The adhesion of the emulsion layers and/or of the auxiliary layers to the support base is improved both under wet and dry conditions.

Abstract translation: 一种照相元件，包括膜支撑基底，粘附促进层，底层和至少一个感光卤化银乳剂层，其中粘附促进层靠近载体并含有硅烷化合物和聚氨酯， 在由亲水性胶体层组成的组中选择的底层，或包含无机颗粒的连续凝胶网络的层位于粘附促进层和乳剂层之间。本发明还涉及一种照相元件，其包含膜载体 在其一面上涂覆有至少一个感光卤化银乳剂层，并且在其相对侧上具有粘合促进层和至少一个辅助层，其中所述粘附促进层靠近所述载体并含有硅烷化合物和 聚氨酯。本发明还涉及一种涂覆在至少一面上的膜支撑基底 其中粘合促进层和底层，其中粘附促进层靠近载体并含有硅烷化合物和聚氨酯，并且底层选自亲水胶体层或包含连续凝胶层 最后，本发明还涉及一种在其一面上具有粘附促进层和至少一层辅助层的薄膜支撑基底，其中粘附促进层靠近载体并含有硅烷化合物和 聚氨酯粘合剂和辅助层是抗静电层，磁性层，保护层或润滑剂层。在湿和干燥条件下，乳液层和/或辅助层对支撑基底的粘附性得到改善。

公开(公告)号：US06261752B1

公开(公告)日：2001-07-17

申请号：US09482674

申请日：2000-01-13

Applicant: Paola Puppo ,  Alberto Valsecchi ,  Carlo Barlocco ,  Luisa Tavella

Inventor： Paola Puppo ,  Alberto Valsecchi ,  Carlo Barlocco ,  Luisa Tavella

IPC: G03C1835

CPC classification number: G03C1/825 ,  A61K9/2866 ,  C11D3/226 ,  C11D17/0039

Abstract: One object of the present invention is to provide a mixture composed of 1) a cellulose ether derivative esterified at least with a biprotic acid group derivative expressed by the formula HOOC—B—COOH (I), wherein B is a linear aliphatic group represented by (CH2)x with x a positive integer from 1 to 5 or is a 5-member or 6-member cycloaliphatic group and 2) a cellulose or cellulose derivative esterified at least with a phthalic acid derivative represented by the following formula (II). wherein R1 is an all group and y is a positive integer from 0 to 3. Said mixture shows an enhanced stability against hydrolysis when subjected to conditioning at high relative humidity and temperature. The composition may be useful in order to get antihalation layer on photographic films as well as enteric coating of pharmaceutical dosage and for controlled-release applications such as for cleaning formulation.

Abstract translation: 本发明的一个目的是提供一种由以下物质组成的混合物：1）至少与由式HOOC-B-COOH（I）表示的双相酸基衍生物酯化的纤维素醚衍生物，其中B是由 （CH 2）x，xa为1〜5的正整数，或为5元环或6元环脂肪基，2）至少与下式（II）表示的邻苯二甲酸衍生物酯化的纤维素或纤维素衍生物。 R1是全部组，y是0至3的正整数。当在高相对湿度和温度下进行调理时，所述混合物显示出增强的抗水解稳定性。组合物可用于在照相胶片上获得防晕层 以及用于药物剂量和控制释放应用的肠溶衣，例如用于清洁制剂。

公开(公告)号：US5914222A

公开(公告)日：1999-06-22

申请号：US936125

申请日：1997-09-24

Applicant: Eric D. Morrison ,  Paola Puppo ,  Alberto Valsecchi ,  Elio Martino ,  William L. Kausch ,  Renzo Torterolo

Inventor： Eric D. Morrison ,  Paola Puppo ,  Alberto Valsecchi ,  Elio Martino ,  William L. Kausch ,  Renzo Torterolo

IPC: C08F214/08 ,  C08K3/20 ,  C09D127/08 ,  C09D133/02 ,  C09D133/06 ,  C09D135/00 ,  C09K3/16 ,  G03C1/005 ,  G03C1/053 ,  G03C1/85 ,  G03C1/89

CPC classification number: C09K3/16 ,  G03C1/005 ,  G03C1/053 ,  G03C1/85 ,  G03C1/853 ,  G03C1/89

Abstract: A photographic element comprising a polymeric film base, a silver halide emulsion layer, and an antistatic layer comprising a colloidal vanadium oxide and a vinyl addition polymer dispersion in a dry weight ratio of from 1:30 to 1:500. The antistatic layer may be present as a backing layer on the side of the base opposite the silver halide emulsion layer, as a subbing layer between the base and the emulsion layer in a single or double side coated photographic element, and/or as a subbing layer between the base and a different backing layer. No barrier layer is used over the antistatic layer.

Abstract translation: 包含聚合物膜基材，卤化银乳剂层和包含胶体氧化钒和乙烯基加成聚合物分散体的干燥重量比为1:30至1:500的抗静电层的照相元件。 抗静电层可以作为背衬层存在于与卤化银乳剂层相对的一侧上，作为在单面或双面涂布的照相元件中的基底和乳剂层之间的底层，和/或作为底层 基底和不同背衬层之间的层。 在抗静电层上不使用阻隔层。

公开(公告)号：US5484693A

公开(公告)日：1996-01-16

申请号：US116515

申请日：1993-09-07

Applicant: Alberto Valsecchi ,  Omar Farooq

Inventor： Alberto Valsecchi ,  Omar Farooq

IPC: G03C1/89 ,  G03C1/85

CPC classification number: G03C1/89

Abstract: Polymeric film bases at least one side of which is coated with an antistatic layer comprising the reaction product of (a) a water-soluble, electrically conductive polymer containing carboxylic groups and (b) a polyfunctional epoxide crosslinking agent, and photographic elements comprising said film bases, wherein said conductive polymer is a copolymer of a water soluble salt of styrene sulfonic acid and maleic acid having a weight average molecular weight of 100,000 to 350,000 and a water soluble salt of styrene sulfonic acid to maleic acid molar ratio of at least 2:1 up to 9:1.

Abstract translation: 聚合物膜基底的至少一侧涂覆有抗静电层，其包含（a）含有羧基的水溶性导电聚合物和（b）多官能环氧化物交联剂的反应产物，以及包含所述膜的照相元件 碱，其中所述导电聚合物是苯乙烯磺酸的水溶性盐和重均分子量为100,000至350,000的马来酸和苯乙烯磺酸的水溶性盐与马来酸的摩尔比至少为2:1的共聚物， 1到9：1。

公开(公告)号：US4914018A

公开(公告)日：1990-04-03

申请号：US278358

申请日：1988-12-01

Applicant: Mauro Besio ,  Alberto Valsecchi

Inventor： Mauro Besio ,  Alberto Valsecchi

IPC: G03C1/89

CPC classification number: G03C1/89 ,  Y10S430/162 ,  Y10T428/31884 ,  Y10T428/31986

Abstract: An improved antistatic base comprises a polymeric support film having coated thereon in sequence a first antistatic layer comprising a quaternary polyelectrolyte compound and a polymeric hydrophobic binder and a second protective layer comprising a polymeric hydrophobic binder, wherein said quaternary polyelectrolyte compound is a homopolymer or a copolymer of a diallyldialkylammonium salt compound.The antistatic base is particularly useful as a support for light-sensitive silver halide photographic elements.