ADDITIVE FOR MAXIMIZING LIGHT OLEFINS IN FCC AND PROCESS FOR PREPARATION THEREOF
    3.
    发明申请
    ADDITIVE FOR MAXIMIZING LIGHT OLEFINS IN FCC AND PROCESS FOR PREPARATION THEREOF 审中-公开
    用于最大化FCC中的轻油的添加剂及其制备方法

    公开(公告)号:US20090099006A1

    公开(公告)日:2009-04-16

    申请号:US12249444

    申请日:2008-10-10

    IPC分类号: B01J29/06 B01J29/04 B01J29/40

    摘要: The present, invention relates to a process for the production of additives for catalysts for fluid catalytic cracking (FCC) based on zeolite that is selective for light olefins, with the aim of increasing the yields, in FCC units, of liquefied petroleum gas (LPG) and light olefins, of high added value, among others propene and isobutene. This invention provides a method of preparation of catalytic compositions, starting from zeolite modified with phosphate and alkaline-earth metal, that leads to the production of an additive with better performance than the additives, of similar compositions, obtained by other methods of the prior art. The process can be regarded as a development in relation to other processes, as it promotes interaction between the zeolite that is selective for light olefins and its activator, reagent “X”. For this, a separate stage is used during the sequence of stages in the preparation. Moreover, the zeolite does not undergo additional treatments such as filtration, washing or calcination after the treatment with its activator.This additive can be obtained starting from any commercial zeolite that is selective for light olefins, such as zeolite of type ZSM-5.

    摘要翻译: 本发明涉及一种基于对轻质烯烃选择性的沸石生产用于流化催化裂化催化剂的催化剂(FCC)的方法,其目的是提高FCC单元中液化石油气(LPG)的产率 )和轻质烯烃,具有高附加值的丙烯和异丁烯。 本发明提供了一种由磷酸盐和碱土金属改性的沸石开始的催化组合物的制备方法,其通过现有技术的其它方法获得的相似成分的添加剂的性能优于添加剂 。 该方法可以被认为是与其它方法相关的发展,因为它促进了对轻质烯烃选择性的沸石与其活化剂“X”之间的相互作用。 为此,在制备阶段的序列中使用单独的阶段。 此外,沸石在用其活化剂处理后不进行过滤,洗涤或煅烧等附加处理。 该添加剂可以从对轻质烯烃选择性的任何商业沸石如ZSM-5型沸石开始获得。

    Molecular sieves of faujasite structure
    4.
    发明授权
    Molecular sieves of faujasite structure 失效
    八面沸石结构分子筛

    公开(公告)号:US06756029B2

    公开(公告)日:2004-06-29

    申请号:US10164926

    申请日:2002-06-07

    IPC分类号: C01B3924

    摘要: A process for preparing molecular sieves of type Y faujasite structure is described, as well as pre-shaped bodies of faujasite structure type Y molecular sieves. The process comprises preparing a precursor gel from a source of silica-alumina or a source of alumina and a source of silica with a template agent at a SiO2/Al2O3 greater than 7 and suitable for forming a type Y zeolite, drying the precursor gel and contacting the dried precursor gel with steam, optionally followed by caustic washing, without the formation of crystalline phases other than type Y zeolite being observed. Advantageously, the pre-shaped bodies prepared with the precursor gel of Y zeolite, when subjected to the process of the invention, will have their outer surface covered by type Y zeolite crystals. The molecular sieves so obtained may be employed as catalysts or adsorbents in various processes of the chemical or oil industry.

    摘要翻译: 描述了制备Y型八面沸石结构的分子筛的方法,以及Y型分子筛的八面沸石结构体的预制体。 该方法包括从二氧化硅 - 氧化铝源或氧化铝源和二氧化硅源以二氧化硅/ Al 2 O 3大于7的模板剂制备前体凝胶并适于形成Y型沸石,干燥前体凝胶和 使干燥的前体凝胶与蒸汽接触,任选地随后进行苛性碱洗涤,而不形成除Y型沸石以外的结晶相。 有利的是,当用Y沸石的前体凝胶制备的预制体在进行本发明的方法时,其外表面将被Y型沸石晶体覆盖。 如此获得的分子筛可用作化学或石油工业的各种方法中的催化剂或吸附剂。