摘要:
According to the invention, polyaddition products containing imide groups are manufactured by reacting certain polyimides (preferably maleimides) with polycarboxylic acids in the presence of basic compounds. The preferred embodiment (C) relates to the use of catalysts as basic compounds. In particular, tertiary amines, secondary amines or mixed tertiary-secondary amines can be used. A further embodiment (D) relates to the use of primary polyamines as basic compounds. In the latter case, the polyamine participates in the polyaddition mechanism, that is to say the molecules are incorporated into the polyaddition products. In this latter case, catalysts can also be used additionally.The invention can be utilized particularly in the fields of surface protection, the electrical industry, laminating processes, and the manufacture of foamed plastics, and in the building industry.
摘要:
According to the invention, polyaddition products containing imide groups are manufactured by reacting certain polyimides (preferably maleimides) with polyhydric phenols in the presence of basic compounds. The preferred embodiment (A) relates to the use of catalysts as basic compounds. In particular, tertiary, secondary or mixed tertiary-secondary amines can be used. A further embodiment (B) relates to the use of primary polyamines as basic compounds. In the latter case, the polyamine participates in the polyaddition mechanism, that is to say the molecules are incorporated into the polyaddition products. In this latter case, catalysts can also be used additionally.The invention can be utilized particularly in the fields of surface protection, the electrical industry, laminating processes and the manufacture of foamed plastics, and in the building industry.
摘要:
A polymerizable composition comprises a mixture of(A) a substance having at least one allyl- or methallyl-substituted bicyclo[2.2.1]-hept-5-ene-2,3-dicarboxylic acid imide residue, and(B) a substance having at least one polymerizable residue of formulaCH.sub.2 =C(R.sup.1)COO-- I where R.sup.1 denotes a hydrogen atom or a methyl group.Typically, (A) is bis[4-(allylbicyclo[2.2.1]hept-5-ene-2,3-dicarboximidophenyl)]methane and (B) is an acrylate or methacrylate of a polyhydric alcohol. The compositions can be photopolymerized or heat-cured. They are suitable for use in prepreg manufacture and in image formation.
摘要:
Polyglycidyl ethers which are obtainable by reacting acetophenone with 0.7 to 1.4 mol of formaldehyde per mol of acetophenone, in the presence of an alkaline catalyst and in the temperature range from 50.degree. to 100.degree. C., to a carbonylated acetophenone/formaldehyde resin, hydrogenating said carbonylated resin to a modified hydroxylated acetophenone/formaldehyde resin, subsequently converting said resin with epichlorohydrin, in the presence of a phase transfer catalyst, into the corresponding polychlorohydrin ether, and dehydrochlorinating said ether with a base, are suitable for use as epoxy resins, for example for the preparation of powder coating compositions having good resistance to chemicals and good adhesion.
摘要:
Compounds of formula ##STR1## wherein E and R' are each independently of the other a hydrogen atom or a methyl group,X is ##STR2## and R is --C.sub.m H.sub.2m --, in which m is 2 to 20, --C.sub.n H.sub.2n O--, in which n is 2 to 6, m- or p-phenylene, m- or p-oxyphenylene, in which the oxygen atom is attached to the group X, or X is ##STR3## and R is m- or p-phenylene, or X is ##STR4## and R is --(CH.sub.2 CH.sub.2 O).sub.q --, --(CH.sub.2 CH.sub.2 CH.sub.2 O).sub.q -- or --[CH.sub.2 CH(CH.sub.3)O].sub.q --, in which q is 1 to 6, m- or p-oxyphenylene, in which the oxygen atom is attached to the group X, or X is ##STR5## and R is --C.sub.r H.sub.2r --, in which r is 2 to 4, or m- or p-phenylene,are suitable for the preparation of crosslinked polymers.
摘要:
Heat-curable mixtures comprising(a) 10-90% by weight of at least one compound of formula I ##STR1## (b) 90-10% by weight of at least one compound of formula II ##STR2## and, based on the sum of (a)+(b), (c) 0-30% by weight of at least one compound which is able to react with component (b),in which formulae above n, m, R, R', R.sub.1, R.sub.2 and R.sub.3 are as defined in claim 1, are suitable for the preparation of moulded articles such as prepregs and composites, coatings and bonds.
摘要翻译:(a)10-90重量%的至少一种式I化合物(I)(b)90-10重量%的至少一种式II化合物(II) ),并且基于(a)+(b),(c)0-30重量%的至少一种能够与组分(b)反应的化合物的总和,其中在n,m,R R 1,R 2,R 2和R 3如权利要求1中所定义,适用于制备模塑制品,如预浸料和复合材料,涂料和粘合剂。
摘要:
Crosslinked polymers which can be obtained by heating imides of the formula I ##STR1## in which E is allyl or methallyl, G is hydrogen or methyl, R is hydrogen, alkyl, alkenyl, cycloalkyl, aryl, benzyl, alkylene or arylene and n is 1 or 2, in the presence of a catalyst suitable for cationic polymerization. The use of the catalyst makes it possible to carry out curing at relatively low temperatures and within short reaction times. The polymers can be used, in particular, for the preparation of heat-resistant composite materials and they can also be used as electrical insulating materials and whirl-sintered powder paints.
摘要:
A coating composition for paper is provided, which composition consists of an aqueous preparation containing at least a polymeric binder, an inorganic pigment, and a water-insoluble urea-formaldehyde polycondensation product from 1 mole of urea and 1.3 to 2 moles, of formaldehyde, which product is in a highly dispersed form and has a mean particle diameter of 3 to 6 microns, and a specific BET surface urea of 3 to 12 m.sup.2 /g.Papers coated with these compositions exhibit, in addition to an enhanced degree of whiteness and equally good gloss and improved opacity and smoothness, above all better printability.
摘要:
According to the invention, polyaddition products containing imide groups are manufactured by reacting certain polyimides (preferably maleimides) with polyhydric alcohols in the presence of basic compounds. The preferred embodiment (E) relates to the use of catalysts as basic compounds. In particular, amines and alkali metal compounds can be used. A further embodiment (F) relates to the use of primary polyamines as basic compounds. In the latter case, the polyamine participates in the polyaddition mechanism, that is to say the molecules are incorporated into the polyaddition products. In this latter case, catalysts can also be used additionally.
摘要:
A device for ventilating and cooling the interior of a vehicle with at least one air guide channel (7) having air inlet openings (8) located in the rear of a solar cell equipped vehicle roof (5a, 5b), the air guide channel (7) being restricted to the rear area (3) of the vehicle roof (5a, 5b) and having at least one fan (15) for taking in outside air (10) and at least one cooling element (14) for cooling the air taken in. The bottom of the air guide channel (7) is formed by a first section (12) of a roof portion (5b) which extends from the vehicle rear toward the vehicle front (3, 1) and the top of the air guide channel (7) is formed by a second section (13) of a roof portion (5a) which extends from the vehicle front toward the vehicle rear (1, 3).