公开(公告)号：US07594995B2

公开(公告)日：2009-09-29

申请号：US12313135

申请日：2008-11-17

申请人： Baojian Shen ,  Jinsen Gao ,  Chunming Xu ,  Liang Zhao ,  Xianfeng Li ,  Pei Wu

发明人： Baojian Shen ,  Jinsen Gao ,  Chunming Xu ,  Liang Zhao ,  Xianfeng Li ,  Pei Wu

IPC分类号： C10G47/04 ,  C10G11/02 ,  C10G11/05

CPC分类号： B01J29/80 ,  B01J29/005 ,  B01J29/049 ,  B01J29/084 ,  B01J29/166 ,  B01J29/40 ,  B01J29/48 ,  B01J29/7007 ,  B01J29/7815 ,  B01J37/0009 ,  B01J2229/18 ,  B01J2229/20 ,  B01J2229/42 ,  C10G11/05 ,  C10G11/18 ,  C10G2300/1074 ,  C10G2300/301 ,  C10G2300/708 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/20

摘要： The present invention provides a catalyst and a process for its preparation and its use in cracking heavy feedstocks. The catalyst comprises one or more zeolites having a controlled silica to alumina ratio and preferably treated with alkali in the presence of a matrix component selected from the group consisting of clays, synthetic matrix other than pillared clay, and mixtures thereof. The catalyst are particularly useful in treating heavy feedstock such as residues from oil sands processing.

公开(公告)号：US20130149235A1

公开(公告)日：2013-06-13

申请号：US13713490

申请日：2012-12-13

申请人： Baojian Shen ,  Jing Li ,  Xiaohua Wang ,  Wencheng Zhang ,  Qiaoxia Guo ,  Bojun Shen ,  Bing Feng ,  Guangming Wen ,  Zhihua Zhang ,  Ran Tian

发明人： Baojian Shen ,  Jing Li ,  Xiaohua Wang ,  Wencheng Zhang ,  Qiaoxia Guo ,  Bojun Shen ,  Bing Feng ,  Guangming Wen ,  Zhihua Zhang ,  Ran Tian

IPC分类号： B01J32/00

CPC分类号： C01B39/085 ,  B01J29/89 ,  B01J32/00 ,  B01J35/002

摘要： The present invention relates to a synthesis method for ETS-10 titanosilicate molecular sieves. The method comprises the steps of mixing a titanium oxide hydrosol, a silicon source, a sodium hydroxide, a fluorine-containing mineralizer and a water to give a gel and adjusting the pH thereof to 10.4 to 10.8; and hydrothermal crystallizing the gel at 170 to 250° C. for 10 to 100 hours to obtain the ETS-10 titanosilicate molecular sieves. In the synthesis method for ETS-10 titanosilicate molecular sieves provided by the present invention, a titanium oxide hydrosol is used as the titanium source to synthesize the ETS-10 titanosilicate molecular sieves, and the problem that conventional soluble titanium salt-based titanium sources tend to hydrolyze and the problem of poor dispersibility for the titanium source system of insoluble titanium oxide are therefore prevented. The ETS-10 titanosilicate molecular sieves synthesized has high purity and high crystallinity.

摘要翻译： 本发明涉及一种用于ETS-10钛硅酸盐分子筛的合成方法。 该方法包括以下步骤：将氧化钛水溶胶，硅源，氢氧化钠，含氟矿化剂和水混合，得到凝胶并将其pH调节至10.4至10.8; 并将该凝胶在170〜250℃水热结晶10〜100小时，得到ETS-10钛硅酸盐分子筛。 在本发明提供的ETS-10钛硅酸盐分子筛的合成方法中，使用钛氧化物水溶胶作为钛源来合成ETS-10钛硅酸盐分子筛，以及常规可溶性钛盐基钛源倾向于 从而可以防止水解不溶性氧化钛的钛源体系的分散性差的问题。 合成的ETS-10钛硅酸盐分子筛具有高纯度和高结晶度。

公开(公告)号：US07459413B2

公开(公告)日：2008-12-02

申请号：US11709115

申请日：2007-02-21

申请人： Baojian Shen ,  Jinsen Gao ,  Chunming Xu ,  Liang Zhao ,  Xianfeng Li ,  Pei Wu

发明人： Baojian Shen ,  Jinsen Gao ,  Chunming Xu ,  Liang Zhao ,  Xianfeng Li ,  Pei Wu

IPC分类号： B01J29/06

CPC分类号： B01J29/80 ,  B01J29/005 ,  B01J29/049 ,  B01J29/084 ,  B01J29/166 ,  B01J29/40 ,  B01J29/48 ,  B01J29/7007 ,  B01J29/7815 ,  B01J37/0009 ,  B01J2229/18 ,  B01J2229/20 ,  B01J2229/42 ,  C10G11/05 ,  C10G11/18 ,  C10G2300/1074 ,  C10G2300/301 ,  C10G2300/708 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/20

摘要： The present invention provides a catalyst and a process for its preparation and its use in cracking heavy feedstocks. The catalyst comprises one or more zeolites having a controlled silica to alumina ratio and preferably treated with alkali in the presence of a matrix component selected from the group consisting of clays, synthetic matrix other than pillared clay, and mixtures thereof. The catalyst are particularly useful in treating heavy feedstock such as residues from oil sands processing.

摘要翻译： 本发明提供催化剂及其制备方法及其在重质原料裂解中的应用。 催化剂包含一种或多种具有受控的二氧化硅与氧化铝比的沸石，并且优选在碱存在下用碱处理，所述基体组分选自粘土，除柱状粘土以外的合成基质及其混合物。 该催化剂特别可用于处理重质原料如油砂处理中的残留物。

公开(公告)号：US20070209969A1

公开(公告)日：2007-09-13

申请号：US11709115

申请日：2007-02-21

申请人： Baojian Shen ,  Jinsen Gao ,  Chunming Xu ,  Liang Zhao ,  Xianfeng Li ,  Pei Wu

发明人： Baojian Shen ,  Jinsen Gao ,  Chunming Xu ,  Liang Zhao ,  Xianfeng Li ,  Pei Wu

IPC分类号： B01J29/06 ,  C10G35/00

CPC分类号： B01J29/80 ,  B01J29/005 ,  B01J29/049 ,  B01J29/084 ,  B01J29/166 ,  B01J29/40 ,  B01J29/48 ,  B01J29/7007 ,  B01J29/7815 ,  B01J37/0009 ,  B01J2229/18 ,  B01J2229/20 ,  B01J2229/42 ,  C10G11/05 ,  C10G11/18 ,  C10G2300/1074 ,  C10G2300/301 ,  C10G2300/708 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/20

摘要： The present invention provides a catalyst and a process for its preparation and its use in cracking heavy feedstocks. The catalyst comprises one or more zeolites having a controlled silica to alumina ratio and preferably treated with alkali in the presence of a matrix component selected from the group consisting of clays, synthetic matrix other than pillared clay, and mixtures thereof. The catalyst are particularly useful in treating heavy feedstock such as residues from oil sands processing.

摘要翻译： 本发明提供催化剂及其制备方法及其在重质原料裂解中的应用。 催化剂包含一种或多种具有受控的二氧化硅与氧化铝比的沸石，并且优选在碱存在下用碱处理，所述基体组分选自粘土，除柱状粘土以外的合成基质及其混合物。 该催化剂特别可用于处理重质原料如油砂处理中的残留物。

公开(公告)号：US06723228B2

公开(公告)日：2004-04-20

申请号：US10459278

申请日：2003-06-11

申请人： Shuqin Su ,  Guoliang Wang ,  Haiqing Guo ,  Xianliang Deng ,  Longyan Wang ,  Wenyi Qi ,  Shufang Liu ,  Baojian Shen ,  Jinlong Liu ,  Dongming Zhao

发明人： Shuqin Su ,  Guoliang Wang ,  Haiqing Guo ,  Xianliang Deng ,  Longyan Wang ,  Wenyi Qi ,  Shufang Liu ,  Baojian Shen ,  Jinlong Liu ,  Dongming Zhao

IPC分类号： C10G1100

CPC分类号： B01J29/088 ,  B01J29/166 ,  C10G11/02 ,  C10G11/04 ,  C10G11/05 ,  C10G11/18 ,  C10G47/04 ,  C10G47/30

摘要： An additive used in catalytic cracking of hydrocarbons, which is in the form of homogeneous liquid and comprises a composite metal compound, wherein said composite metal compound consists of the oxides, hydroxides, organic acid salts, inorganic acid salts or metal organic complex compounds of at least one of the 1st group metals and at least one of the 2nd group metals, wherein the 1st group metals are selected from the group consisting of the metals of the IIIA, IVA, VA, VIA groups of the Element Period Table, boron, silicon, phosphorous and tellurium; wherein the 2nd group metals are selected from the group consisting of alkali-earth metals, transition metals, and rare earth metals, is disclosed. A process of catalytic cracking of hydrocarbons, utilizing the additive is also disclosed. The additive can passivate metals and promote the oxidation of CO, and is operated easily with production cost decreased.

摘要翻译： 用于烃类催化裂化的添加剂，其为均匀液体的形式并且包含复合金属化合物，其中所述复合金属化合物由以下物质的氧化物，氢氧化物，有机酸盐，无机酸盐或金属有机络合物组成： 第1族金属中的至少一种和第2族金属中的至少一种，其中第1族金属选自IIIA，IVA，VA，VIA族的金属 元素周期表，硼，硅，磷和碲; 其中第二组金属选自碱土金属，过渡金属和稀土金属。 还公开了利用添加剂的烃的催化裂化过程。 添加剂可以钝化金属，促进CO的氧化，易于生产成本降低。

公开(公告)号：US20090101543A1

公开(公告)日：2009-04-23

申请号：US12313135

申请日：2008-11-17

申请人： Baojian Shen ,  Jinsen Gao ,  Chunming Xu ,  Liang Zhao ,  Xianfeng Li ,  Pei Wu

发明人： Baojian Shen ,  Jinsen Gao ,  Chunming Xu ,  Liang Zhao ,  Xianfeng Li ,  Pei Wu

IPC分类号： C10G11/05

CPC分类号： B01J29/80 ,  B01J29/005 ,  B01J29/049 ,  B01J29/084 ,  B01J29/166 ,  B01J29/40 ,  B01J29/48 ,  B01J29/7007 ,  B01J29/7815 ,  B01J37/0009 ,  B01J2229/18 ,  B01J2229/20 ,  B01J2229/42 ,  C10G11/05 ,  C10G11/18 ,  C10G2300/1074 ,  C10G2300/301 ,  C10G2300/708 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/20

摘要： The present invention provides a catalyst and a process for its preparation and its use in cracking heavy feedstocks. The catalyst comprises one or more zeolites having a controlled silica to alumina ratio and preferably treated with alkali in the presence of a matrix component selected from the group consisting of clays, synthetic matrix other than pillared clay, and mixtures thereof. The catalyst are particularly useful in treating heavy feedstock such as residues from oil sands processing.

摘要翻译： 本发明提供催化剂及其制备方法及其在重质原料裂解中的应用。 催化剂包含一种或多种具有受控的二氧化硅与氧化铝比的沸石，并且优选在碱存在下用碱处理，所述基体组分选自粘土，除柱状粘土以外的合成基质及其混合物。 该催化剂特别可用于处理重质原料如油砂处理中的残留物。