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    Carbon-Coated Li-Containing Powders and Process for Production Thereof
    3.
    发明申请
    Carbon-Coated Li-Containing Powders and Process for Production Thereof 有权
    含碳酸钙的粉末及其生产工艺

    公开(公告)号：US20110212365A1

    公开(公告)日：2011-09-01

    申请号：US13042653

    申请日：2011-03-08

    申请人： Albane AUDEMER ,  Calin WURM ,  Mathieu MORCRETTE ,  Sylvain GWIZDALA ,  Christian MASQUELIER

    发明人： Albane AUDEMER ,  Calin WURM ,  Mathieu MORCRETTE ,  Sylvain GWIZDALA ,  Christian MASQUELIER

    IPC分类号： H01M4/583 ,  B05D5/12

    CPC分类号： H01M4/5825 ,  C01B25/37 ,  C01B25/375 ,  C01B25/45 ,  H01M4/131 ,  H01M4/1391 ,  H01M4/36 ,  H01M4/366 ,  H01M4/62 ,  H01M4/624 ,  H01M4/625 ,  H01M6/185 ,  H01M10/052 ,  H01M10/0562 ,  H01M2004/021 ,  H01M2004/028

    摘要： The invention provides a new route for the synthesis of carbon-coated powders having the olivine or NASICON structure, which form promising classes of active products for the manufacture of rechargeable lithium batteries. Carbon-coating of the powder particles is necessary to achieve good performances because of the rather poor electronic conductivity of said structures. For the preparation of coated LiFePO4, sources of Li, Fe and phosphate are dissolved in an aqueous solution together with a polycarboxylic acid and a polyhydric alcohol. Upon water evaporation, polyesterification occurs while a mixed precipitate is formed containing Li, Fe and phosphate. The resin-encapsulated mixture is then heat treated at 700° C. in a reducing atmosphere. This results in the production of a fine powder consisting of an olivine LiFePO4 phase, coated with conductive carbon. When this powder is used as active material in a lithium insertion-type electrode, fast charge and discharge rates are obtained at room temperature and an excellent capacity retention is observed.

    摘要翻译： 本发明提供了一种用于合成具有橄榄石或NASICON结构的碳涂覆粉末的新途径，其形成用于制造可再充电锂电池的有希望的活性产品类别。 由于所述结构的电子导电性差，所以粉末颗粒的碳涂层是必需的，以获得良好的性能。 为了制备涂覆的LiFePO 4，将Li，Fe和磷酸盐源与多元羧酸和多元醇一起溶解在水溶液中。 当水蒸发时，在形成含有Li，Fe和磷酸盐的混合沉淀物的同时发生聚酯化。 然后将树脂包封的混合物在还原气氛中在700℃下进行热处理。 这导致由导电碳涂覆的由橄榄石LiFePO 4相组成的细粉末的生产。 当这种粉末用作锂插入型电极中的活性材料时，在室温下能够获得快速的充放电率，并且观察到优异的容量保持率。

    THREE-DIMENSIONAL MICROBATTERY AND METHOD FOR THE PRODUCTION THEREOF
    4.
    发明申请
    THREE-DIMENSIONAL MICROBATTERY AND METHOD FOR THE PRODUCTION THEREOF 审中-公开
    三维微生物及其生产方法

    公开(公告)号：US20110070480A1

    公开(公告)日：2011-03-24

    申请号：US12919539

    申请日：2009-02-25

    申请人： Robert Hahn ,  Thomas Wohrle ,  Calin Wurm

    发明人： Robert Hahn ,  Thomas Wohrle ,  Calin Wurm

    IPC分类号： H01M10/02 ,  H01M10/04 ,  H01M6/46

    CPC分类号： H01M10/0436 ,  H01M2/0207 ,  H01M6/40 ,  H01M10/0525 ,  H01M10/0565 ,  H01M10/0585 ,  H01M2300/0085 ,  Y10T29/49115

    摘要： A three-dimensional microbattery is disclosed, in which a depression, in which two chambers lying adjacent to one another in the substrate plane are implemented, is provided in a substrate. The active mass, which is impregnated with an electrolyte, of negative and positive electrodes is received in each of the chambers. A porous partition wall, which is impregnated with the electrolyte and prevents a passage of active electrode mass, is located between the two chambers. The free surfaces of the active mass of both electrodes and the partition wall lie in a plane with the surface of the substrate. The electrodes and the partition wall are hermetically sealed by a cover layer, which projects beyond the edge of the depression.

    摘要翻译： 公开了一种三维微电池，其中在衬底中提供了其中实现了在衬底平面中彼此相邻放置的两个腔室的凹陷。 在每个室中接收由电解质浸渍的负极和正极的活性物质。 浸渍有电解质并防止有效电极块通过的多孔分隔壁位于两个室之间。 两个电极和分隔壁的活性物质的自由表面位于与衬底表面的平面内。 电极和分隔壁被覆盖层气密地密封，覆盖层突出超出凹陷的边缘。

    Carbon-coated Li-containing powders and process for production thereof
    5.
    发明授权
    Carbon-coated Li-containing powders and process for production thereof 有权
    含碳的含碳粉末及其生产方法

    公开(公告)号：US08236453B2

    公开(公告)日：2012-08-07

    申请号：US13042653

    申请日：2011-03-08

    申请人： Albane Audemer ,  Calin Wurm ,  Mathieu Morcrette ,  Sylvain Gwizdala ,  Christian Masquelier

    发明人： Albane Audemer ,  Calin Wurm ,  Mathieu Morcrette ,  Sylvain Gwizdala ,  Christian Masquelier

    IPC分类号： H01M4/58

    CPC分类号： H01M4/5825 ,  C01B25/37 ,  C01B25/375 ,  C01B25/45 ,  H01M4/131 ,  H01M4/1391 ,  H01M4/36 ,  H01M4/366 ,  H01M4/62 ,  H01M4/624 ,  H01M4/625 ,  H01M6/185 ,  H01M10/052 ,  H01M10/0562 ,  H01M2004/021 ,  H01M2004/028

    摘要： The invention provides a new route for the synthesis of carbon-coated powders having the olivine or NASICON structure, which form promising classes of active products for the manufacture of rechargeable lithium batteries. Carbon-coating of the powder particles is necessary to achieve good performances because of the rather poor electronic conductivity of said structures. For the preparation of coated LiFePO4, sources of Li, Fe and phosphate are dissolved in an aqueous solution together with a polycarboxylic acid and a polyhydric alcohol. Upon water evaporation, polyesterification occurs while a mixed precipitate is formed containing Li, Fe and phosphate. The resin-encapsulated mixture is then heat treated at 700° C. in a reducing atmosphere. This results in the production of a fine powder consisting of an olivine LiFePO4, phase, coated with conductive carbon. When this powder is used as active material in a lithium insertion-type electrode, fast charge and discharge rates are obtained at room temperature and an excellent capacity retention is observed.

    摘要翻译： 本发明提供了一种用于合成具有橄榄石或NASICON结构的碳涂覆粉末的新途径，其形成用于制造可再充电锂电池的有希望的活性产品类别。 由于所述结构的电子导电性差，所以粉末颗粒的碳涂层是必需的，以获得良好的性能。 为了制备涂覆的LiFePO 4，将Li，Fe和磷酸盐源与多元羧酸和多元醇一起溶解在水溶液中。 当水蒸发时，在形成含有Li，Fe和磷酸盐的混合沉淀物的同时发生聚酯化。 然后将树脂包封的混合物在还原气氛中在700℃下进行热处理。 这导致生产由用导电碳涂覆的橄榄石LiFePO 4相的细粉末。 当这种粉末用作锂插入型电极中的活性材料时，在室温下能够获得快速的充放电率，并且观察到优异的容量保持率。

    Carbon-coated Li-containing powders and process for production thereof
    8.
    发明授权
    Carbon-coated Li-containing powders and process for production thereof 有权
    含碳的含碳粉末及其生产方法

    公开(公告)号：US07923154B2

    公开(公告)日：2011-04-12

    申请号：US12270969

    申请日：2008-11-14

    申请人： Albane Audemer ,  Calin Wurm ,  Mathieu Morcrette ,  Sylvain Gwizdala ,  Christian Masquelier

    发明人： Albane Audemer ,  Calin Wurm ,  Mathieu Morcrette ,  Sylvain Gwizdala ,  Christian Masquelier

    IPC分类号： H01M4/58

    CPC分类号： H01M4/5825 ,  C01B25/37 ,  C01B25/375 ,  C01B25/45 ,  H01M4/131 ,  H01M4/1391 ,  H01M4/36 ,  H01M4/366 ,  H01M4/62 ,  H01M4/624 ,  H01M4/625 ,  H01M6/185 ,  H01M10/052 ,  H01M10/0562 ,  H01M2004/021 ,  H01M2004/028

    摘要： The invention provides a new route for the synthesis of carbon-coated powders having the olivine or NASICON structure, which form promising classes of active products for the manufacture of rechargeable lithium batteries. Carbon-coating of the powder particles is necessary to achieve good performances because of the rather poor electronic conductivity of said structures. For the preparation of coated LiFePO4, sources of Li, Fe and phosphate are dissolved in an aqueous solution together with a polycarboxylic acid and a polyhydric alcohol. Upon water evaporation, polyesterification occurs while a mixed precipitate is formed containing Li, Fe and phosphate. The resin-encapsulated mixture is then heat treated at 700° C. in a reducing atmosphere. This results in the production of a fine powder consisting of an olivine LiFePO4 phase, coated with conductive carbon. When this powder is used as active material in a lithium insertion-type electrode, fast charge and discharge rates are obtained at room temperature and an excellent capacity retention is observed.

    摘要翻译： 本发明提供了一种用于合成具有橄榄石或NASICON结构的碳涂覆粉末的新途径，其形成用于制造可再充电锂电池的有希望的活性产品类别。 由于所述结构的电子导电性差，所以粉末颗粒的碳涂层是必需的，以获得良好的性能。 为了制备涂覆的LiFePO 4，将Li，Fe和磷酸盐源与多元羧酸和多元醇一起溶解在水溶液中。 当水蒸发时，在形成含有Li，Fe和磷酸盐的混合沉淀物的同时发生聚酯化。 然后将树脂包封的混合物在还原气氛中在700℃下进行热处理。 这导致由导电碳涂覆的由橄榄石LiFePO 4相组成的细粉末的生产。 当这种粉末用作锂插入型电极中的活性材料时，在室温下能够获得快速的充放电率，并且观察到优异的容量保持率。

    Process for making lithium transition metal phosphate powder for battery electrode
    9.
    发明授权
    Process for making lithium transition metal phosphate powder for battery electrode 有权
    制备电池电极用锂过渡金属磷酸盐粉末的方法

    公开(公告)号：US07670721B2

    公开(公告)日：2010-03-02

    申请号：US11786334

    申请日：2007-04-11

    申请人： Calin Wurm ,  Mathieu Morcrette ,  Sylvain Gwizdala ,  Christian Masquelier

    发明人： Calin Wurm ,  Mathieu Morcrette ,  Sylvain Gwizdala ,  Christian Masquelier

    IPC分类号： C01B25/00

    CPC分类号： H01M4/136 ,  C01B25/375 ,  C01B25/377 ,  C01B25/45 ,  H01M4/1397 ,  H01M4/5825 ,  H01M10/052

    摘要： Methods of manufacture and use of phosphates of transition metals are described as positive electrodes for secondary lithium batteries, including a process for the production of LiMPO4 with controlled size and morphology, M being FexCoyNizMnw, where 0≦x≦1, 0≦y≦1, 0≦w≦1, and x+y+z+w=1. According to an exemplary embodiment, a process is described for the manufacture of LiFePO4 including the steps of providing an equimolar aqueous solution of Li1+, Fe3+ and PO43−, evaporating water from the solution to produce a solid mixture, decomposing the solid mixture at a temperature of below 500° C. to form a pure homogeneous Li and Fe phosphate precursor, and annealing the precursor at a temperature of less than 800° C. in a reducing atmosphere to produce the LiFePO4 powder. The obtained powders can have a particle size of less than 1 μm, and can provide superior electrochemical performance when mixed for an appropriate time with an electrically conductive powder.

    摘要翻译： 过渡金属磷酸盐的制造和使用方法被描述为二次锂电池的正电极，包括用于制备具有受控尺寸和形态的LiMPO4的方法，M是FexCoyNizMnw，其中0＆nlE; x＆nlE; 1,0＆amp; nlE; y＆nlE; 1 ，0＆nlE; w＆nlE; 1，x + y + z + w =​​ 1。 根据一个示例性实施方案，描述了制备LiFePO 4的方法，其包括以下步骤：提供Li1 +，Fe3 +和PO43-的等摩尔水溶液，从溶液中蒸发水以产生固体混合物，并在一定温度下分解固体混合物 在500℃以上以形成纯均匀的Li和Fe磷酸盐前体，并在还原气氛中在小于800℃的温度下退火前体以产生LiFePO 4粉末。 得到的粉末可以具有小于1μm的粒度，并且当与导电粉末混合适当的时间时，可提供优异的电化学性能。

    Carbon-coated li-containing powders and process for production thereof
    10.
    发明申请
    Carbon-coated li-containing powders and process for production thereof 失效
    含碳的含Li粉末及其生产方法

    公开(公告)号：US20060035150A1

    公开(公告)日：2006-02-16

    申请号：US10518560

    申请日：2003-06-19

    申请人： Albane Audemer ,  Calin Wurm ,  Mathieu Morcrette ,  Sylvain Gwizdala ,  Christain Masquelier

    发明人： Albane Audemer ,  Calin Wurm ,  Mathieu Morcrette ,  Sylvain Gwizdala ,  Christain Masquelier

    IPC分类号： H01M4/58 ,  B05D5/12

    CPC分类号： H01M4/5825 ,  C01B25/37 ,  C01B25/375 ,  C01B25/45 ,  H01M4/131 ,  H01M4/1391 ,  H01M4/36 ,  H01M4/366 ,  H01M4/62 ,  H01M4/624 ,  H01M4/625 ,  H01M6/185 ,  H01M10/052 ,  H01M10/0562 ,  H01M2004/021 ,  H01M2004/028

    摘要： The invention provides a new route for the synthesis of carbon-coated powders having the olivine or NASICON structure, which form promising classes of active products for the manufacture of rechargeable lithium batteries. Carbon-coating of the powder particles is necessary to achieve good performances because of the rather poor electronic conductivity of said structures. For the preparation of coated LiFePO4, sources of Li, Fe and phosphate are dissolved in an aqueous solution together with a polycarboxylic acid and a polyhydric alcohol. Upon water evaporation, polyesterification occurs while a mixed precipitate is formed containing Li, Fe and phosphate. The resin-encapsulated mixture is then heat treated at 700° C. in a reducing atmosphere. This results in the production of a fine powder consisting of an olivine LiFePO4 phase, coated with conductive carbon. When this powder is used as active material in a lithium insertion-type electrode, fast charge and discharge rates are obtained at room temperature and an excellent capacity retention is observed.

    摘要翻译： 本发明提供了一种用于合成具有橄榄石或NASICON结构的碳涂覆粉末的新途径，其形成用于制造可再充电锂电池的有希望的活性产品类别。 由于所述结构的电子导电性差，所以粉末颗粒的碳涂层是必需的，以获得良好的性能。 为了制备涂覆的LiFePO 4，将Li，Fe和磷酸盐源与多元羧酸和多元醇一起溶解在水溶液中。 当水蒸发时，在形成含有Li，Fe和磷酸盐的混合沉淀物的同时发生聚酯化。 然后将树脂包封的混合物在还原气氛中在700℃下进行热处理。 这导致生产由导电碳涂覆的由橄榄石LiFePO 4 N 4相组成的细粉末。 当这种粉末用作锂插入型电极中的活性材料时，在室温下能够获得快速的充放电率，并且观察到优异的容量保持率。