摘要:
A method for capturing certain fluorinated vinyl monomers from a gaseous mixture using ionic liquids is described. The gaseous mixture is contacted with at least one ionic liquid, whereby at least a portion of the fluorinated vinyl monomer is absorbed by the ionic liquid. The method is useful for reducing emissions of fluorinated vinyl monomers and for increasing the product yields in the manufacture of polymers from these monomers.
摘要:
A process for making an aqueous dispersion of fluorinated ionomer particles by providing dispersed particulate of fluorinated ionomer in an aqueous polymerization medium and polymerizing at least one fluorinated monomer having an ionic group in the aqueous polymerization medium in the presence of the dispersed particulate of fluorinated ionomer and initiator to form the aqueous dispersion of particles of fluorinated ionomer.
摘要:
A process for making an aqueous dispersion of fluoropolymer particles by polymerizing in a first polymerization step at least one fluorinated monomer having an ionic group in an aqueous polymerization medium in the presence of initiator, the polymerizing providing dispersed particulate of fluorinated ionomer, and polymerizing in a second polymerization step at least one fluorinated monomer in the aqueous polymerization medium in the presence of the dispersed particulate of fluorinated ionomer and initiator to form the aqueous dispersion of particles of fluoropolymer.
摘要:
A process for making an aqueous dispersion of fluoropolymer particles by providing dispersed particulate of fluorinated ionomer in an aqueous polymerization medium and polymerizing at least one fluorinated monomer in the aqueous polymerization medium in the presence of the dispersed particulate of fluorinated ionomer and initiator to form the aqueous dispersion of particles of fluoropolymer.
摘要:
A process for making an aqueous dispersion of fluorinated ionomer particles by polymerizing in a first polymerization step at least one fluorinated monomer having an ionic group in an aqueous polymerization medium in the presence of initiator, the polymerizing providing dispersed particulate of fluorinated ionomer, polymerizing in a second polymerization step at least one fluorinated monomer having an ionic group in the aqueous polymerization medium in the presence of the dispersed particulate of fluorinated ionomer and initiator to form the aqueous dispersion of particles of fluorinated ionomer, and suspending the first polymerization step prior to beginning the second polymerization step.
摘要:
Azeotropic or near-azeotropic compositions are disclosed comprising about 0.1 weight percent to about 99.9 weight percent Z-1,2,3,3,3-pentafluoropropene (Z-1225ye) and about 99.9 weight percent to about 0.1 weight percent E-1,2,3,3,3-pentafluoropropene (E-1225ye).Also disclosed is a method for increasing refrigeration capacity for 1,2,3,3,3-pentafluoropropene (HFC-1225ye), said method comprising increasing the amount of Z-isomer (Z-1225ye) relative to the amount of E-isomer (E-1225ye).
摘要:
A process for reducing the fluorosurfactant content of an aqueous fluoropolymer dispersion by filling a shipping container with fluoropolymer dispersion and contacting the dispersion with a fluorosurfactant sorbent in the shipping container.
摘要:
The present invention relates to the pyrolysis of hydrochlorofluorocarbons to form fluoromonomers such as tetrafluoroethylene, the pyrolysis being carried out in a reaction zone lined with nickel and mechanically supported by a jacket of other corrosion resistant metal, the nickel lining providing an improved yield of valuable reaction products.
摘要:
The present invention relates to the co-pyrolysis of fluoroform and chlorodifluoromethane to form a mixture of useful fluoroolefin and saturated HFCs, notably, tetrafluoroethylene and hexafluoropropylene and CF3CHF2 and CF3CHFCF3, respectively.