公开(公告)号：US20100032610A1

公开(公告)日：2010-02-11

申请号：US12517577

申请日：2007-12-12

申请人： Mario Joseph Nappa ,  Barbara Haviland Minor ,  Charles Joseph Noelke

发明人： Mario Joseph Nappa ,  Barbara Haviland Minor ,  Charles Joseph Noelke

IPC分类号： C09K5/00

CPC分类号： C09K5/045 ,  A62D1/0057 ,  A62D1/0092 ,  C08J9/127 ,  C08J9/146 ,  C08J9/149 ,  C08J2203/06 ,  C08J2203/12 ,  C08J2203/14 ,  C08J2203/142 ,  C08J2207/04 ,  C09K3/30 ,  C09K2205/126 ,  Y02P20/124

摘要： Azeotropic or near-azeotropic compositions are disclosed comprising about 0.1 weight percent to about 99.9 weight percent Z-1,2,3,3,3-pentafluoropropene (Z-1225ye) and about 99.9 weight percent to about 0.1 weight percent E-1,2,3,3,3-pentafluoropropene (E-1225ye).Also disclosed is a method for increasing refrigeration capacity for 1,2,3,3,3-pentafluoropropene (HFC-1225ye), said method comprising increasing the amount of Z-isomer (Z-1225ye) relative to the amount of E-isomer (E-1225ye).

摘要翻译： 公开了共沸或近共沸组合物，其包含约0.1重量％至约99.9重量％的Z-1,2,3,3,3-五氟丙烯（Z-1225ye）和约99.9重量％至约0.1重量％的E-1， 2,3,3,3-五氟丙烯（E-1225ye）。 还公开了用于提高1,2,3,3,3-五氟丙烯（HFC-1225ye）的制冷容量的方法，所述方法包括相对于E-异构体的量增加Z-异构体（Z-1225ye）的量 （E-1225ye）。

公开(公告)号：US09890311B2

公开(公告)日：2018-02-13

申请号：US14878381

申请日：2015-10-08

申请人： Mario Joseph Nappa ,  Barbara Haviland Minor ,  Allen Capron Sievert

发明人： Mario Joseph Nappa ,  Barbara Haviland Minor ,  Allen Capron Sievert

IPC分类号： C09K5/04 ,  F25B1/00 ,  F25B39/02 ,  C07C21/18 ,  F25B45/00 ,  F25B30/02 ,  F25B31/00 ,  F25B39/00

CPC分类号： C09K5/045 ,  C07C21/18 ,  C09K5/04 ,  C09K2205/126 ,  C09K2205/22 ,  C09K2205/40 ,  F25B1/00 ,  F25B30/02 ,  F25B31/002 ,  F25B39/00 ,  F25B39/02 ,  F25B45/00 ,  F25B2400/12 ,  F25B2400/121

摘要： The present invention relates to fluoroolefin compositions. The fluoroolefin compositions of the present invention are useful as refrigerants or heat transfer fluids and in processes for producing cooling or heat. Additionally, the fluoroolefin compositions of the present invention may be used to replace currently used refrigerant or heat transfer fluid compositions that have higher global warming potential.

公开(公告)号：US08668791B2

公开(公告)日：2014-03-11

申请号：US13313458

申请日：2011-12-07

申请人： Thomas J. Leck ,  Barbara Haviland Minor ,  Mario Joseph Nappa ,  Nandini C. Mouli ,  Jon Lee Howell

发明人： Thomas J. Leck ,  Barbara Haviland Minor ,  Mario Joseph Nappa ,  Nandini C. Mouli ,  Jon Lee Howell

IPC分类号： C09K5/04

CPC分类号： C09K5/045 ,  C09K2205/126

摘要： The present disclosure relates to compositions comprising at least one fluoroolefin and an effective amount of a stabilizer comprising at least one ascorbic acid, terephthalate, or nitromethane, or mixtures thereof. The stabilized compositions may be useful in cooling apparatus, such as refrigeration, air-conditioning, chillers and heat pumps, as well as in applications as foam blowing agents, solvents, aerosol propellants, fire extinguishants, and sterilants.

摘要翻译： 本公开涉及包含至少一种氟代烯烃和有效量的包含至少一种抗坏血酸，对苯二甲酸酯或硝基甲烷或其混合物的稳定剂的组合物。 稳定的组合物可用于冷却装置，例如制冷，空调，冷却器和热泵，以及作为泡沫发泡剂，溶剂，气溶胶推进剂，灭火剂和灭菌剂的应用。

公开(公告)号：US08529786B2

公开(公告)日：2013-09-10

申请号：US12377474

申请日：2007-08-31

申请人： Thomas J. Leck ,  Nandini C. Mouli ,  Barbara Haviland Minor ,  Mario Joseph Nappa ,  Jon Lee Howell

发明人： Thomas J. Leck ,  Nandini C. Mouli ,  Barbara Haviland Minor ,  Mario Joseph Nappa ,  Jon Lee Howell

IPC分类号： C09K5/04

CPC分类号： C09K5/045 ,  C09K2205/126

摘要： The present disclosure relates to compositions comprising at least one fluoroolefin and an effective amount of a stabilizer comprising at least one phosphorus-containing compound selected from the group consisting of thiophosphates, butylated triphenylphosphorothionates, and organophosphates. The stabilized compositions may be useful in cooling apparatus, such as refrigeration, air-conditioning, chillers and heat pumps, as well as in applications as foam blowing agents, solvents, aerosol propellants, fire extinguishants, and sterilants.

摘要翻译： 本公开涉及包含至少一种氟代烯烃和有效量的稳定剂的组合物，其包含至少一种选自硫代磷酸酯，丁基化三苯基硫代硫酸酯和有机磷酸酯的含磷化合物。 稳定的组合物可用于冷却装置，例如制冷，空调，冷却器和热泵，以及作为泡沫发泡剂，溶剂，气溶胶推进剂，灭火剂和灭菌剂的应用。

公开(公告)号：US20100288965A1

公开(公告)日：2010-11-18

申请号：US12377645

申请日：2007-08-31

申请人： Jon Lee Howell ,  Velliyur Nott Mallikarjuna Rao ,  Thomas J. Leck ,  Barbara Haviland Minor ,  Mario Joseph Nappa ,  Nandini C. Mouli ,  Ekaterina Swearingen ,  Andrew Edward Feiring

发明人： Jon Lee Howell ,  Velliyur Nott Mallikarjuna Rao ,  Thomas J. Leck ,  Barbara Haviland Minor ,  Mario Joseph Nappa ,  Nandini C. Mouli ,  Ekaterina Swearingen ,  Andrew Edward Feiring

IPC分类号： C07C17/42 ,  C09K5/04

CPC分类号： C09K5/045 ,  C09K2205/126

摘要： The present invention relates to compositions comprising at least one fluoroolefin and an effective amount of stabilizer that may be a terpene, terpenoid or fullerene; or a mixture of a terpene, terpenoid or fullerene with other stabilizers. The stabilized compositions may be useful in cooling apparatus, such as refrigeration, air-conditioning, chillers, and heat pumps, as well as in applications as foam blowing agents, solvents, aerosol propellants, fire extinguishants, and sterilants.

摘要翻译： 本发明涉及包含至少一种氟烯烃和有效量的可以是萜烯，萜烯或富勒烯的稳定剂的组合物; 或萜烯，萜烯或富勒烯与其他稳定剂的混合物。 稳定的组合物可用于冷却装置，例如制冷，空调，冷却器和热泵，以及作为泡沫发泡剂，溶剂，气溶胶推进剂，灭火剂和灭菌剂的应用。

公开(公告)号：US20090056349A1

公开(公告)日：2009-03-05

申请号：US12263786

申请日：2008-11-03

申请人： Mario Joseph Nappa ,  Barbara Haviland Minor ,  Velliyur Nott Mallikarjuna Rao

发明人： Mario Joseph Nappa ,  Barbara Haviland Minor ,  Velliyur Nott Mallikarjuna Rao

IPC分类号： F25D15/00 ,  C09K5/10 ,  C09K5/04 ,  B08B3/08 ,  C11D7/50

CPC分类号： C09K5/045 ,  C09K2205/102 ,  C09K2205/108 ,  C09K2205/11 ,  C09K2205/122 ,  C09K2205/126 ,  C09K2205/132 ,  C11D7/505 ,  C11D7/5063 ,  C11D7/5068 ,  C23G5/02803

摘要： Disclosed herein are 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene compositions for use in refrigeration and air conditioning systems, particularly in centrifugal compressor systems. Also disclosed are 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene in combination with at least one bromofluorocarbon, ketones, alcohols, chlorocarbons, ethers, esters, 4-chloro-1,1,2,3,3,4-hexafluorobutene, N-(difluoromethyl)-N,N-dimethylamine, or mixtures thereof, which are azeotropic or near azeotropic.

摘要翻译： 本文公开了用于制冷和空调系统中的3,3,4,4,5,5,6,6,6-九氟-1-己烯组合物，特别是在离心式压缩机系统中。 还公开了3,3,4,4,5,5,6,6,6-九氟-1-己烯与至少一种溴氟烃，酮，醇，氯代烃，醚，酯，4-氯-1,2-二氯， 1,2,3,3,4-六氟丁烯，N-（二氟甲基）-N，N-二甲胺或其混合物，它们是共沸的或接近共沸的。

公开(公告)号：US07449126B2

公开(公告)日：2008-11-11

申请号：US11410587

申请日：2006-04-25

申请人： Mario Joseph Nappa ,  Barbara Haviland Minor ,  Velliyur Nott Mallikarjuna Rao

发明人： Mario Joseph Nappa ,  Barbara Haviland Minor ,  Velliyur Nott Mallikarjuna Rao

IPC分类号： C09K5/04

CPC分类号： C11D7/5072 ,  C09K5/045 ,  C09K2205/12

摘要： Disclosed herein are 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene compositions for use in refrigeration and air conditioning systems, particularly in centrifugal compressor systems. Also disclosed are 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene in combination with hydrocarbons, which are azeotropic or near azeotropic.

摘要翻译： 本文公开了用于制冷和空调系统中的3,3,4,4,5,5,6,6,6-九氟-1-己烯组合物，特别是在离心式压缩机系统中。 还公开了3,3,4,4,5,5,6,6,6-九氟-1-己烯与烃共沸，它们是共沸的或接近共沸的。

公开(公告)号：US07413676B2

公开(公告)日：2008-08-19

申请号：US11410491

申请日：2006-04-25

申请人： Mario Joseph Nappa ,  Barbara Haviland Minor ,  Allen Capron Sievert ,  Velliyur Nott Mallikarjuna Rao

发明人： Mario Joseph Nappa ,  Barbara Haviland Minor ,  Allen Capron Sievert ,  Velliyur Nott Mallikarjuna Rao

IPC分类号： C09K5/04

CPC分类号： C09K5/045 ,  C09K2205/112 ,  C09K2205/126 ,  C09K2205/32 ,  C11D7/5063 ,  C11D11/0047 ,  C23G5/02803 ,  C23G5/032

摘要： The present invention relates to Disclosed herein are 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene compositions for use in refrigeration and air conditioning systems, particularly in centrifugal compressor systems. Also disclosed are 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene in combination with fluoroethers, which are azeotropic or near azeotropic.

摘要翻译： 本发明涉及用于制冷和空调系统中的3,3,4,4,5,5,6,6,6-九氟-1-己烯组合物，特别是在离心式压缩机系统中。 还公开了3,3,4,4,5,5,6,6,6-九氟-1-己烯与氟代醚的组合，它们是共沸的或接近共沸的。

公开(公告)号：US08535555B2

公开(公告)日：2013-09-17

申请号：US12377454

申请日：2007-08-31

申请人： Andrew Edward Feiring ,  Viacheslav A. Petrov ,  Barbara Haviland Minor ,  Mario Joseph Nappa ,  Nandini C. Mouli ,  Thomas J. Leck ,  Jon Lee Howell

发明人： Andrew Edward Feiring ,  Viacheslav A. Petrov ,  Barbara Haviland Minor ,  Mario Joseph Nappa ,  Nandini C. Mouli ,  Thomas J. Leck ,  Jon Lee Howell

IPC分类号： C09K5/04

CPC分类号： C09K5/045 ,  C09K2205/10 ,  C09K2205/102 ,  C09K2205/104 ,  C09K2205/11 ,  C09K2205/126 ,  C09K2205/132 ,  C09K2205/134 ,  C09K2205/24 ,  F25B39/02

摘要： The present invention relates to compositions comprising at least one fluoroolefin and an effective amount of stabilizer that may be an epoxide, fluorinated epoxide or oxetane, or a mixture thereof with other stabilizers. The stabilized compositions may be useful in cooling apparatus, such as refrigeration, air-conditioning, chillers, and heat pumps, as well as in applications as foam blowing agents, solvents, aerosol propellants, fire extinguishants, and sterilants.

公开(公告)号：US08394286B2

公开(公告)日：2013-03-12

申请号：US12377708

申请日：2007-08-31

申请人： Thomas J. Leck ,  Barbara Haviland Minor ,  Mario Joseph Nappa ,  Nandini C. Mouli

发明人： Thomas J. Leck ,  Barbara Haviland Minor ,  Mario Joseph Nappa ,  Nandini C. Mouli

IPC分类号： C09K5/04

CPC分类号： C09K5/045 ,  C09K2205/126

摘要： The present disclosure relates to compositions comprising at least one fluoroolefin and an effective amount of a stabilizer comprising at least one thiol or thioether, or mixtures thereof. The stabilized compositions may be useful in cooling apparatus, such as refrigeration, air-conditioning, chillers and heat pumps, as well as in applications as foam blowing agents, solvents, aerosol propellants, fire extinguishants, and sterilants.

摘要翻译： 本公开涉及包含至少一种氟烯烃和有效量的包含至少一种硫醇或硫醚的稳定剂或其混合物的组合物。 稳定的组合物可用于冷却装置，例如制冷，空调，冷却器和热泵，以及作为泡沫发泡剂，溶剂，气溶胶推进剂，灭火剂和灭菌剂的应用。