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    Electrode protection in both aqueous and non-aqueous electrochemical cells, including rechargeable lithium batteries
    2.
    发明申请
    Electrode protection in both aqueous and non-aqueous electrochemical cells, including rechargeable lithium batteries 有权
    水电和非水电化学电池中的电极保护，包括可充电锂电池

    公开(公告)号：US20070224502A1

    公开(公告)日：2007-09-27

    申请号：US11400025

    申请日：2006-04-06

    申请人： John D. Affinito ,  Yuriy Mikhaylik ,  Yordan Geronov ,  Christopher Sheehan

    发明人： John D. Affinito ,  Yuriy Mikhaylik ,  Yordan Geronov ,  Christopher Sheehan

    IPC分类号： H01M4/02 ,  H01M10/44

    CPC分类号： H01M4/366 ,  H01M2/1673 ,  H01M4/02 ,  H01M4/13 ,  H01M4/382 ,  H01M4/385 ,  H01M4/62 ,  H01M4/628 ,  H01M4/66 ,  H01M4/661 ,  H01M10/36 ,  H01M10/4235 ,  H01M10/44 ,  H01M2004/021 ,  H01M2004/027 ,  H01M2300/0002 ,  Y02E60/122 ,  Y02P70/54

    摘要： Electrode protection in electrochemical cells, and more specifically, electrode protection in both aqueous and non-aqueous electrochemical cells, including rechargeable lithium batteries, are presented. In one embodiment, an electrochemical cell includes an anode comprising lithium and a multi-layered structure positioned between the anode and an electrolyte of the cell. A multi-layered structure can include at least a first single-ion conductive material layer (e.g., a lithiated metal layer), and at least a first polymeric layer positioned between the anode and the single-ion conductive material. The invention also can provide an electrode stabilization layer positioned within the electrode, i.e., between one portion and another portion of an electrode, to control depletion and re-plating of electrode material upon charge and discharge of a battery. Advantageously, electrochemical cells comprising combinations of structures described herein are not only compatible with environments that are typically unsuitable for lithium, but the cells may be also capable of displaying long cycle life, high lithium cycling efficiency, and high energy density.

    摘要翻译： 在电化学电池中的电极保护，更具体地说，包括可再充电锂电池在水性和非水电化学电池中的电极保护。 在一个实施例中，电化学电池包括包含锂的阳极和位于电池的阳极和电解质之间的多层结构。 多层结构可以包括至少第一单离子导电材料层（例如，锂化金属层）和至少第一聚合物层，其位于阳极和单离子导电材料之间。 本发明还可以提供一种位于电极内，即电极的一部分与另一部分之间的电极稳定层，以在电池充电和放电时控制电极材料的耗尽和再镀层。 有利地，包含本文所述结构的电化学电池不仅与通常不适合于锂的环境兼容，而且电池还可以显示长循环寿命，高锂循环效率和高能量密度。

    Rechargeable lithium/water, lithium/air batteries
    3.
    发明申请
    Rechargeable lithium/water, lithium/air batteries 审中-公开
    充电锂/水，锂/空气电池

    公开(公告)号：US20070221265A1

    公开(公告)日：2007-09-27

    申请号：US11400781

    申请日：2006-04-06

    申请人： John Affinito ,  Yuriy Mikhaylik ,  Yordan Geronov ,  Christopher Sheehan

    发明人： John Affinito ,  Yuriy Mikhaylik ,  Yordan Geronov ,  Christopher Sheehan

    IPC分类号： H02N6/00 ,  H01L25/00

    CPC分类号： H01M4/366 ,  H01M2/1673 ,  H01M4/02 ,  H01M4/13 ,  H01M4/382 ,  H01M4/385 ,  H01M4/62 ,  H01M4/628 ,  H01M4/66 ,  H01M4/661 ,  H01M10/36 ,  H01M10/4235 ,  H01M10/44 ,  H01M2004/021 ,  H01M2004/027 ,  H01M2300/0002 ,  Y02E60/122 ,  Y02P70/54

    摘要： Electrochemical cells, and more specifically, rechargeable batteries comprising lithium anodes for use in water and/or air environments, as well as non-aqueous and non-air environments, are presented. In one embodiment, an electrochemical cell includes an anode comprising lithium and a multi-layered structure positioned between the anode and an electrolyte of the cell. A multi-layered structure can include at least a first single-ion conductive material layer (e.g., a lithiated metal layer), and at least a first polymeric layer positioned between the anode and the single-ion conductive material. The invention also can provide an electrode stabilization layer positioned within the electrode, i.e., between one portion and another portion of an electrode, to control depletion and re-plating of electrode material upon charge and discharge of a battery. Advantageously, electrochemical cells comprising combinations of structures described herein are not only compatible with environments that are typically unsuitable for lithium, but the cells may be also capable of displaying long cycle life, high lithium cycling efficiency, and high energy density.

    摘要翻译： 提出了电化学电池，更具体地说，包括用于水和/或空气环境的锂阳极以及非水和非空气环境的可再充电电池。 在一个实施例中，电化学电池包括包含锂的阳极和位于电池的阳极和电解质之间的多层结构。 多层结构可以包括至少第一单离子导电材料层（例如，锂化金属层）和至少第一聚合物层，其位于阳极和单离子导电材料之间。 本发明还可以提供一种位于电极内，即电极的一部分与另一部分之间的电极稳定层，以在电池充电和放电时控制电极材料的耗尽和再镀层。 有利地，包含本文所述结构的电化学电池不仅与通常不适合于锂的环境兼容，而且电池还可以显示长循环寿命，高锂循环效率和高能量密度。