摘要:
Systems and methods for producing hydrogen gas with a fuel processing system that includes a hydrogen-producing region that produces hydrogen gas from a feed stream and a heating assembly that consumes a fuel stream to produce a heated exhaust stream for heating the hydrogen-producing region. In some embodiments, the heating assembly heats the hydrogen-producing region to at least a minimum hydrogen-producing temperature. In some embodiments, the rate at which an air stream is delivered to the heating assembly is controlled to selectively increase or decrease the temperature of the heated exhaust stream. In some embodiments, the feed stream and the fuel stream both contain a carbon-containing feedstock and at least 25 wt % water. In some embodiments, the feed and fuel streams have the same composition.
摘要:
Systems and methods for producing hydrogen gas with a fuel processing system that includes a hydrogen-producing region that produces hydrogen gas from a feed stream and a heating assembly that consumes a fuel stream to produce a heated exhaust stream for heating the hydrogen-producing region. In some embodiments, the heating assembly heats the hydrogen-producing region to at least a minimum hydrogen-producing temperature. In some embodiments, the feed stream and the fuel stream both contain a carbon-containing feedstock and at least 25 wt % water. In some embodiments, at least one of the feed and fuel streams contain at least one additional component. In some embodiments, the feed and fuel streams have the same composition. In some embodiments, the feed and fuel streams are drawn or obtained from a common source or supply, and in some embodiments as a liquid stream that is selectively apportioned to form the feed and fuel streams.
摘要:
Methanol steam reforming catalysts, and steam reformers and fuel cell systems incorporating the same. In some embodiments, the methanol steam reforming catalyst includes zinc oxide as an active component. In some embodiments, the methanol steam reforming catalyst further includes at least one of chromium oxide and calcium aluminate. In some embodiments, the methanol steam reforming catalyst is not pyrophoric. Similarly, in some embodiments, steam reformers including a reforming catalyst according to the present disclosure may include an air-permeable or air-accessible reforming catalyst bed. In some embodiments, the methanol steam reforming catalyst is not reduced during use. In some embodiments, the methanol reforming catalysts are not active at temperatures below 275° C. In some embodiments, the methanol steam reforming catalyst includes a sulfur-absorbent material. Steam reformers, reforming systems, fuel cell systems and methods of using the reforming catalysts are also disclosed.
摘要:
Systems and methods for producing hydrogen gas with a fuel processing system that includes a hydrogen-producing region that produces hydrogen gas from a feed stream and a heating assembly that consumes a fuel stream to produce a heated exhaust stream for heating the hydrogen-producing region. In some embodiments, the heating assembly heats the hydrogen-producing region to at least a minimum hydrogen-producing temperature. In some embodiments, the feed stream and the fuel stream both contain a carbon-containing feedstock and at least 25 wt % water. In some embodiments, at least one of the feed and fuel streams contain at least one additional component. In some embodiments, the feed and fuel streams have the same composition. In some embodiments, the feed and fuel streams are drawn or obtained from a common source or supply, and in some embodiments as a liquid stream that is selectively apportioned to form the feed and fuel streams.
摘要:
PSA assemblies with at least one energy recovery assembly, as well as hydrogen-generation assemblies and/or fuel cell systems containing the same, and methods of operating the same. The energy recovery assemblies are configured to recover mechanical energy from the product hydrogen stream and to apply the recovered mechanical energy to one or more components of the PSA assembly, the hydrogen-generation assembly, and/or the energy producing system. In some embodiments, the energy recovery assembly includes a gas motor configured to recover mechanical energy from the product hydrogen stream produced by the PSA assembly. In some embodiments, the gas motor operates among a plurality of operating states based, at least in part, on the pressure of the product hydrogen stream. In some embodiments, the energy recovery assembly is configured to apply the recovered mechanical energy to at least a vacuum pump.
摘要:
Methanol steam reforming catalysts, and steam reformers and fuel cell systems incorporating the same. In some embodiments, the methanol steam reforming catalyst includes zinc oxide as an active component. In some embodiments, the methanol steam reforming catalyst further includes at least one of chromium oxide and calcium aluminate. In some embodiments, the methanol steam reforming catalyst is not pyrophoric. Similarly, in some embodiments, steam reformers including a reforming catalyst according to the present disclosure may include an air-permeable or air-accessible reforming catalyst bed. In some embodiments, the methanol steam reforming catalyst is not reduced during use. In some embodiments, the methanol reforming catalysts are not active at temperatures below 275° C. In some embodiments, the methanol steam reforming catalyst includes a sulfur-absorbent material. Steam reformers, reforming systems, fuel cell systems and methods of using the reforming catalysts are also disclosed.
摘要:
Pressure swing adsorption (PSA) assemblies with optimized startup times, as well as to hydrogen-generation assemblies and/or fuel cell systems containing the same, and methods of operating the same. Startup and shutdown methods for a PSA assembly, and optionally an associated fuel processing system, are disclosed to provide for shortened startup times. The PSA assemblies may be in fluid communication with a hydrogen source that may be used or otherwise configured or controlled to purge the PSA adsorbent columns of adsorbents during startup and/or shutdown procedures, the hydrogen source additionally or alternatively may be used or otherwise configured or controlled to charge the columns with hydrogen for idling in a pressurized state. The use of this hydrogen source, together with specific startup and shutdown methodologies, provides for reducing the startup time of the PSA assembly.
摘要:
Pressure swing adsorption (PSA) assemblies with optimized startup times, as well as to hydrogen-generation assemblies and/or fuel cell systems containing the same, and methods of operating the same. Startup and shutdown methods for a PSA assembly, and optionally an associated fuel processing system, are disclosed to provide for shortened startup times. The PSA assemblies may be in fluid communication with a hydrogen source that may be used or otherwise configured or controlled to purge the PSA adsorbent columns of adsorbents during startup and/or shutdown procedures, the hydrogen source additionally or alternatively may be used or otherwise configured or controlled to charge the columns with hydrogen for idling in a pressurized state. The use of this hydrogen source, together with specific startup and shutdown methodologies, provides for reducing the startup time of the PSA assembly.
摘要:
Hydrogen-producing fuel processing assemblies, including steam reforming fuel processing assemblies, startup assemblies for use therein, and methods of operating the same. In some embodiments, the startup assemblies include a startup reforming region that is upstream from a primary, or second, hydrogen-producing reforming region. In some embodiments, the startup reforming region and primary reforming regions are both steam reforming regions. In some embodiments, the startup assembly further includes at least one of a vaporization region and a startup heating assembly. In some embodiments, the startup heating assembly is an electrically powered heating assembly, and the fuel processing assembly further includes a (primary) heating assembly that combusts a byproduct stream from the fuel processing assembly to produce a combustion exhaust stream. In some embodiments, the startup reforming region is adapted to produce a gaseous output stream that will remain a gas-phase stream even if cooled below a minimum hydrogen-producing temperature.
摘要:
Systems and methods for monitoring and/or controlling fuel cell exhaust to provide a non-flammable exhaust stream. In some embodiments, operation of the fuel cell system is regulated to provide an exhaust stream that has a maximum flammability that is less than a predetermined fractional threshold of the lower flammability limit for the gases contained therein. In some embodiments, the systems and methods utilize the current produced by the fuel cell, or fuel cell stack, to monitor and/or regulate the flammability of the fuel cell exhaust stream. In some embodiments, the fuel cell system includes one or more controllers that are adapted to monitor the flammability of the exhaust stream from the fuel cell stack and/or to regulate the operation of the fuel cell system responsive thereto. In some embodiments, the operation and/or duty cycle of at least an anode purge valve is regulated or controlled responsive to the measured current.